GB801529A - Organosilicon resins - Google Patents
Organosilicon resinsInfo
- Publication number
- GB801529A GB801529A GB1582856A GB1582856A GB801529A GB 801529 A GB801529 A GB 801529A GB 1582856 A GB1582856 A GB 1582856A GB 1582856 A GB1582856 A GB 1582856A GB 801529 A GB801529 A GB 801529A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- styrene
- reacted
- per cent
- propylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 title abstract 5
- 239000011347 resin Substances 0.000 title abstract 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- 235000011087 fumaric acid Nutrition 0.000 abstract 4
- 235000011037 adipic acid Nutrition 0.000 abstract 3
- 150000001279 adipic acids Chemical class 0.000 abstract 3
- 239000007795 chemical reaction product Substances 0.000 abstract 3
- 150000002238 fumaric acids Chemical class 0.000 abstract 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 3
- 125000002348 vinylic group Chemical group 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 abstract 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 abstract 2
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- 229920001225 polyester resin Polymers 0.000 abstract 2
- 239000004645 polyester resin Substances 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 235000013772 propylene glycol Nutrition 0.000 abstract 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 abstract 2
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 abstract 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 abstract 1
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000010425 asbestos Substances 0.000 abstract 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- LDCRTTXIJACKKU-ONEGZZNKSA-N dimethyl fumarate Chemical compound COC(=O)\C=C\C(=O)OC LDCRTTXIJACKKU-ONEGZZNKSA-N 0.000 abstract 1
- 229960004419 dimethyl fumarate Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000001530 fumaric acid Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 229910052895 riebeckite Inorganic materials 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract 1
- 150000004819 silanols Chemical class 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 1
- 229920006337 unsaturated polyester resin Polymers 0.000 abstract 1
- -1 vinylic compound Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical group O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
- C08G63/6954—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon derived from polxycarboxylic acids and polyhydroxy compounds
- C08G63/6958—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Resinous copolymers suitable as casting resins consist essentially of the reaction products of mixtures of from 24.9 to 74.6 per cent (by weight] of a vinylic compound, from 24.9 to 74.6 per cent of an unsaturated polyester resin and from 0.5 to 30 per cent of <FORM:0801529/IV (a)/1> wherein R is a monovalent saturated or unsaturated hydrocarbon radical, X is an alkoxy or hydroxy radical, n has an average value of from 1 to 2 inclusive and m has an average value of from 0.03 to 3 inclusive. The vinylic resins (monomers or polymers) specified are vinyl chloride, vinylidene chloride, acrylonitrile, vinyl alcohol, styrene, a -methyl styrene, chloro styrene, vinyl toluene, vinyl naphthalene, ethyl-vinyl benzene and vinyl acetate, and may also contain (preferably less than 10 mol. per cent of the total vinylic resin) divinyl compounds such as divinyl benzene. The polyester resins used are the reaction products of polyhydric alcohols and unsaturated dicarboxylic acids with or without other polycarboxylic acids, e.g. the reaction products of glycerine, and phthalic and maleic anhydrides, ethylene glycol and adipic and fumaric acids, propylene glycol and fumaric acid, tripropylene glycol and maleic anhydride, propylene glycol, sebacic acid and maleic anhydride, and propylene glycol, dimethyl terephthalate and dimethyl fumarate. The organosilicon compounds used may also be monomeric or polymeric, e.g. alkoxysilanes of the formula RnSi(OR1)4-n, silanols of the formula RnSi(OH)4-n and partial condensates thereof. The reactants may be reacted in any order, but preferably the organosilicon compound is reacted with the polyester resin and the resulting product is then reacted with the vinylic resin. Plasticisers, stabilizers and fillers, e.g. silica, glass, asbestos, alumina and titania, may be added. In a typical example, the polyester obtained by reaction of ethylene glycol, adipic and fumaric acids was reacted with a methoxy methylphenylpolysiloxane, and the resulting product after dilution with styrene containing t-butylcatechol as inhibitor, was mixed with a styrene solution of a polyester obtained by reaction of propylene glycol, adipic and fumaric acids, and polymerized by heating with t-butyl perbenzoate. Specification 759,197 and 766,627 are referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1582856A GB801529A (en) | 1956-05-22 | 1956-05-22 | Organosilicon resins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1582856A GB801529A (en) | 1956-05-22 | 1956-05-22 | Organosilicon resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB801529A true GB801529A (en) | 1958-09-17 |
Family
ID=10066260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1582856A Expired GB801529A (en) | 1956-05-22 | 1956-05-22 | Organosilicon resins |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB801529A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3720538A (en) * | 1967-06-30 | 1973-03-13 | Wacker Chemie Gmbh | Method of protecting materials against water absorption |
| EP0029947A1 (en) * | 1979-11-28 | 1981-06-10 | Bayer Ag | Dispersions of graft polymers, their preparation and use |
| EP0029948A3 (en) * | 1979-11-28 | 1981-12-23 | Bayer Ag | Graft polymers, process for their preparation and their use |
| DE10301976A1 (en) * | 2003-01-20 | 2004-07-29 | Wacker Polymer Systems Gmbh & Co. Kg | Novel silicon-containing polymers obtained by radical polymerization of ethylenically-unsaturated monomers in presence of branched polysiloxanes which can act as emulsifiers |
-
1956
- 1956-05-22 GB GB1582856A patent/GB801529A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3720538A (en) * | 1967-06-30 | 1973-03-13 | Wacker Chemie Gmbh | Method of protecting materials against water absorption |
| EP0029947A1 (en) * | 1979-11-28 | 1981-06-10 | Bayer Ag | Dispersions of graft polymers, their preparation and use |
| EP0029948A3 (en) * | 1979-11-28 | 1981-12-23 | Bayer Ag | Graft polymers, process for their preparation and their use |
| DE10301976A1 (en) * | 2003-01-20 | 2004-07-29 | Wacker Polymer Systems Gmbh & Co. Kg | Novel silicon-containing polymers obtained by radical polymerization of ethylenically-unsaturated monomers in presence of branched polysiloxanes which can act as emulsifiers |
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