GB814222A - Process for the production of co-polyamides - Google Patents
Process for the production of co-polyamidesInfo
- Publication number
- GB814222A GB814222A GB5277/57A GB527757A GB814222A GB 814222 A GB814222 A GB 814222A GB 5277/57 A GB5277/57 A GB 5277/57A GB 527757 A GB527757 A GB 527757A GB 814222 A GB814222 A GB 814222A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzoic acid
- aminomethyl
- polyamides
- caprolactam
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920006018 co-polyamide Polymers 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- QCTBMLYLENLHLA-UHFFFAOYSA-N aminomethylbenzoic acid Chemical compound NCC1=CC=C(C(O)=O)C=C1 QCTBMLYLENLHLA-UHFFFAOYSA-N 0.000 abstract 6
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 abstract 3
- 125000004494 ethyl ester group Chemical group 0.000 abstract 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 1
- LFIWXXXFJFOECP-UHFFFAOYSA-N 4-(aminomethyl)benzonitrile Chemical compound NCC1=CC=C(C#N)C=C1 LFIWXXXFJFOECP-UHFFFAOYSA-N 0.000 abstract 1
- GBVNYDNYSMQHEF-UHFFFAOYSA-N 4-(formamidomethyl)benzoic acid Chemical compound OC(=O)C1=CC=C(CNC=O)C=C1 GBVNYDNYSMQHEF-UHFFFAOYSA-N 0.000 abstract 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229930003836 cresol Natural products 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
Abstract
Co-polyamides are made by reacting e -caprolactam or e -aminocaptroic acid in the absence of oxygen with 4-(amino-methyl) benzoic acid or an amide forming derivative thereof. Specified derivatives of 4-(aminomethyl) benzoic acid are the ethyl ester thereof, 4-(formylaminomethyl) benzoic acid or 4-(aminomethyl) benzonitrile. The process may be continuous or discontinuous and may be carried out in solvents, e.g. phenol, xylenol or cresol. The examples describe the preparation of co-polyamides from (1) and (3) 4-(aminomethyl) benzoic acid and e -caprolactam; (2) 4-(aminomethyl) benzoic acid and e -aminocaproic acid; (4) 4-(aminomethyl) benzoic acid nitrile and e -caprolactam; and (5) the ethyl ester of 4-(aminomethyl) benzoic acid. The products may be extruded into the form of monofilaments or converted into injection mouldings.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH814222X | 1956-03-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB814222A true GB814222A (en) | 1959-06-03 |
Family
ID=4538796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5277/57A Expired GB814222A (en) | 1956-03-09 | 1957-02-15 | Process for the production of co-polyamides |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH353173A (en) |
| DE (1) | DE1147384B (en) |
| FR (1) | FR1175428A (en) |
| GB (1) | GB814222A (en) |
| NL (2) | NL210930A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190002639A1 (en) * | 2016-09-14 | 2019-01-03 | Kingfa Sci. & Tech. Co., Ltd. | Semiaromatic copolyamide resin and polyamide molding composition consisting of the same |
| CN110770278A (en) * | 2017-06-14 | 2020-02-07 | 索尔维特殊聚合物美国有限责任公司 | Copolyamides obtainable from 3- (aminomethyl) benzoic acid |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2071253A (en) * | 1935-01-02 | 1937-02-16 | Du Pont | Linear condensation polymers |
| NL52517C (en) * | 1939-02-22 |
-
0
- NL NL98485D patent/NL98485C/xx active
- NL NL210930D patent/NL210930A/xx unknown
-
1956
- 1956-03-09 CH CH353173D patent/CH353173A/en unknown
-
1957
- 1957-01-12 DE DEI12690A patent/DE1147384B/en active Pending
- 1957-01-30 FR FR1175428D patent/FR1175428A/en not_active Expired
- 1957-02-15 GB GB5277/57A patent/GB814222A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190002639A1 (en) * | 2016-09-14 | 2019-01-03 | Kingfa Sci. & Tech. Co., Ltd. | Semiaromatic copolyamide resin and polyamide molding composition consisting of the same |
| US10731002B2 (en) * | 2016-09-14 | 2020-08-04 | Kingfa Sci. & Tech. Co., Ltd. | Semiaromatic copolyamide resin and polyamide molding composition consisting of the same |
| CN110770278A (en) * | 2017-06-14 | 2020-02-07 | 索尔维特殊聚合物美国有限责任公司 | Copolyamides obtainable from 3- (aminomethyl) benzoic acid |
| CN110770278B (en) * | 2017-06-14 | 2023-02-17 | 索尔维特殊聚合物美国有限责任公司 | Copolyamides obtainable from 3-(aminomethyl)benzoic acid |
Also Published As
| Publication number | Publication date |
|---|---|
| CH353173A (en) | 1961-03-31 |
| NL98485C (en) | |
| FR1175428A (en) | 1959-03-26 |
| NL210930A (en) | |
| DE1147384B (en) | 1963-04-18 |
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