GB845021A - Improvements in or relating to sulphonium compounds - Google Patents
Improvements in or relating to sulphonium compoundsInfo
- Publication number
- GB845021A GB845021A GB1037257A GB1037257A GB845021A GB 845021 A GB845021 A GB 845021A GB 1037257 A GB1037257 A GB 1037257A GB 1037257 A GB1037257 A GB 1037257A GB 845021 A GB845021 A GB 845021A
- Authority
- GB
- United Kingdom
- Prior art keywords
- salt
- appropriate
- heterocyclic
- alkylthioalkyl
- ethanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 4
- -1 alkane thiol Chemical class 0.000 abstract 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 abstract 3
- 150000001450 anions Chemical class 0.000 abstract 3
- 150000003839 salts Chemical group 0.000 abstract 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 159000000000 sodium salts Chemical class 0.000 abstract 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract 1
- 229940095064 tartrate Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
- C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
- C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention comprises compounds of the formula: <FORM:0845021/IV(b)/1> (wherein R, R1 and R2 are the same or different alkyl groups each having 1 to 4 carbon atoms, n is 4, 5 or 6, R3 and R4 together with the nitrogen atom form a piperidine, pyrrolidine or morpholine ring and X- is a monovalent anion or 2X- is the divalent anion of a dibasic acid) and their preparation by treating the appropriate N-(alkylthioalkyl)-heterocyclic compound or a monoalkyl quaternary salt thereof with a suitable quaternizing agent, particularly an alkyl halide, conveniently in a solvent such as p acetone or ethanol. The invention also comprises the preparation of the N-(alkylthioalkyl)-heterocyclic compounds by the reaction of a hydrohalide salt of an appropriate N-haloalkyl heterocyclic compound with a metal salt e.g. a sodium salt, of an alkane thiol, conveniently in a solvent such as ethanol. Anions referred to are the chloride, bromide, iodide, citrate and tartrate ions, the organic acid salts being advantageously prepared by treating the halide salts with a silver salt of the appropriate organic acid or alternatively, with the free acid in presence of ethylene oxide. Examples are given. In the Provisional Specification R3, R4 and the adjacent nitrogen atom are defined as a heterocyclic ring system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1037257A GB845021A (en) | 1957-03-29 | 1957-03-29 | Improvements in or relating to sulphonium compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1037257A GB845021A (en) | 1957-03-29 | 1957-03-29 | Improvements in or relating to sulphonium compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB845021A true GB845021A (en) | 1960-08-17 |
Family
ID=9966631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1037257A Expired GB845021A (en) | 1957-03-29 | 1957-03-29 | Improvements in or relating to sulphonium compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB845021A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5416210A (en) * | 1991-01-03 | 1995-05-16 | Rohm And Haas Company | Antimicrobial polymeric quaternary ammonium salts |
| WO2005087753A1 (en) * | 2004-03-10 | 2005-09-22 | Wako Pure Chemical Industries, Ltd. | Reagent for reaction |
-
1957
- 1957-03-29 GB GB1037257A patent/GB845021A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5416210A (en) * | 1991-01-03 | 1995-05-16 | Rohm And Haas Company | Antimicrobial polymeric quaternary ammonium salts |
| WO2005087753A1 (en) * | 2004-03-10 | 2005-09-22 | Wako Pure Chemical Industries, Ltd. | Reagent for reaction |
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