GB896814A - New acylating agents and process for their manufacture - Google Patents
New acylating agents and process for their manufactureInfo
- Publication number
- GB896814A GB896814A GB5685/60A GB568560A GB896814A GB 896814 A GB896814 A GB 896814A GB 5685/60 A GB5685/60 A GB 5685/60A GB 568560 A GB568560 A GB 568560A GB 896814 A GB896814 A GB 896814A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mono
- metal
- acid
- aqueous
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 10
- 229910052751 metal Inorganic materials 0.000 abstract 8
- 239000002184 metal Substances 0.000 abstract 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 6
- -1 chloride or bromide Chemical class 0.000 abstract 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical class OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 abstract 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical class [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000005470 impregnation Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000006193 liquid solution Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 239000004627 regenerated cellulose Substances 0.000 abstract 1
- 238000005185 salting out Methods 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Catalysts (AREA)
Abstract
896,814. Mono-metal salts of cyanuric acid monohalides. CIBA Ltd. Feb. 17, 1960 [Feb. 18, 1959], No. 5685/60. Class 1(2) [Also in Groups IV(a), IV(c) and VIII] A water-soluble mono-metal salt of a 6- halogen - 2:4 - dihydroxy - 1:3:5 - triazine (cyanuric acid monohalide) is prepared by reacting a cyanuric halide, e.g. chloride or bromide, with a water-soluble metal salt of an acid weaker than formic acid, or a hydroxide or an oxide of a metal to form a dimetal salt of cyanuric acid monohalide and neutralizing the dimetal salt with an acid, e.g. HCI. Alternatively, the cyanuric halide and the metal compound are reacted in the correct molecular ratio to form the mono-metal salt directly. Alkali or alkaline earth metal hydroxides or: carbonates may be used, e.g. LiOH, NaOH, or KOH, and the first stage of the two-stage process may be carried out in two stages, by reacting first with weak alkali, e.g. NaHCO 3 , and secondly with strong alkali, e.g. NaOH. The reaction may be effected in aqueous or aqueous-organic liquid (e.g. aqueous acetone) media. The mono-metal salt may be isolated as solid by filtering with, or without, addition of a salting- out agent, e.g. NaCl, or by evaporating, e.g. under reduced pressure at 40‹-80‹C, The mono-alkali metal salts may be reacted with water-soluble salts, e.g. chloride or sulphate, of nickel, cobalt, or copper, or alkaline earth metal, e.g. magnesium, calcium, or barium, to form the corresponding mono-metal salts. Polyhydroxylated fibrous materials, e.g. polyvinyl alcohol, cellulose, regenerated cellulose, linen, or cotton, may be acylated by impregnation with aqueous or aqueous-organic liquid solutions of the mono-metal salts to improve swelling capacity, wet crease resistance, dyestuff affinity, and pest and rot resistance. The solutions may contain buffer agents, e.g. mono- or di-sodium phosphates or alkali metal borates, acid-binding agents, e.g. alkali metal hydroxide, carbonate, or bicarbonate, electrolytes, e.g. NaCl, or Na 2 SO 4 , or non-electrolytes, e.g. urea, or the impregnated material may be subsequently steamed, or subjected to dry heat, in the presence of these agents.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH6973759A CH373048A (en) | 1959-02-18 | 1959-02-18 | Process for the production of new metal compounds |
| CH995360A CH370384A (en) | 1959-10-01 | 1959-10-01 | Process for the finishing of textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB896814A true GB896814A (en) | 1962-05-16 |
Family
ID=31979210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5685/60A Expired GB896814A (en) | 1959-02-18 | 1960-02-17 | New acylating agents and process for their manufacture |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB896814A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0616071A1 (en) * | 1993-03-13 | 1994-09-21 | Pfersee Chemie GmbH | Process for the treatment of fibrous materials with triazin derivatives |
| EP0903434A1 (en) * | 1997-09-17 | 1999-03-24 | Ciba SC Holding AG | Process for the treatment of cellulosic fibres |
| WO1999019555A1 (en) * | 1997-10-15 | 1999-04-22 | Lenzing Aktiengesellschaft | Method for treating cellulosic shaped bodies |
| TR199801842A3 (en) * | 1997-09-17 | 1999-10-21 | Ciba Specialty Chemicals Holding Inc. | Processing method of cellulose fibers. |
| JP2005508458A (en) * | 2001-11-09 | 2005-03-31 | デグサ アクチエンゲゼルシャフト | Method for flameproofing cellulose fibers |
| DE102005018500A1 (en) * | 2005-04-21 | 2006-10-26 | Degussa Ag | Process for the preparation of salts of dihydroxychlorotriazine |
| DE102007014272A1 (en) | 2007-03-26 | 2008-10-02 | Evonik Degussa Gmbh | Process for the flameproofing of cotton |
-
1960
- 1960-02-17 GB GB5685/60A patent/GB896814A/en not_active Expired
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0616071A1 (en) * | 1993-03-13 | 1994-09-21 | Pfersee Chemie GmbH | Process for the treatment of fibrous materials with triazin derivatives |
| EP0903434A1 (en) * | 1997-09-17 | 1999-03-24 | Ciba SC Holding AG | Process for the treatment of cellulosic fibres |
| TR199801842A3 (en) * | 1997-09-17 | 1999-10-21 | Ciba Specialty Chemicals Holding Inc. | Processing method of cellulose fibers. |
| US6033443A (en) * | 1997-09-17 | 2000-03-07 | Ciba Specialty Chemicals Corporation | Process for treating cellulose fibres |
| WO1999019555A1 (en) * | 1997-10-15 | 1999-04-22 | Lenzing Aktiengesellschaft | Method for treating cellulosic shaped bodies |
| US6241933B1 (en) | 1997-10-15 | 2001-06-05 | Lenzing Aktiengesellschaft | Process for the treatment of cellulosic moulded bodies |
| JP2005508458A (en) * | 2001-11-09 | 2005-03-31 | デグサ アクチエンゲゼルシャフト | Method for flameproofing cellulose fibers |
| DE102005018500A1 (en) * | 2005-04-21 | 2006-10-26 | Degussa Ag | Process for the preparation of salts of dihydroxychlorotriazine |
| DE102007014272A1 (en) | 2007-03-26 | 2008-10-02 | Evonik Degussa Gmbh | Process for the flameproofing of cotton |
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