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GB834984A - Optically active aryl-(2-pyridyl) aryl-substituted tertiary amines - Google Patents

Optically active aryl-(2-pyridyl) aryl-substituted tertiary amines

Info

Publication number
GB834984A
GB834984A GB21467/58A GB2146758A GB834984A GB 834984 A GB834984 A GB 834984A GB 21467/58 A GB21467/58 A GB 21467/58A GB 2146758 A GB2146758 A GB 2146758A GB 834984 A GB834984 A GB 834984A
Authority
GB
United Kingdom
Prior art keywords
phenyl
optically active
aryl
radical
pyridyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB21467/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MSD International Holdings GmbH
Original Assignee
Scherico Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scherico Ltd filed Critical Scherico Ltd
Publication of GB834984A publication Critical patent/GB834984A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/36Radicals substituted by singly-bound nitrogen atoms
    • C07D213/38Radicals substituted by singly-bound nitrogen atoms having only hydrogen or hydrocarbon radicals attached to the substituent nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pyridine Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention comprises optically active forms of compounds of the general formula <FORM:0834984/IV (b)/1> wherein Py is a 2-pyridyl residue, R represents a phenyl or a halogenated phenyl radical, and R1 represents a dialkylamino group or a morpholino, piperidino, or pyrrolidino radical; and acid addition salts thereof, particularly phenyl succinates, maleates, gluconates 8-halogenotheophyllinates, and 8-halogenoxanthinates; and the preparation thereof by resolution of appropriate racemates by means of optically active substituted succinic acids, especially phenyl- or substituted phenyl-succinic acids or, in the cases where R is phenyl, by dehalohydrogenation of optically active compounds of the above general formula where R is a halogenated phenyl radical using palladium on carbon or Raney nickel as catalyst; and, if desired, conversion of the products into acid addition salts by customary methods. The d-isomers have antihistaminic activity and the l-isomers have local anaesthetic properties and are useful as anti-emetics.
GB21467/58A 1958-03-04 1958-07-04 Optically active aryl-(2-pyridyl) aryl-substituted tertiary amines Expired GB834984A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US834984XA 1958-03-04 1958-03-04

Publications (1)

Publication Number Publication Date
GB834984A true GB834984A (en) 1960-05-18

Family

ID=22178735

Family Applications (1)

Application Number Title Priority Date Filing Date
GB21467/58A Expired GB834984A (en) 1958-03-04 1958-07-04 Optically active aryl-(2-pyridyl) aryl-substituted tertiary amines

Country Status (2)

Country Link
DE (1) DE1268620B (en)
GB (1) GB834984A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111499567A (en) * 2020-04-26 2020-08-07 上海新华联制药有限公司 Chlorpheniramine maleate, preparation method and application thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE538932A (en) * 1954-06-15

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111499567A (en) * 2020-04-26 2020-08-07 上海新华联制药有限公司 Chlorpheniramine maleate, preparation method and application thereof

Also Published As

Publication number Publication date
DE1268620B (en) 1968-05-22

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