GB899946A - Resinous poly-ª--olefines and their preparation - Google Patents
Resinous poly-ª--olefines and their preparationInfo
- Publication number
- GB899946A GB899946A GB1049159A GB1049159A GB899946A GB 899946 A GB899946 A GB 899946A GB 1049159 A GB1049159 A GB 1049159A GB 1049159 A GB1049159 A GB 1049159A GB 899946 A GB899946 A GB 899946A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alicyclic
- polymers
- monomers
- titanium
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 229920000642 polymer Polymers 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 abstract 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 2
- 125000002723 alicyclic group Chemical group 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- 125000002433 cyclopentenyl group Chemical group C1(=CCCC1)* 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- -1 methanol Chemical compound 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- ONQCKWIDZTZEJA-UHFFFAOYSA-N sodium;pentane Chemical compound [Na+].CCCC[CH2-] ONQCKWIDZTZEJA-UHFFFAOYSA-N 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 abstract 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Resinous olefin polymers are made from monomers having the general formula: CH2=CH-(CH2)nR wherein n is 1 or 2 and R is an alicyclic or unsaturated alicyclic group, containing from 5 to 9 carbon atoms. Monomers specified are various 4-alicyclic-1-butenes and 3-alicyclic-1-propenes, e.g. cyclohexyl, -pentyl and -pentadienyl derivatives. The monomers are polymerized at 20 DEG -250 DEG C. using a catalyst comprising a Ti, Cr, V, Zr or Mo halide and an alkyl of a metal of Group I, II or III of the Periodic Table. Catalyst components specified are titanium tri- and tetrachloride, titanium diethoxy dichloride, vanadium tetrachloride, molybdenum pentachloride, triethylaluminium, ethylmagnesium bromide, amylsodium and butyllithium. The polymerization is preferably carried out at raised pressures and under an inert atmosphere, e.g. nitrogen, and in an inert organic solvent, e.g. pentane, hexane, heptane or higher alkanes. The polymer may be separated after the reaction by pouring into a lower alcohol, e.g. methanol, and may be washed with acidified methanol and water. The polymers can be dissolved, e.g. in hot tetralin, to form viscous dopes which can be spun into fibres and filaments which may be stretched and the polymers can also be extruded into sheets and films, e.g. photographic film supports, and may be moulded. Certain polymers which contain unsaturated substituents, e.g. cyclohexenyl, cyclopentenyl or cyclopentadienyl groups can be obtained in rubbery form, especially by using a dialkoxy titanium dichloride as a catalyst component, and these may then be cross-linked.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US72480558A | 1958-03-31 | 1958-03-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB899946A true GB899946A (en) | 1962-06-27 |
Family
ID=24911987
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1049159A Expired GB899946A (en) | 1958-03-31 | 1959-03-26 | Resinous poly-ª--olefines and their preparation |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1117308B (en) |
| FR (1) | FR1221437A (en) |
| GB (1) | GB899946A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589182A (en) * | 2015-10-14 | 2017-04-26 | 中国石油化工股份有限公司 | Polymer with syndiotactic structure, and preparation method thereof |
| US9902695B1 (en) | 2016-12-16 | 2018-02-27 | Novoset Llc | Resin compositions |
| US11685808B2 (en) | 2020-06-11 | 2023-06-27 | Novoset, Llc | Oligomer resin compositions |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL111136C (en) * | 1954-12-03 |
-
1959
- 1959-03-18 DE DEE17327A patent/DE1117308B/en active Pending
- 1959-03-26 GB GB1049159A patent/GB899946A/en not_active Expired
- 1959-03-27 FR FR790621A patent/FR1221437A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106589182A (en) * | 2015-10-14 | 2017-04-26 | 中国石油化工股份有限公司 | Polymer with syndiotactic structure, and preparation method thereof |
| CN106589182B (en) * | 2015-10-14 | 2019-12-24 | 中国石油化工股份有限公司 | Polymer with syndiotactic structure and preparation method thereof |
| US9902695B1 (en) | 2016-12-16 | 2018-02-27 | Novoset Llc | Resin compositions |
| WO2018111337A1 (en) * | 2016-12-16 | 2018-06-21 | Novoset, Llc | Resin compositions |
| US10358418B2 (en) | 2016-12-16 | 2019-07-23 | Novoset, Llc | Resin compositions |
| CN110099932A (en) * | 2016-12-16 | 2019-08-06 | 诺佛赛特有限责任公司 | Resin combination |
| US11685808B2 (en) | 2020-06-11 | 2023-06-27 | Novoset, Llc | Oligomer resin compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1221437A (en) | 1960-06-01 |
| DE1117308B (en) | 1961-11-16 |
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