GB856403A - Improvements in or relating to polymers with organic solvent and water solubility - Google Patents
Improvements in or relating to polymers with organic solvent and water solubilityInfo
- Publication number
- GB856403A GB856403A GB21321/59A GB2132159A GB856403A GB 856403 A GB856403 A GB 856403A GB 21321/59 A GB21321/59 A GB 21321/59A GB 2132159 A GB2132159 A GB 2132159A GB 856403 A GB856403 A GB 856403A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methyl
- amino
- propanediol
- dimethylamino
- propanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Dispersion Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Cosmetics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Copolymers of vinyl acetate and crotonic acid are modified to render them soluble in water and in organic solvents by reacting them with an aminohydroxy compound having a boiling point above 160 DEG C. at atmospheric pressure and a molecular weight above 85. The aminohydroxy compounds may be: 2-amino-2 methyl-1, 3-propanediol; 2-amino-2-ethyl-1, 3-propanediol; 2-amino-2-methyl-1-propanol; tris (hydroxymethyl)-aminoethane; 1-amino-2-methyl-2- propanol; 3-amino-2-pentanol; 2-amino-1-phenyl-1-butanol; 2-dimethylamino-2-methyl-1-propanol; N1-(2-hydroxyethyl)-2-methyl-1, 2-propanediamine; tris (hydroxymethyl) dimethyl-methane 2-amino-1-butanol; 2-amino-2-methyl-3-pentanol; 2-amino-1-phenyl-1-propanol; 2-dimethylamino-2-methyl-1, 3 propanediol; 2-dimethylamino-2-ethyl-1, 3 propanediol; N1-(2-hydroxypropyl)-2-methyl-1, 2-propane diamine; 2-dimethylamino-2-methyl-1, 3-propanediol. The reaction may be effected in a solvent, especially ethyl alcohol, although acetone, methyl acetate, ethyl acetate, isopropanol or methyl ethyl ketone may be used. The modified copolymers may be used as adhesives, and in solution together with a halogenated hydrocarbon aerosol propellant, e.g. monofluorotrichloromethane, as a hair spray lacquer.ALSO:Hair spray lacquers are obtained by adding a halogenated hydrocarbon aerosol propellant to a copolymer of vinyl acetate and crotonic acid which has been modified by reaction with an aminohydroxy compound having a boiling point above 160 DEG C. at atmospheric pressure and a molecular weight above 85 (see Group IV(a)). The aminohydroxy compounds may be 2-amino-2 methyl - 1,3 - propanediol; 2 - amino 2 - ethyl-1,3 - propanediol; 2 - amino; 2 methyl; 1-propanol; tris (hydroxymethyl) - aminoethane; 1 - amino - 2 - methyl - 2 - propanol; 3 - amino-2 - pentanol; 2 - amino - 1 - phenyl - 1 - butanol; 2 - dimethylamino - 2 - methyl - 1 - propanol; N1 - (2 - hydroxyethyl) - 2 - methyl - 1,2 - propane diamine; tris (hydroxymethyl) dimethylaminomethane; 2 - amino - 1 - butanol; 2 - amino-2 - methyl - 3 - pentanol; 2 - amino - 1 phenyl-1 - propanol; 2 - dimethylamino - 2 - methyl-1,3, propanediol; 2 - dimethylamino - 2 - ethyl-1,3, propanediol; N1 - (2 - hydroxypropyl)-2 - methyl - 1,2 - propane diamine; and 2-dimethylamino - 2 - methyl - 1,3 - propanediol. Ethanol may also be added.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US856403XA | 1958-06-23 | 1958-06-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB856403A true GB856403A (en) | 1960-12-14 |
Family
ID=22192972
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21321/59A Expired GB856403A (en) | 1958-06-23 | 1959-06-22 | Improvements in or relating to polymers with organic solvent and water solubility |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB856403A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3182047A (en) * | 1961-06-02 | 1965-05-04 | Commerical Solvents Corp | Amino alcohol modified polyacrylates |
| DE2022264A1 (en) * | 1969-05-09 | 1970-11-19 | Oreal | New cosmetic products and new copolymers |
| GB2190393A (en) * | 1986-05-16 | 1987-11-18 | Oreal | Use of partially acetylated polyvinyl alcohol as a foaming agent in compositions in the form of aerosols |
-
1959
- 1959-06-22 GB GB21321/59A patent/GB856403A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3182047A (en) * | 1961-06-02 | 1965-05-04 | Commerical Solvents Corp | Amino alcohol modified polyacrylates |
| DE2022264A1 (en) * | 1969-05-09 | 1970-11-19 | Oreal | New cosmetic products and new copolymers |
| GB2190393A (en) * | 1986-05-16 | 1987-11-18 | Oreal | Use of partially acetylated polyvinyl alcohol as a foaming agent in compositions in the form of aerosols |
| US4880618A (en) * | 1986-05-16 | 1989-11-14 | L'oreal | Use of partially acetylated polyvinyl alcohol as a foaming agent in compositions in the form of aerosols |
| GB2190393B (en) * | 1986-05-16 | 1990-05-02 | Oreal | Use of partially acetylated polyvinyl alcohol as a foaming agent in compositions in the form of aerosols |
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