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GB730431A - Process for producing polyhydroxy organic compounds - Google Patents

Process for producing polyhydroxy organic compounds

Info

Publication number
GB730431A
GB730431A GB11618/53A GB1161853A GB730431A GB 730431 A GB730431 A GB 730431A GB 11618/53 A GB11618/53 A GB 11618/53A GB 1161853 A GB1161853 A GB 1161853A GB 730431 A GB730431 A GB 730431A
Authority
GB
United Kingdom
Prior art keywords
hydrogen peroxide
olefinic
hydroxylation
water
give
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11618/53A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB730431A publication Critical patent/GB730431A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/23—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Polyhydroxy organic compounds are produced by reacting water-soluble olefinic compounds with hydrogen peroxide in the presence of an unstable peracid-forming metal oxide hydroxylation catalyst at temperatures between 40 DEG and 60 DEG C. until the hydrogen peroxide is substantially completely consumed but hydroxylation of the olefinic compound is incomplete and then completing the hydroxylation at a temperature between 60 DEG and 100 DEG C. Examples of water-soluble olefinic compounds are olefinic alcohols, aldehydes, ketones and ethers and the water-soluble halo-substitution products of the olefinic alcohols, ethers, aldehydes and ketones having the halogen atom or atoms linked to non-olefinic carbon atoms. The preferred metal oxide hydroxylation catalysts are the oxides of tungsten, molybdenum or vanadium. In the presence of hydrogen peroxide the oxides form unstable peracids. The oxides can be added in the form of their acids, e.g. tungstic acid or molybdic acid. In the examples: (a) allyl alcohol is treated with hydrogen peroxide in the presence of water and tungstic acid to give glycerine; (b) crotyl alcohol is treated similarly to give glyceraldehyde and (c) acrolein is treated with hydrogen peroxide in the presence of osmium tetroxide to give glyceraldehyde.
GB11618/53A 1952-04-28 1953-04-27 Process for producing polyhydroxy organic compounds Expired GB730431A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US730431XA 1952-04-28 1952-04-28

Publications (1)

Publication Number Publication Date
GB730431A true GB730431A (en) 1955-05-25

Family

ID=22111362

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11618/53A Expired GB730431A (en) 1952-04-28 1953-04-27 Process for producing polyhydroxy organic compounds

Country Status (1)

Country Link
GB (1) GB730431A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0297444A3 (en) * 1987-06-30 1989-05-03 BASF Aktiengesellschaft Method for the production of 1,2,4-butanetriol
EP2150521A4 (en) * 2007-06-27 2010-08-11 H R D Corp Method of making glycerol

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0297444A3 (en) * 1987-06-30 1989-05-03 BASF Aktiengesellschaft Method for the production of 1,2,4-butanetriol
EP2150521A4 (en) * 2007-06-27 2010-08-11 H R D Corp Method of making glycerol

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