GB815227A - Improvements in alkyd resins and methods of making the same - Google Patents
Improvements in alkyd resins and methods of making the sameInfo
- Publication number
- GB815227A GB815227A GB26055/55A GB2605555A GB815227A GB 815227 A GB815227 A GB 815227A GB 26055/55 A GB26055/55 A GB 26055/55A GB 2605555 A GB2605555 A GB 2605555A GB 815227 A GB815227 A GB 815227A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dihydric alcohol
- glycerol
- unsaturated
- specified
- alkyd resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000180 alkyd Polymers 0.000 title abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- DJKGDNKYTKCJKD-BPOCMEKLSA-N (1s,4r,5s,6r)-1,2,3,4,7,7-hexachlorobicyclo[2.2.1]hept-2-ene-5,6-dicarboxylic acid Chemical compound ClC1=C(Cl)[C@]2(Cl)[C@H](C(=O)O)[C@H](C(O)=O)[C@@]1(Cl)C2(Cl)Cl DJKGDNKYTKCJKD-BPOCMEKLSA-N 0.000 abstract 1
- BVIQZSQUDHUPDC-UHFFFAOYSA-N 2,3-dihydroxypropyl heptanoate Chemical compound CCCCCCC(=O)OCC(O)CO BVIQZSQUDHUPDC-UHFFFAOYSA-N 0.000 abstract 1
- BYPJBHDBVGRMOF-UHFFFAOYSA-N 2,3-dihydroxypropyl nonanoate Chemical compound CCCCCCCCC(=O)OCC(O)CO BYPJBHDBVGRMOF-UHFFFAOYSA-N 0.000 abstract 1
- 239000004342 Benzoyl peroxide Substances 0.000 abstract 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 abstract 1
- 238000005698 Diels-Alder reaction Methods 0.000 abstract 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- -1 aliphatic saturated fatty acid Chemical class 0.000 abstract 1
- 235000019400 benzoyl peroxide Nutrition 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical class OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/682—Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens
- C08G63/6824—Polyesters containing atoms other than carbon, hydrogen and oxygen containing halogens derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6828—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
In the manufacture of unsaturated alkyd resins by polycondensing an unsaturated dicarboxylic acid with a dihydric alcohol, polyaddition reactions are inhibited by using as dihydric alcohol a compound having two free hydroxyl groups and at least one hydroxy group esterified with an aliphatic saturated fatty acid containing 6-11 carbon atoms. Specified unsaturated dicarboxylic acids are maleic, fumaric, itaconic and mesaconic acids and their Diels-Alder adducts with dienes, e.g. hexachloroendomethylene tetrahydrophthalic acid. Specified dihydric alcohols are glycerol monoheptanoate and glycerol monopelargonate. The dihydric alcohol may be purified by treatment with ozone and distillation under reduced pressure. The unsaturated alkyd may be mixed with styrene, the mixture stabilized with hydroquinone and later copolymerized using as catalyst benzoyl peroxide or a mixture thereof with cobalt naphthenate. Specification 500,547, [Group IV], is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR815227X | 1954-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB815227A true GB815227A (en) | 1959-06-24 |
Family
ID=9267126
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB26055/55A Expired GB815227A (en) | 1954-09-14 | 1955-09-12 | Improvements in alkyd resins and methods of making the same |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB815227A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012136714A1 (en) * | 2011-04-08 | 2012-10-11 | Nuplex Resins B.V. | Glycerol based unsaturated polyester resins and raw materials therefor |
-
1955
- 1955-09-12 GB GB26055/55A patent/GB815227A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012136714A1 (en) * | 2011-04-08 | 2012-10-11 | Nuplex Resins B.V. | Glycerol based unsaturated polyester resins and raw materials therefor |
| GB2504868A (en) * | 2011-04-08 | 2014-02-12 | Nuplex Resins Bv | Glycerol based unsaturated polyester resins and raw materials therefor |
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