GB903132A - Process for the manufacture of epoxy resins - Google Patents
Process for the manufacture of epoxy resinsInfo
- Publication number
- GB903132A GB903132A GB3445760A GB3445760A GB903132A GB 903132 A GB903132 A GB 903132A GB 3445760 A GB3445760 A GB 3445760A GB 3445760 A GB3445760 A GB 3445760A GB 903132 A GB903132 A GB 903132A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glycidol
- monoglycidyl ether
- reacting
- reaction
- epoxy resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003822 epoxy resin Substances 0.000 title abstract 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 title abstract 2
- 229920000647 polyepoxide Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 abstract 4
- ZQUWQGHAAIMMFF-UHFFFAOYSA-N 3-(oxiran-2-ylmethoxy)phenol Chemical compound OC1=CC=CC(OCC2OC2)=C1 ZQUWQGHAAIMMFF-UHFFFAOYSA-N 0.000 abstract 2
- 125000005529 alkyleneoxy group Chemical group 0.000 abstract 2
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- -1 orthotitanic acid ester Chemical class 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 150000005846 sugar alcohols Polymers 0.000 abstract 2
- 239000004593 Epoxy Substances 0.000 abstract 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 abstract 1
- 150000008065 acid anhydrides Chemical class 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000000732 arylene group Chemical group 0.000 abstract 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3254—Epoxy compounds containing three or more epoxy groups containing atoms other than carbon, hydrogen, oxygen or nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
Abstract
Epoxy resins are made by reacting an orthotitanic acid ester with a monoglycidyl compound containing at least one hydroxyl group, selected from glycidol and its monoethers with di- or polyalcohols, to produce a resin <FORM:0903132/IV(a)/1> in which x is zero or a whole number and R is alkylene, alkyleneoxy, arylene, aryleneoxy or substituted forms of these groups, the resin then being hardened by reacting with an organic amine or an acid anhydride. The examples describe the reaction of tetrabutyl titanate with:-(1) glycidol; (2) glycol monoglycidyl ether and (3) resorcinol monoglycidyl ether, the products being cured by reaction with:- (1) diethylamine and (2) and (3) phthalic anhydride.ALSO:Epoxy containing compounds of the formula <FORM:0903132/IV (b)/1> where x is zero or a whole number and R is alkyleneoxy, or aryleneoxy or substituted forms of these groups, are made by reacting an ortho-titanic acid ester with glycidol or a monoether thereof with a di- or polyalcohol. The examples describe the reaction of tetrabutyl titanate with:-(1) glycidol; (2) glycol monoglycidyl ether and (3) resorcinol monoglycidyl ether.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEL34435A DE1105612B (en) | 1959-10-08 | 1959-10-08 | Process for the production of plastics based on polyepoxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB903132A true GB903132A (en) | 1962-08-09 |
Family
ID=7266670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3445760A Expired GB903132A (en) | 1959-10-08 | 1960-10-07 | Process for the manufacture of epoxy resins |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1105612B (en) |
| GB (1) | GB903132A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2353998A (en) * | 1999-09-08 | 2001-03-14 | Goodyear Tire & Rubber | Titanium and zirconium compounds |
| CN100375757C (en) * | 2005-09-28 | 2008-03-19 | 中国航空工业第一集团公司北京航空材料研究院 | Organic titanium epoxy resin catalytic ester cyanate system |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1127079B (en) * | 1960-07-05 | 1962-04-05 | Licentia Gmbh | Process for the production of molded bodies by curing polyepoxy compounds with customary curing agents |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE910335C (en) * | 1951-05-31 | 1954-04-29 | Albert Ag Chem Werke | Method of hardening AEthoxylin resins |
-
1959
- 1959-10-08 DE DEL34435A patent/DE1105612B/en active Pending
-
1960
- 1960-10-07 GB GB3445760A patent/GB903132A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2353998A (en) * | 1999-09-08 | 2001-03-14 | Goodyear Tire & Rubber | Titanium and zirconium compounds |
| US6417286B1 (en) * | 1999-09-08 | 2002-07-09 | The Goodyear Tire & Rubber Company | Titanium and zirconium compounds |
| GB2353998B (en) * | 1999-09-08 | 2004-03-17 | Goodyear Tire & Rubber | Titanium and zirconium compounds |
| US6870064B2 (en) | 1999-09-08 | 2005-03-22 | The Goodyear Tire & Rubber Company | Titanium and zirconium compounds |
| CN100375757C (en) * | 2005-09-28 | 2008-03-19 | 中国航空工业第一集团公司北京航空材料研究院 | Organic titanium epoxy resin catalytic ester cyanate system |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1105612B (en) | 1961-04-27 |
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