GB854191A - Improvements in or relating to the production of resinous compositions - Google Patents
Improvements in or relating to the production of resinous compositionsInfo
- Publication number
- GB854191A GB854191A GB373258A GB373258A GB854191A GB 854191 A GB854191 A GB 854191A GB 373258 A GB373258 A GB 373258A GB 373258 A GB373258 A GB 373258A GB 854191 A GB854191 A GB 854191A
- Authority
- GB
- United Kingdom
- Prior art keywords
- emulsion
- weight
- vinyl acetate
- polyvinyl acetate
- plasticizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title 1
- 239000000839 emulsion Substances 0.000 abstract 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 3
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 3
- 239000011118 polyvinyl acetate Substances 0.000 abstract 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 2
- 239000004160 Ammonium persulphate Substances 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 2
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 2
- 239000000084 colloidal system Substances 0.000 abstract 2
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 abstract 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 abstract 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 230000001681 protective effect Effects 0.000 abstract 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 abstract 1
- 229920001817 Agar Polymers 0.000 abstract 1
- 241000416162 Astragalus gummifer Species 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 abstract 1
- 241000206672 Gelidium Species 0.000 abstract 1
- 229920000084 Gum arabic Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 241000978776 Senegalia senegal Species 0.000 abstract 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 abstract 1
- 229920001615 Tragacanth Polymers 0.000 abstract 1
- YYQRGCZGSFRBAM-UHFFFAOYSA-N Triclofos Chemical compound OP(O)(=O)OCC(Cl)(Cl)Cl YYQRGCZGSFRBAM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000205 acacia gum Substances 0.000 abstract 1
- 235000010489 acacia gum Nutrition 0.000 abstract 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 abstract 1
- 235000010419 agar Nutrition 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- VFGRALUHHHDIQI-UHFFFAOYSA-N butyl 2-hydroxyacetate Chemical compound CCCCOC(=O)CO VFGRALUHHHDIQI-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 125000001557 phthalyl group Chemical group C(=O)(O)C1=C(C(=O)*)C=CC=C1 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 abstract 1
- 235000010263 potassium metabisulphite Nutrition 0.000 abstract 1
- 239000004297 potassium metabisulphite Substances 0.000 abstract 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 abstract 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- 229960001147 triclofos Drugs 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F18/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F18/02—Esters of monocarboxylic acids
- C08F18/04—Vinyl esters
- C08F18/08—Vinyl acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polyvinyl acetate emulsions are obtained by catalytically polymerizing vinyl acetate by starting the polymerization in an emulsion containing (a) at least 2,2% by weight, based on the weight of the final emulsion, of a protective colloid and (b) from 0,5 to 2,5% of a plasticizer for polyvinyl acetate and then adding vinyl acetate slowly to the emulsion, the amount of vinyl acetate in the emulsion being kept at a concentration not greater than 15% by weight, based on the weight of the emulsion. The protective colloid may be a hydroxyethyl cellulose, sodium carboxy methyl cellulose, methyl cellulose, benzyl cellulose, gum arabic, gum tragacanth or agar-agar, or a hydrolysed or partially hydrolysed polyvinyl acetate. The plasticizer may be dibutyl phthalate, diethylphthalate, tricresyl phosphate, trichloroethyl phosphate, triethylene glycol dihexoate, dibutyl sebacate or butyl phthalyl butyl glycollate. The polymerization catalyst may be hydrogen peroxide, benzoyl peroxide, acetyl peroxide, ammonium persulphate, sodium perborate, the ammonium persulphate and potassium metabisulphite redox system or azo-bis-iso-butyronitrile. Specifications 511,036, 641,653 and 658,426 are referred to.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB373258A GB854191A (en) | 1958-02-05 | 1958-02-05 | Improvements in or relating to the production of resinous compositions |
| BE575427A BE575427A (en) | 1958-02-05 | 1959-02-05 | Improvements in the production of resinous compounds. |
| FR785883A FR1216044A (en) | 1958-02-05 | 1959-02-05 | Polyvinyl acetate production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB373258A GB854191A (en) | 1958-02-05 | 1958-02-05 | Improvements in or relating to the production of resinous compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB854191A true GB854191A (en) | 1960-11-16 |
Family
ID=9763911
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB373258A Expired GB854191A (en) | 1958-02-05 | 1958-02-05 | Improvements in or relating to the production of resinous compositions |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE575427A (en) |
| FR (1) | FR1216044A (en) |
| GB (1) | GB854191A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4350788A (en) * | 1980-09-26 | 1982-09-21 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Synthetic resin emulsion and its uses |
| EP0133899A3 (en) * | 1983-07-01 | 1985-05-22 | Wacker-Chemie Gmbh | Process for preparing aqueous polymer dispersions, and their use |
| EP0134449A3 (en) * | 1983-07-01 | 1985-05-29 | Wacker-Chemie Gmbh | Process for preparing aqueous polymer dispersions, and their use |
| EP0134450A3 (en) * | 1983-07-01 | 1985-05-29 | Wacker-Chemie Gmbh | Process for preparing aqueous polymer dispersions, and their use |
| EP0134451A3 (en) * | 1983-07-01 | 1985-06-12 | Wacker-Chemie Gmbh | Process for preparing redispersable powder based on dispersions stabilised with natural substances as protective colloids |
| EP0603746A1 (en) * | 1992-12-17 | 1994-06-29 | Wacker-Chemie GmbH | Aqueous biodegradable dispersions |
-
1958
- 1958-02-05 GB GB373258A patent/GB854191A/en not_active Expired
-
1959
- 1959-02-05 BE BE575427A patent/BE575427A/en unknown
- 1959-02-05 FR FR785883A patent/FR1216044A/en not_active Expired
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4350788A (en) * | 1980-09-26 | 1982-09-21 | Nippon Gohsei Kagaku Kogyo Kabushiki Kaisha | Synthetic resin emulsion and its uses |
| EP0133899A3 (en) * | 1983-07-01 | 1985-05-22 | Wacker-Chemie Gmbh | Process for preparing aqueous polymer dispersions, and their use |
| EP0134449A3 (en) * | 1983-07-01 | 1985-05-29 | Wacker-Chemie Gmbh | Process for preparing aqueous polymer dispersions, and their use |
| EP0134450A3 (en) * | 1983-07-01 | 1985-05-29 | Wacker-Chemie Gmbh | Process for preparing aqueous polymer dispersions, and their use |
| EP0134451A3 (en) * | 1983-07-01 | 1985-06-12 | Wacker-Chemie Gmbh | Process for preparing redispersable powder based on dispersions stabilised with natural substances as protective colloids |
| EP0603746A1 (en) * | 1992-12-17 | 1994-06-29 | Wacker-Chemie GmbH | Aqueous biodegradable dispersions |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1216044A (en) | 1960-04-21 |
| BE575427A (en) | 1959-05-29 |
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