GB906408A - Phosphorus containing condensation polymers - Google Patents
Phosphorus containing condensation polymersInfo
- Publication number
- GB906408A GB906408A GB4040558A GB4040558A GB906408A GB 906408 A GB906408 A GB 906408A GB 4040558 A GB4040558 A GB 4040558A GB 4040558 A GB4040558 A GB 4040558A GB 906408 A GB906408 A GB 906408A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphorus
- compound
- prepared
- formula
- trihalide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052698 phosphorus Inorganic materials 0.000 title abstract 12
- 239000011574 phosphorus Substances 0.000 title abstract 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title abstract 5
- 229920000642 polymer Polymers 0.000 title abstract 4
- 230000005494 condensation Effects 0.000 title 1
- 238000009833 condensation Methods 0.000 title 1
- -1 phosphorus compound Chemical class 0.000 abstract 10
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 4
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 abstract 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- SXIWNIQDOJKDGB-UHFFFAOYSA-N dichloro-phenyl-sulfanylidene-$l^{5}-phosphane Chemical compound ClP(Cl)(=S)C1=CC=CC=C1 SXIWNIQDOJKDGB-UHFFFAOYSA-N 0.000 abstract 2
- IBDMRHDXAQZJAP-UHFFFAOYSA-N dichlorophosphorylbenzene Chemical compound ClP(Cl)(=O)C1=CC=CC=C1 IBDMRHDXAQZJAP-UHFFFAOYSA-N 0.000 abstract 2
- 125000005843 halogen group Chemical group 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 229910052740 iodine Inorganic materials 0.000 abstract 2
- 239000011630 iodine Substances 0.000 abstract 2
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 abstract 2
- 229910001623 magnesium bromide Inorganic materials 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical group [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- IMDXZWRLUZPMDH-UHFFFAOYSA-N dichlorophenylphosphine Chemical compound ClP(Cl)C1=CC=CC=C1 IMDXZWRLUZPMDH-UHFFFAOYSA-N 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
- C08G79/06—Phosphorus linked to carbon only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
Abstract
Polymers having the formula <FORM:0906408/IV(a)/1> where R is a monofunctional aromatic hydrocarbon radical; X is a difunctional hydrocarbon group which can be aliphatic, aromatic or substituted groups of these types; Y is an oxygen atom, a sulphur atom or is absent (i.e. the phosphorus is trivalent); and n is 3 to 10 or higher-are prepared by condensing a difunctional organo-metallic compound having the formula M-X-M, where M is MgCl, MgBr, MgI, Li, Na or K, with a phosphorus compound having the formula <FORM:0906408/IV(a)/2> where Z is chlorine, bromine or iodine; the phosphorus compound reactant may be replaced partially or completely by a phosphorus compound containing three halogen atoms bonded directly to the phosphorus atom, e.g. a phosphorus trihalide, phosphoryl trihalide or thiophosphorus trihalide. In the examples polymers are prepared by reacting (1) phenyl phosphonic dichloride with phenylene 1:4-dilithium in tetrahydrofuran to give a product soluble in ethyl alcohol (2) phenyl phosphonic dichloride, phosphorus oxychloride and the disodium compound prepared from 4,41-dibromodiphenyl ether in a solvent mixture of tetrahydrofuran and ether (3) phenyldichlorophosphine and the dilithium compound prepared from 1:10-dibromodecane (4) phosphorus oxychloride and the di Grignard compound prepared from 1:5-dibromopentene in diethyl ether and (5) phenyldichlorophosphine sulphide and phenylene 1:4-bis magnesium bromide.ALSO:Polymers having the formula <FORM:0906408/IV (b)/1> or <FORM:0906408/IV (b)/2> where R is a monofunctional aromatic hydrocarbon radical; X is a difunctional hydrocarbon group which can be aliphatic, aromatic, or substituted groups of these types; Y is an oxygen atom, a sulphur atom or is absent (i.e. the phosphorus is trivalent); and n is at least 3-are prepared by condensing a difunctional organo-metallic compound having the formula M-X-M, where H is MgCl, MgBr, MgI, Li, Na or K, with a phosphorus compound having the formula <FORM:0906408/IV (b)/3> where Z is chlorine, bromine or iodine and/or with a phosphorus compound containing three halogen atoms bonded directly to the phosphorus atom, e.g. a phosphorus trihalide, phosphoryl trihalide or thiophosphorus trihalide. The reactants utilised in the examples are organo-metallic compounds phenylene 1:4-dilithium, the disodium compound prepared from 4,41-dibromodiphenyl ether, the dilithium compound prepared from 1:10-dibromodecane, the di Grignard compound prepared from 1:5-dibromopentene, and phenylene 1:4 bis magnesium bromide; phosphorus compounds phenyl phosphoric dichloride, phosphorus oxychloride and phenyldichlorophosphine sulphide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4040558A GB906408A (en) | 1958-12-15 | 1958-12-15 | Phosphorus containing condensation polymers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB4040558A GB906408A (en) | 1958-12-15 | 1958-12-15 | Phosphorus containing condensation polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB906408A true GB906408A (en) | 1962-09-19 |
Family
ID=10414744
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4040558A Expired GB906408A (en) | 1958-12-15 | 1958-12-15 | Phosphorus containing condensation polymers |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB906408A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004055098A3 (en) * | 2002-12-16 | 2004-09-02 | Univ British Columbia | Polymerization of phosphaalkenes |
-
1958
- 1958-12-15 GB GB4040558A patent/GB906408A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004055098A3 (en) * | 2002-12-16 | 2004-09-02 | Univ British Columbia | Polymerization of phosphaalkenes |
| US7728091B2 (en) | 2002-12-16 | 2010-06-01 | The University Of British Columbia | Polymerization of phosphaalkenes |
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