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GB898796A - Improvements in the sulphonation of hydrocarbon oils - Google Patents

Improvements in the sulphonation of hydrocarbon oils

Info

Publication number
GB898796A
GB898796A GB36045/58A GB3604558A GB898796A GB 898796 A GB898796 A GB 898796A GB 36045/58 A GB36045/58 A GB 36045/58A GB 3604558 A GB3604558 A GB 3604558A GB 898796 A GB898796 A GB 898796A
Authority
GB
United Kingdom
Prior art keywords
oil
members
gas
apertures
discs
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36045/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sonneborn Chemical and Refining Corp
Original Assignee
Sonneborn Chemical and Refining Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sonneborn Chemical and Refining Corp filed Critical Sonneborn Chemical and Refining Corp
Publication of GB898796A publication Critical patent/GB898796A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
    • B01F27/73—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with rotary discs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/60—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis
    • B01F27/74—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a horizontal or inclined axis with rotary cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/006—Baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B45/00—Formation or introduction of functional groups containing sulfur
    • C07B45/02—Formation or introduction of functional groups containing sulfur of sulfo or sulfonyldioxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
    • C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00083—Coils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00189—Controlling or regulating processes controlling the stirring velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/182—Details relating to the spatial orientation of the reactor horizontal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

<PICT:0898796/III/1> <PICT:0898796/III/2> Gas-liquid reactor for use in the sulphonation of hydrocarbon oils with an SO3-containing gas (see Group IV(b)) comprises (Fig. 1) a container 1 having therein a plurality of substantially parallel spaced apart members 8 rotatable about a substantially horizontal axis by a shaft 7, the members each having a portion thereof dipping in a body of the oil in the lower part of the container and each having apertures formed therein and/or being so p spaced apart that on rotation an oil film is formed across those apertures and/or spaces between the members which are out of contact with the oil. The gas is forced through those apertures in and/or the spaces between the members 8 which carry the oil film. The apertured rotatable members may be perforated discs or cylinders, concentrically disposed ring segments, impellers, propellers, discs apertured to form spokes or a plurality of concentric rings. The rotatable members may also be in the form of a plurality of concentric imperforate cylinders. As shown, the members 8 are expanded metal discs which may be provided with heating or cooling coils (Fig. 4) and scraper bars 9. Other forms of members rotatable by shaft 7 are illustrated including a nest of wire mesh cylinders mounted concentrically on the shaft. The apparatus can be of non-uniform circular cross-section. The apparatus may be used with co-current flow, gas and liquid inlets 10, 12 being provided at one end and a gas outlet 11 and a liquid overflow being provided at the other end, or if desired, the apparatus may be adapted for counter-current flow of the gas and liquid. Examples describe sulphonations with air containing SO3 in the above apparatus wherein (1) a partially acid-treated heavy coastal petroleum distillate is sulphonated and the emergent oil stream is neutralized and the sulphonates therein are extracted; (2) the oil recovered from (1) is resulphonated to provide a heavy medicinal white oil; (3) a solvent treated coastal oil distillate is similarly sulphonated.ALSO:<PICT:0898796/IV (b)/1> Hydrocarbon oils are sulphonated by an SO3-containing gas, the method comprising so rotating about a substantially horizontal axis a plurality of substantially parallel spaced-apart members in a container with a lower portion of each member dipping into a body of the oil therein (the members having apertures formed therein and/or being so spaced apart that, on rotation, an oil film is formed across these apertures and/or spaces between the members which are out of contact with the oil) that, at any instant, only a portion of the effective area of apertures and/or spaces is in contact with the oil but after completion of one rotation substantially the whole of the effective area of apertures and/or spaces has been immersed and forcing the SO3-containing gas through the apertures in and/or spaces between the members which carry the oil film. The apertured rotatable members may be perforated discs or cylinders, concentrically disposed ring segments, impellers, propellers, discs apertured to form spokes or a plurality of concentric rings. The rotable members may also be in the form of a plurality of concentric imperforate cylinders. Suitable apparatus comprises a jacketed cylindrical container 1 (see Fig. 1) through which extends axially a rotable shaft 7 carrying perforated discs 8 of a diameter substantially that of the container. The discs may be provided with heating or cooling means and scraper bars 9. The SO3 gas and hydrocarbon oil are introduced via inlets 10, 12 at one end and at the other end are provided a gas outlet 11 and a liquid overflow. If desired, counter-current flow of gas and liquid may be used. The apparatus need not be of uniform circular cross-section. The discs shown are of expanded metal. Other forms are illustrated including a nest of wire mesh cylinders mounted concentrically on shaft 7. Examples describe sulphonations with air containing SO3 using the above apparatus wherein (1) a partially acid treated petroleum distillate is sulphonated and the emergent oil stream is neutralised and extracted to recover petroleum sulphonates (6.0 vol. per cent.) therefrom; (2) the residual oil is resulphonated as in (1) leaving a purified white oil; (3) a solvent treated Coastal oil distillate is similarly sulphonated.
GB36045/58A 1958-01-09 1958-11-10 Improvements in the sulphonation of hydrocarbon oils Expired GB898796A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70794158A 1958-01-09 1958-01-09

Publications (1)

Publication Number Publication Date
GB898796A true GB898796A (en) 1962-06-14

Family

ID=24843766

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36045/58A Expired GB898796A (en) 1958-01-09 1958-11-10 Improvements in the sulphonation of hydrocarbon oils

Country Status (3)

Country Link
DE (1) DE1138392B (en)
FR (1) FR1273876A (en)
GB (1) GB898796A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2716356A4 (en) * 2011-05-27 2015-01-07 Lg Chemical Ltd METHOD FOR REMOVING NON-REAGENT MONOMER FROM A POLYMER USING A ROTATING CONE COLUMN
EP2716357A4 (en) * 2011-05-27 2015-01-14 Lg Chemical Ltd COLUMN OF ROTATING CONES FOR ENHANCING THE MOBILITY OF AN OBJECT TO BE REMOVED
CN109265376A (en) * 2018-10-22 2019-01-25 中石油克拉玛依石化有限责任公司 The method and device of continous way production petroleum sulfonate

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE306083B (en) * 1963-11-04 1968-11-18 Mo Och Domsjoe Ab
CA998825A (en) * 1972-08-30 1976-10-26 Allied Chemical Corporation Process and apparatus for reacting a thin liquid film with a gas
DE59505196D1 (en) * 1994-12-30 1999-04-08 Fischer Karl Ind Gmbh Reactor device for flowable and highly viscous media

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE571124C (en) * 1930-03-25 1933-02-24 H Th Boehme Akt Ges Device for the sulfonation of organic compounds

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2716356A4 (en) * 2011-05-27 2015-01-07 Lg Chemical Ltd METHOD FOR REMOVING NON-REAGENT MONOMER FROM A POLYMER USING A ROTATING CONE COLUMN
EP2716357A4 (en) * 2011-05-27 2015-01-14 Lg Chemical Ltd COLUMN OF ROTATING CONES FOR ENHANCING THE MOBILITY OF AN OBJECT TO BE REMOVED
US9018346B2 (en) 2011-05-27 2015-04-28 Lg Chem, Ltd. Method for removing unreacted monomers in polymer using SCC
US9162210B2 (en) 2011-05-27 2015-10-20 Lg Chem, Ltd. SCC with improvied mobility of material to be removed
CN109265376A (en) * 2018-10-22 2019-01-25 中石油克拉玛依石化有限责任公司 The method and device of continous way production petroleum sulfonate
CN109265376B (en) * 2018-10-22 2021-07-02 克拉玛依市先进能源技术创新有限公司 Method and device for continuously producing petroleum sulfonate

Also Published As

Publication number Publication date
DE1138392B (en) 1962-10-25
FR1273876A (en) 1961-10-20

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