GB893816A - Improvements in or relating to synthetic resin emulsions and their production and to surface coatings and vibration damping compositions derived therefrom - Google Patents
Improvements in or relating to synthetic resin emulsions and their production and to surface coatings and vibration damping compositions derived therefromInfo
- Publication number
- GB893816A GB893816A GB884958A GB884958A GB893816A GB 893816 A GB893816 A GB 893816A GB 884958 A GB884958 A GB 884958A GB 884958 A GB884958 A GB 884958A GB 893816 A GB893816 A GB 893816A
- Authority
- GB
- United Kingdom
- Prior art keywords
- emulsion
- dispersion
- styrene
- polymerization
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 14
- 239000000839 emulsion Substances 0.000 title abstract 10
- 238000013016 damping Methods 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920003002 synthetic resin Polymers 0.000 title 1
- 239000000057 synthetic resin Substances 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 14
- 239000006185 dispersion Substances 0.000 abstract 10
- 239000010445 mica Substances 0.000 abstract 7
- 229910052618 mica group Inorganic materials 0.000 abstract 7
- 238000006116 polymerization reaction Methods 0.000 abstract 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 6
- 239000000178 monomer Substances 0.000 abstract 6
- CMCJNODIWQEOAI-UHFFFAOYSA-N bis(2-butoxyethyl)phthalate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1C(=O)OCCOCCCC CMCJNODIWQEOAI-UHFFFAOYSA-N 0.000 abstract 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 5
- 230000000379 polymerizing effect Effects 0.000 abstract 5
- 239000000945 filler Substances 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 3
- 239000000454 talc Substances 0.000 abstract 3
- 229910052623 talc Inorganic materials 0.000 abstract 3
- 239000004408 titanium dioxide Substances 0.000 abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 3
- 229920002554 vinyl polymer Polymers 0.000 abstract 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 229910000831 Steel Inorganic materials 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 239000004927 clay Substances 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 2
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 2
- 239000003973 paint Substances 0.000 abstract 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 2
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 2
- 239000011118 polyvinyl acetate Substances 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 239000010959 steel Substances 0.000 abstract 2
- 229920001897 terpolymer Polymers 0.000 abstract 2
- 229920005992 thermoplastic resin Polymers 0.000 abstract 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract 2
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical class ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 abstract 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001241 acetals Chemical class 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- 229910052570 clay Inorganic materials 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 150000001868 cobalt Chemical class 0.000 abstract 1
- 239000007799 cork Substances 0.000 abstract 1
- 239000004815 dispersion polymer Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000013013 elastic material Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- QJQZEJFUIOWFMS-UHFFFAOYSA-N formaldehyde;sulfanediol Chemical class O=C.OSO QJQZEJFUIOWFMS-UHFFFAOYSA-N 0.000 abstract 1
- 239000010438 granite Substances 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 239000010453 quartz Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
- 239000010455 vermiculite Substances 0.000 abstract 1
- 229910052902 vermiculite Inorganic materials 0.000 abstract 1
- 235000019354 vermiculite Nutrition 0.000 abstract 1
- 229920006163 vinyl copolymer Polymers 0.000 abstract 1
- 239000002023 wood Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
Surfaces, e.g. those of metal or glass, are coated with a composition comprising finely divided water-insoluble filler materials in a polymer emulsion produced by polymerizing in from 1 to 4 successive and substantially complete steps in the presence of a preformed dispersion of a thermoplastic resin a number of ethylenically unsaturated monomers, not more than three monomers being present in any one step and the monomeric material used in one step differing from that employed in any other step and from any monomeric precursors of the aqueous dispersion. The examples describe the application to steel plates of the following compositions: (1) a mixture of china clay and powdered mica in a dispersion obtained by polymerizing first styrene and then methyl methacrylate in a vinyl acetate/dioctyl maleate copolymer emulsion followed by the addition of di(butoxyethyl) phthalate thereto; (2) a mixture of china clay and powdered mica in a dispersion obtained by polymerizing first styrene and then methyl methacrylate in an emulsion of polyvinyl acetate which contains di(butoxyethyl) phthalate; (3) a composition as in (1) but with detail variations; and (4) china clay and powdered mica in a dispersion obtained by polymerizing a mixture of ethyl acrylate and acrylonitrile in an emulsion of a styrene/methyl methacrylate/dioctyl maleate terpolymer. The effect of the application of the foregoing compositions is to damp flexural vibrations in the steel plates. The compositions may also be used as emulsion paints, as in Example (5) in which a mixture of titanium dioxide, talc and woolastonite is added to the polymer dispersion described in Example (1) and the resulting composition applied to a glass plate. Other preformed polymers, monomers and fillers are listed (see Group IV(a)).ALSO:Coating compositions are produced by polymerizing in from 1 to 4 successive and substantially complete steps in the presence of an already preformed dispersion of at least one thermoplastic resin a number of ethylenically unsaturated monomers, not more than three different monomers being present in any polymerization step and the monomeric material employed on one step differing from that employed in any other step and from any monomeric precursors of the aqueous dispersion, and adding to the resulting dispersion comminuted substantially water-insoluble filler material. Preformed polymers specified are homopolymers of vinyl esters and copolymers with acrylic, methacrylic, maleic and fumaric esters and vinyl chloride, polystyrene, polyvinyl acetals and ketals and polyvinyl alkyl ketanes. Unsaturated monomers specified are styrene, acrylic and methacrylic esters, vinyl and vinylidene chlorides and vinyl esters. Fillers specified are clay, talc, mica, exfoliated vermiculite, comminuted granite and quartz asbestos fibres, woolastonite, titanium dioxide, wood, cork and thermosetting resins. Polymerization may be assisted by the use of initiators such as peroxides, hydroperoxides, e.g. cumene hydroperoxide, hydrogen peroxide, persulphates and azobisisobutyronitrile, and activators such as formaldehyde sulphoxylates, bisulphites, polyamines, tertiary amines and iron and cobalt salts. The examples describe: (1) the polymerization of styrene in an emulsion of a vinyl acetate/dioctyl maleate copolymer, followed by the further polymerization therein of methyl methacrylate and the addition to the resulting dispersion of di (butoxyethyl)phthalate and a mixture of clay and powdered mica; (2) the polymerization of styrene in an emulsion of polyvinyl acetate which contains di(butoxyethyl)phthalate, followed by the polymerization therein of methyl methacrylate and the addition to the resulting dispersion of a mixture of china clay and powdered mica; (3) a precess as in (1) but with detail variations; (4) the polymerization of a mixture of ethyl acrylate and acrylonitrile in an emulsion of a styrene/methyl methacrylate/dioctyl maleate terpolymer followed by the addition thereto of di(butoxyethyl) phthalate, china clay and powdered mica; and (5) the addition of titanium dioxide, talc, woolastonite and dibutyl phthalate to an emulsion prepared as in (1) to produce a paint. The products of Examples (11-14) are used for damping flexural vibrations in elastic materials.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB884958A GB893816A (en) | 1958-03-19 | 1958-03-19 | Improvements in or relating to synthetic resin emulsions and their production and to surface coatings and vibration damping compositions derived therefrom |
| DER25161A DE1110424B (en) | 1958-03-19 | 1959-03-17 | Process for the production of a polymer emulsion consisting of several components for the application of vibration-damping coatings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB884958A GB893816A (en) | 1958-03-19 | 1958-03-19 | Improvements in or relating to synthetic resin emulsions and their production and to surface coatings and vibration damping compositions derived therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB893816A true GB893816A (en) | 1962-04-11 |
Family
ID=9860415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB884958A Expired GB893816A (en) | 1958-03-19 | 1958-03-19 | Improvements in or relating to synthetic resin emulsions and their production and to surface coatings and vibration damping compositions derived therefrom |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1110424B (en) |
| GB (1) | GB893816A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119081490A (en) * | 2024-11-08 | 2024-12-06 | 安徽中梵科技有限公司 | A kind of water-based sound insulation and noise reduction coating and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1222678B (en) * | 1961-12-21 | 1966-08-11 | Monsanto Co | Process for the production of mixed polymer latices |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL98807C (en) * | 1955-11-15 |
-
1958
- 1958-03-19 GB GB884958A patent/GB893816A/en not_active Expired
-
1959
- 1959-03-17 DE DER25161A patent/DE1110424B/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119081490A (en) * | 2024-11-08 | 2024-12-06 | 安徽中梵科技有限公司 | A kind of water-based sound insulation and noise reduction coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1110424B (en) | 1961-07-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4183991A (en) | Process for preparing highly filled acrylic articles | |
| SE305193B (en) | ||
| GB802853A (en) | Polymerisable compositions and their production of polymer products therefrom | |
| GB1132267A (en) | Production of polymeric organic coatings by electrophoretic deposition | |
| GB926142A (en) | Production of graft copolymers | |
| US5478641A (en) | Latex containing copolymers having a plurality of activatable functional ester groups therein | |
| GB1109643A (en) | Interpolymers and coating compositions made therefrom | |
| GB1312098A (en) | Production of a copolymer and coating composition derived therefro | |
| GB1029566A (en) | Polymer compositions | |
| GB961043A (en) | Aqueous dispersion polymer compositions | |
| US3896073A (en) | Aqueous dispersions of film-forming | |
| GB1106717A (en) | Photographic materials | |
| GB893816A (en) | Improvements in or relating to synthetic resin emulsions and their production and to surface coatings and vibration damping compositions derived therefrom | |
| CA1191980A (en) | Stable latexes of carboxyl containing polymers | |
| GB889564A (en) | Production of aqueous dispersion of vinylidene chloride copolymers | |
| GB1101789A (en) | New polymers containing oxetane groups and process for their manufacture, and use | |
| GB751494A (en) | Modified polystyrene and styrene copolymer | |
| GB1415222A (en) | Process for producing methyl methacrylate resins | |
| US3847855A (en) | Water-borne latices | |
| GB934038A (en) | Polymer dispersions in organic liquid media and methods of preparation | |
| GB705887A (en) | ||
| US3351602A (en) | Film-forming acrylonitrile polymer and latex thereof | |
| US3630984A (en) | Latexes of vinyl cyclohexanecarboxylate polymers | |
| GB971843A (en) | Coated articles | |
| DE502004010637D1 (en) | Thermostabile vinylchlorid-mischpolymerisate |