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GB870949A - Process of manufacture of ferrocene derivatives - Google Patents

Process of manufacture of ferrocene derivatives

Info

Publication number
GB870949A
GB870949A GB4068558A GB4068558A GB870949A GB 870949 A GB870949 A GB 870949A GB 4068558 A GB4068558 A GB 4068558A GB 4068558 A GB4068558 A GB 4068558A GB 870949 A GB870949 A GB 870949A
Authority
GB
United Kingdom
Prior art keywords
derivative
formula
ferrocene derivatives
anhydrous iron
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4068558A
Inventor
Thomas Leigh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB4068558A priority Critical patent/GB870949A/en
Priority to FR812448A priority patent/FR1444659A/en
Priority to DEI17344A priority patent/DE1116225B/en
Priority to CH8193959A priority patent/CH377048A/en
Publication of GB870949A publication Critical patent/GB870949A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)

Abstract

Ferrocene derivatives of formula: <FORM:0870949/IV (b)/1> wherein R1 stands for hydrogen or an alkyl radical, and R11 and R111, which may be the same or different, stand for alkyl radicals are made by reacting a cyclopentadiene derivative of formula: <FORM:0870949/IV (b)/2> wherein R1, R11 and R111 have the meanings above with an anhydrous iron halide in the presence of a strong organic base, or b) interaction of a metal derivative of the said cyclopentadiene compound and an anhydrous iron halide. The mutual derivative may be an alkali metal derivative or a magnesium halide derivative. The process is preferably carried out in an inert solvent e.g. tetrahydrofuran or toluene, and at a temperature between 0 DEG and 30 DEG C. Suitable organic basis specified are piperidine and diethylamine. The preparation of 1:11-dineopentylferrocene is described.
GB4068558A 1958-12-17 1958-12-17 Process of manufacture of ferrocene derivatives Expired GB870949A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB4068558A GB870949A (en) 1958-12-17 1958-12-17 Process of manufacture of ferrocene derivatives
FR812448A FR1444659A (en) 1958-12-17 1959-12-08 Process for the manufacture of ferrocene derivatives such as 1: 1'-dineopentylferrocene
DEI17344A DE1116225B (en) 1958-12-17 1959-12-10 Process for the production of ferrocene derivatives
CH8193959A CH377048A (en) 1958-12-17 1959-12-16 Process for the production of ferrocene derivatives

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4068558A GB870949A (en) 1958-12-17 1958-12-17 Process of manufacture of ferrocene derivatives

Publications (1)

Publication Number Publication Date
GB870949A true GB870949A (en) 1961-06-21

Family

ID=10416117

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4068558A Expired GB870949A (en) 1958-12-17 1958-12-17 Process of manufacture of ferrocene derivatives

Country Status (3)

Country Link
CH (1) CH377048A (en)
DE (1) DE1116225B (en)
GB (1) GB870949A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL278556A (en) * 1961-05-19

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1083936A (en) * 1952-10-01 1955-01-13 Du Pont Process for manufacturing cyclopentadienyl compounds
US3071605A (en) * 1955-02-15 1963-01-01 Union Carbide Corp Process for producing cyclopentadienyl-type metallic compounds

Also Published As

Publication number Publication date
CH377048A (en) 1964-04-30
DE1116225B (en) 1961-11-02

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