GB804066A - Improvements relating to anion-exchange resins - Google Patents
Improvements relating to anion-exchange resinsInfo
- Publication number
- GB804066A GB804066A GB3363355A GB3363355A GB804066A GB 804066 A GB804066 A GB 804066A GB 3363355 A GB3363355 A GB 3363355A GB 3363355 A GB3363355 A GB 3363355A GB 804066 A GB804066 A GB 804066A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reacted
- amine
- polymer
- anion
- diethylamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003957 anion exchange resin Substances 0.000 title abstract 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 abstract 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 2
- 239000004793 Polystyrene Substances 0.000 abstract 2
- 238000005349 anion exchange Methods 0.000 abstract 2
- 229920002223 polystyrene Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 abstract 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229920006037 cross link polymer Polymers 0.000 abstract 1
- 125000001188 haloalkyl group Chemical group 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- SBIDUCNDVPSWQT-UHFFFAOYSA-N n-ethyl-n-(oxiran-2-ylmethyl)ethanamine Chemical compound CCN(CC)CC1CO1 SBIDUCNDVPSWQT-UHFFFAOYSA-N 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Anion-exchange resins containing two or more nitrogen atoms in each anion-exchange group are prepared by reacting under alkaline conditions a cross-linked polymer containing haloalkyl groups, an o -ethylene oxide substituted alkyl halide, and a primary or secondary amine to form an intermediate polymer which is further reacted with an amine. The o -ethylene oxide substituted alkyl halide and the amine may be reacted together and then reacted with the polymer or, in a modification, the polymer may be reacted with the amine and then with the o -ethylene oxide substituted alkyl halide, and the products finally reacted with an amine. The polymer may be polystyrene cross-linked with divinyl benzene or ketone and in examples beads of chlormethylated polystyrene cross-linked with divinyl benzene are reacted (1) swollen with benzene, with 3-diethylamino-1,2-epoxypropane, a reaction product of diethylamine and epichlorhydrin in a medium made alkaline with caustic soda, and (3) swollen in ethylene dichloride with diethylamine and then with epichlorhydrin in dioxane, to form intermediate resins which are reacted with diethylamine or trimethylamine to give strongly basic resins of high anion exchange capacity.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3363355A GB804066A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
| GB3363255A GB808844A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
| DE1956P0017436 DE1063807B (en) | 1955-11-23 | 1956-11-22 | Process for the production of synthetic resins with anion-exchanging properties |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3363355A GB804066A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
| GB3363255A GB808844A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB804066A true GB804066A (en) | 1958-11-05 |
Family
ID=10355422
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3363255A Expired GB808844A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
| GB3363355A Expired GB804066A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3363255A Expired GB808844A (en) | 1955-11-23 | 1955-11-23 | Improvements relating to anion-exchange resins |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1063807B (en) |
| GB (2) | GB808844A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0006360A1 (en) * | 1978-06-19 | 1980-01-09 | Monsanto Company | A polymeric wet strength paper additive and a process for improving the wet strength of a fibrous cellulosic substrate |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0187281B1 (en) * | 1985-01-07 | 1993-06-23 | Rhone-Poulenc Specialty Chemicals Co. | Novel carboxylate polymers and processes for their preparation and use |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE467746A (en) * | 1945-09-15 | |||
| US2689833A (en) * | 1951-09-21 | 1954-09-21 | Rohm & Haas | Resinous quaternary ammonium alkoxides |
-
1955
- 1955-11-23 GB GB3363255A patent/GB808844A/en not_active Expired
- 1955-11-23 GB GB3363355A patent/GB804066A/en not_active Expired
-
1956
- 1956-11-22 DE DE1956P0017436 patent/DE1063807B/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0006360A1 (en) * | 1978-06-19 | 1980-01-09 | Monsanto Company | A polymeric wet strength paper additive and a process for improving the wet strength of a fibrous cellulosic substrate |
Also Published As
| Publication number | Publication date |
|---|---|
| GB808844A (en) | 1959-02-11 |
| DE1063807B (en) | 1959-08-20 |
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