GB828797A - Resinous compositions - Google Patents
Resinous compositionsInfo
- Publication number
- GB828797A GB828797A GB1114556A GB1114556A GB828797A GB 828797 A GB828797 A GB 828797A GB 1114556 A GB1114556 A GB 1114556A GB 1114556 A GB1114556 A GB 1114556A GB 828797 A GB828797 A GB 828797A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polysiloxanes
- silicon atom
- methyl
- condensation product
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- -1 methyl hydrogen Chemical compound 0.000 abstract 11
- 229920001296 polysiloxane Polymers 0.000 abstract 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 4
- 239000007859 condensation product Substances 0.000 abstract 4
- 238000001035 drying Methods 0.000 abstract 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 4
- 229910052710 silicon Inorganic materials 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 3
- 239000012530 fluid Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 239000004753 textile Substances 0.000 abstract 3
- QLVPICNVQBBOQP-UHFFFAOYSA-N 2-(4,6-diamino-1,3,5-triazin-2-yl)guanidine Chemical compound NC(N)=NC1=NC(N)=NC(N)=N1 QLVPICNVQBBOQP-UHFFFAOYSA-N 0.000 abstract 2
- XOGJBKWFLRETGW-UHFFFAOYSA-N 5-aminotriazine-4-carbaldehyde Chemical compound NC1=CN=NN=C1C=O XOGJBKWFLRETGW-UHFFFAOYSA-N 0.000 abstract 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 229940001007 aluminium phosphate Drugs 0.000 abstract 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 abstract 2
- MASBWURJQFFLOO-UHFFFAOYSA-N ammeline Chemical compound NC1=NC(N)=NC(O)=N1 MASBWURJQFFLOO-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 125000002091 cationic group Chemical group 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 239000006185 dispersion Substances 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 abstract 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 239000011133 lead Substances 0.000 abstract 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000005871 repellent Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 229910001388 sodium aluminate Inorganic materials 0.000 abstract 2
- 239000004408 titanium dioxide Substances 0.000 abstract 2
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical compound N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 abstract 2
- 150000003751 zinc Chemical class 0.000 abstract 2
- UPYPTOCXMIWHSG-UHFFFAOYSA-N 1-dodecylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCCCC UPYPTOCXMIWHSG-UHFFFAOYSA-N 0.000 abstract 1
- DYBIGIADVHIODH-UHFFFAOYSA-N 2-nonylphenol;oxirane Chemical compound C1CO1.CCCCCCCCCC1=CC=CC=C1O DYBIGIADVHIODH-UHFFFAOYSA-N 0.000 abstract 1
- 240000008564 Boehmeria nivea Species 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 abstract 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 240000006240 Linum usitatissimum Species 0.000 abstract 1
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 1
- 239000004677 Nylon Substances 0.000 abstract 1
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 235000009120 camo Nutrition 0.000 abstract 1
- 235000005607 chanvre indien Nutrition 0.000 abstract 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000002657 fibrous material Substances 0.000 abstract 1
- 239000011487 hemp Substances 0.000 abstract 1
- 239000004312 hexamethylene tetramine Substances 0.000 abstract 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 1
- 229960004011 methenamine Drugs 0.000 abstract 1
- 239000011707 mineral Substances 0.000 abstract 1
- 229920001778 nylon Polymers 0.000 abstract 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 abstract 1
- 229920002866 paraformaldehyde Polymers 0.000 abstract 1
- SQYNKIJPMDEDEG-UHFFFAOYSA-N paraldehyde Chemical compound CC1OC(C)OC(C)O1 SQYNKIJPMDEDEG-UHFFFAOYSA-N 0.000 abstract 1
- 229960003868 paraldehyde Drugs 0.000 abstract 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract 1
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 235000015096 spirit Nutrition 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2164—Coating or impregnation specified as water repellent
- Y10T442/218—Organosilicon containing
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Textiles are provided with a water-repellent and crease-resistant finish and are given an improved handle and an improved shrinkage control by treating with an aqueous dispersion of a methyl hydrogen polysiloxane and 0.5 to 14 parts by weight per part of polysiloxane of a partially polymerized colloidal cationic aminotriazine-aldehyde condensation product, associated with 0.5 to 7 mols. of an acid per mol. of condensation product on a monomeric basis, and drying the treated textile to insolubilize the resin. A glazed or embossed finish may be provided after partial drying, followed by complete drying. The polysiloxanes are fluids containing 1 to 1.5 methyl radicals and 0.75 to 1.25 siliconbonded hydrogen atoms per silicon atom and the sum of methyl groups and hydrogen atoms is 2 to 2.25 per silicon atom. They may be used in admixture with other polysiloxanes. A catalyst for the siloxane is desirable, e.g. sodium aluminate or iron, cobalt, manganese, lead and zinc salts of carboxylic acids. These may be added to the composition or applied to the fabric before or after treatment. The aminotriazine resin may be prepared from melamine, N-guanyl melamine, ammeline, formo-, aceto-, propio- and phenyl-guanamine and N-alkyl and aryl substituted derivatives. Methylol melamines and their alkylated derivatives are preferred, prepared as described in Specifications 623,355 and 566,347. Suitable acids are acetic, formic, propionic, gluconic, glycollic, lactic, hydrochloric, sulphuric and phosphoric. Any type of fibrous material may be treated; specified are cotton, linen, flax, ramie, manila, hemp. rayons, wool, silk, nylon, polyesters, acrylonitrile polymers and copolymers and vinyl chloride-vinylidene chloride copolymers. Drying may be effected at 65 DEG F. but preferably above 180 DEG F. Other materials may be included in the compositions, e.g., aluminium oxide and phosphate, titanium dioxide and silica.ALSO:A composition for providing water-repellent finishes on p textiles comprises an aqueous dispersion of a methyl hydrogen polysiloxane and 0.5 to 14 parts by weight, per part of polysiloxane, of a partially polymerized colloidal cationic aminotriazine-aldehyde condensation product, associated with 0.5 to 7 mols. of an acid per mol. of condensation product on a monomeric basis. The polysiloxanes are fluids containing 1 to 1.5 methyl radicals and 0.75 to 1.25 Si-bonded hydrogen atoms per silicon atom and the sum of methyl groups and hydrogen atoms is 2 to 2.25 per silicon atom. They may be used in admixture with other linear or cyclic siloxanes, of which a number is specified, and particularly with fluid dimethyl polysiloxanes having viscosities between 1000 and 100,000 centistokes. A catalyst for the siloxane is desirable, examples being sodium aluminate and iron, cobalt, manganese, lead and zinc salts of carboxylic acids. These may be added to the composition or applied to the fabric before or after treatment. The siloxane and catalyst, which may be in solution, for example in mineral spirits, are emulsified with known dispersing agents, e.g. polyvinyl alcohol, nonyl phenol-ethylene oxide condensates, fatty acid-ethylene oxide condensates, and polyethylene glycol tert. dodecyl thioether. The aminotriazine resin may be prepared from melamine, N-guanyl melamine, ammeline, formo-, aceto-, propio- and phenyl-guanamine and N-alkyl and aryl substituted derivatives. Methylol melamines and their alkylated derivatives are preferred, prepared as described in Specifications 566,347 and 623,355. Aldehydes other than formaldehyde which may be used include paraformaldehyde, hexamethylene tetramine, benzaldehyde, furfural, acetaldehyde and paraldehyde. Suitable acids are acetic, formic, propionic, gluconic, glycollic, lactic, hydrochloric, sulphuric and phosphoric. Curing of the compositions may be effected at 65 DEG F. but preferably above 180 DEG F. Other materials may be included in the compositions, e.g. aluminium oxide and phosphate, titanium dioxide and silica.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50174155 US3032442A (en) | 1955-04-15 | 1955-04-15 | Process of finishing textiles with silicone-colloidal melamine resin mixtures, composition and resultant article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB828797A true GB828797A (en) | 1960-02-24 |
Family
ID=23994840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1114556A Expired GB828797A (en) | 1955-04-15 | 1956-04-12 | Resinous compositions |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US3032442A (en) |
| GB (1) | GB828797A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3345195A (en) * | 1963-09-16 | 1967-10-03 | Dow Corning | Method for imparting a permanent crease to wool |
| US3477984A (en) * | 1966-09-12 | 1969-11-11 | Owens Corning Fiberglass Corp | Insulating material |
| US3935346A (en) * | 1973-03-12 | 1976-01-27 | Owens-Illinois, Inc. | Coated plastic substrates for coating compositions |
| JPS6155268A (en) * | 1984-08-22 | 1986-03-19 | 帝国繊維株式会社 | Flame-resistant fabric |
| DE102013209170A1 (en) | 2013-05-17 | 2013-09-12 | Cht R. Beitlich Gmbh | Composition useful e.g. for waterproofing of absorbent materials, comprises silicone polymer, wax and/or fatty acid esters, aminoplast, urea derivatives and/or melamine derivatives, solvent, crosslinking agent, and dispersing auxiliaries |
| DE102015204736A1 (en) | 2015-03-16 | 2016-09-22 | Cht R. Beitlich Gmbh | Fluorine-free hydrophobing |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2121005A (en) * | 1933-10-14 | 1938-06-21 | Firm Raduner & Co A G | Process of producing textiles with calender finish permanent to washing and product thereof |
| US2612482A (en) * | 1950-03-17 | 1952-09-30 | Gen Electric | Water-repellent compositions |
| BE498183A (en) * | 1949-11-10 | 1900-01-01 | ||
| US2661262A (en) * | 1950-01-30 | 1953-12-01 | Monsanto Chemicals | Composition containing colloidal methyl ether of methylol melamine and other thermoplastic resins and process of applying to cellulose textiles |
| US2758946A (en) * | 1952-09-23 | 1956-08-14 | Gen Electric | Silicone water-repellent compositions |
| BE523008A (en) * | 1952-09-23 |
-
1955
- 1955-04-15 US US50174155 patent/US3032442A/en not_active Expired - Lifetime
-
1956
- 1956-04-12 GB GB1114556A patent/GB828797A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3032442A (en) | 1962-05-01 |
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