GB835807A - Polymerisation of ethylenically unsaturated compounds - Google Patents
Polymerisation of ethylenically unsaturated compoundsInfo
- Publication number
- GB835807A GB835807A GB2489157A GB2489157A GB835807A GB 835807 A GB835807 A GB 835807A GB 2489157 A GB2489157 A GB 2489157A GB 2489157 A GB2489157 A GB 2489157A GB 835807 A GB835807 A GB 835807A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- methoxy
- hyponitrites
- methylethyl
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/04—Azo-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
The process of the parent Specification for polymerizing ethylenically unsaturated compounds using as catalyst organic hyponitrites wherein the organic residue contains at least one ether oxygen atom is modified in that hyponitrites are used wherein both organic residues contain one ether oxygen atom on the alpha carbon atoms and said alpha carbon atoms are attached otherwise only to carbon atoms. The hyponitrites are preferably of formula. ROCR1R11ON = NOCR1R11OR wherein R, R1 and R11 stand for organic radicals and R and R1 or R1 and R11 may be linked together so as to form, with the alpha carbon atom, a ring. Specified hyponitrites are bis (1-methoxy - 1 - methylethyl), bis(1 - ethoxy - 1-methylethyl), bis(1 - nonyloxy - 1 - methylethyl), bis(1 - methoxy - cyclopropan - 1 - yl), bis(1 - methoxycyclobutan - 1 - yl), bis(1-methoxycyclopentan - 1 - yl), bis(2 - methyltetrahydrofuran - 2 - yl), bis(1 - methoxy - 1-methylisobutan - 1 - yl), bis(1 - methoxy - 1-methylneopentan - 1 - yl), bis(1 - methoxy - 2,2, 4,4 - tetramethylcyclobutan - 1 - yl), bis(1-methoxy - 2 - carbomethoxycyclobutan - 1 - yl), bis)1 - methoxy - 2,5 - dimethylcyclopentan - 1-yl), bis(1 - methoxy - 1 - cyclohexylethyl) and bis(1 - methoxy - 1 - methyl - 2 - carbethoxyethyl) hyponitrites. The polymerization of vinyl acetate, ethylene, acrylonitrile and methyl methacrylate is exemplified.
Priority Applications (15)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DENDAT1075835D DE1075835B (en) | 1956-05-02 | Process for the polymerization of ethylenically unsaturated compounds | |
| NL230308D NL230308A (en) | 1956-05-02 | ||
| NL107441D NL107441C (en) | 1956-05-02 | ||
| NL95737D NL95737C (en) | 1956-05-02 | ||
| NL216844D NL216844A (en) | 1956-05-02 | ||
| GB13518/56A GB814668A (en) | 1956-05-02 | 1956-05-02 | Polymerisation of ethylenically unsaturated compounds |
| BE557164A BE557164A (en) | 1956-05-02 | 1957-05-02 | Polymerization of ethylenic unsaturated compounds |
| DEI13177A DE1060601B (en) | 1956-05-02 | 1957-05-02 | Process for the polymerization of olefinically unsaturated compounds |
| FR1174747D FR1174747A (en) | 1956-05-02 | 1957-05-02 | Polymerization of ethylenically unsaturated compounds |
| BE557163A BE557163A (en) | 1956-05-02 | 1957-05-02 | Esters |
| GB2489157A GB835807A (en) | 1957-08-07 | 1957-08-07 | Polymerisation of ethylenically unsaturated compounds |
| US688416A US2971952A (en) | 1956-05-02 | 1957-10-07 | Polymerization of ethylenically unsaturated compounds with organic hyponitrite catalysts |
| US751152A US3042663A (en) | 1956-05-02 | 1958-07-28 | Hyponitrite catalysts for polymerisation of ethylenically unsaturated compounds |
| BE570063A BE570063A (en) | 1956-05-02 | 1958-08-04 | Polymerization of ethylenic unsaturated compounds |
| FR772073A FR73995E (en) | 1956-05-02 | 1958-08-07 | Polymerization of ethylenically unsaturated compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2489157A GB835807A (en) | 1957-08-07 | 1957-08-07 | Polymerisation of ethylenically unsaturated compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB835807A true GB835807A (en) | 1960-05-25 |
Family
ID=10218883
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2489157A Expired GB835807A (en) | 1956-05-02 | 1957-08-07 | Polymerisation of ethylenically unsaturated compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB835807A (en) |
-
1957
- 1957-08-07 GB GB2489157A patent/GB835807A/en not_active Expired
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