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GB836755A - Improvements in and relating to polymers - Google Patents

Improvements in and relating to polymers

Info

Publication number
GB836755A
GB836755A GB27282/58A GB2728258A GB836755A GB 836755 A GB836755 A GB 836755A GB 27282/58 A GB27282/58 A GB 27282/58A GB 2728258 A GB2728258 A GB 2728258A GB 836755 A GB836755 A GB 836755A
Authority
GB
United Kingdom
Prior art keywords
silane
interpolymer
tetravinyl
peroxide
tetraallyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB27282/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodrich Corp
Original Assignee
BF Goodrich Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BF Goodrich Corp filed Critical BF Goodrich Corp
Publication of GB836755A publication Critical patent/GB836755A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/04—Acids, Metal salts or ammonium salts thereof
    • C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

An interpolymer is prepared from a mixture of (1) at least 10% by weight of a monomeric, polymerizable alpha-beta olefinically unsaturated aliphatic carboxylic acid or anhydride thereof, with optionally up to 90% by weight of a different olefinically unsaturated monomer, and (2) from 0.0005 to 6% by weight of the other monomers of a poly-alkenyl compound of formula (Y)4-n-M-(R)n where R is an alkenyl group of 2 to 4 carbon atoms with terminal unsaturation and Y is an hydrocarbon group of 1 to 10 carbon atoms having no olefinic unsaturation, n is 2, 3 or 4, and M is silicon, germanium, tin or lead. The carboxylic acid monomer may be an acrylic or maleic acid or anhydride, which may be substituted, or an homologue thereof. The optional monomer may be styrene, a halo or alkoxy styrene, acrylamide, methacrylamide or an alkylacrylamide, acrylonitrile or methacrylonitrile, an alkyl acrylate or methacrylate, a vinyl halide, a vinylidene cyanide or halide, vinyl acetate, propionate, butyrate, benzoate, pyridine, carbazole, pyrrolidone, piperidine or pyrimidine, isopropenyl acetate, propionate, butyrate or benzoate, an alkyl vinyl ketone, an alkyl isopropenyl ketone, an alkyl vinyl ether, ethylene, isobutylene, or a dialkyl maleate or fumarate. The monomers are polymerized in an organic solvent at 0 DEG to 100 DEG C. in the presence of a catalyst such as benzoyl peroxide, azobisisobutyronitrile, sodium persulphate, capryl peroxide, pelargonyl peroxide, hydrogen peroxide, cumene hydroperoxide, tertiary butyl diperphthalate, tertiary butyl perbenzoate, sodium peracetate or sodium percarbonate. The interpolymer swells in water to form a mucilage. The interpolymer may be converted to an alkali metal, ammonium or amine salt. In examples, interpolymers are formed from acrylic acid, methacrylic acid, maleic anhydride, methyl vinyl ether, isobutylene, styrene, acrylonitrile, tetraallyl silane, tetravinyl silane, triallyl methyl silane, diallyl dimethyl silane, tetramethallyl silane, dimethallyl dimethyl silane, divinyl dimethyl silane, trivinyl methyl silane, diallyl divinyl silane, tetraallyl germane, tetravinyl germane, tetraallyl tin, tetravinyl tin and tetrallyl lead. Specification 731,226 is referred to.
GB27282/58A 1957-12-09 1958-08-26 Improvements in and relating to polymers Expired GB836755A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US70132857A 1957-12-09 1957-12-09

Publications (1)

Publication Number Publication Date
GB836755A true GB836755A (en) 1960-06-09

Family

ID=24816924

Family Applications (1)

Application Number Title Priority Date Filing Date
GB27282/58A Expired GB836755A (en) 1957-12-09 1958-08-26 Improvements in and relating to polymers

Country Status (4)

Country Link
CH (1) CH375526A (en)
DE (1) DE1088718B (en)
FR (1) FR1224066A (en)
GB (1) GB836755A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0259096A1 (en) * 1986-08-26 1988-03-09 Nippon Paint Co., Ltd. Disintegration type, crosslinked acrylic resin particles
CN117567688A (en) * 2024-01-15 2024-02-20 星宇新材料股份有限公司 Butyronitrile emulsion and synthesis method and application thereof

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3534858A1 (en) * 1985-09-30 1987-04-02 Basf Lacke & Farben SOLUBLE ACRYLATE COPOLYMERISATE CONTAINING CARBOXYL GROUPS, METHOD FOR THE PRODUCTION THEREOF AND COATING AGENTS BASED ON THE ACRYLATE COPOLYMERISATE
DE3534874A1 (en) * 1985-09-30 1987-04-02 Basf Lacke & Farben SOLUBLE, CROSSLINKABLE ACRYLATE COPOLYMER, METHOD FOR THE PRODUCTION THEREOF AND COATING AGENTS BASED ON THE ACRYLATE COPOLYMER
FR2674106A1 (en) * 1991-03-21 1992-09-25 Salomon Sa ALPINE SKI BOOT WITH ENERGY CALIPER ARTICULATED ON THE REAR HOOD.
FR2674107A1 (en) * 1991-03-21 1992-09-25 Salomon Sa ALPINE SKI SHOE WITH ENERGY COMPONENT JOINED ON HULL.

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2628246A (en) * 1946-03-11 1953-02-10 Montclair Res Corp Method for the preparation of unsaturated silanes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0259096A1 (en) * 1986-08-26 1988-03-09 Nippon Paint Co., Ltd. Disintegration type, crosslinked acrylic resin particles
CN117567688A (en) * 2024-01-15 2024-02-20 星宇新材料股份有限公司 Butyronitrile emulsion and synthesis method and application thereof
CN117567688B (en) * 2024-01-15 2024-04-05 星宇新材料股份有限公司 Butyronitrile emulsion and synthesis method and application thereof

Also Published As

Publication number Publication date
FR1224066A (en) 1960-06-22
DE1088718B (en) 1960-09-08
CH375526A (en) 1964-02-29

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