GB721827A - Improvements in or relating to fluorescent coating compositions - Google Patents
Improvements in or relating to fluorescent coating compositionsInfo
- Publication number
- GB721827A GB721827A GB2296550A GB2296550A GB721827A GB 721827 A GB721827 A GB 721827A GB 2296550 A GB2296550 A GB 2296550A GB 2296550 A GB2296550 A GB 2296550A GB 721827 A GB721827 A GB 721827A
- Authority
- GB
- United Kingdom
- Prior art keywords
- dye
- resin
- chloride
- xanthenyl
- acetyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000008199 coating composition Substances 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 abstract 6
- 239000011347 resin Substances 0.000 abstract 6
- -1 dimethyl dehydrothiotoluidine Chemical compound 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 abstract 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 3
- 239000000975 dye Substances 0.000 abstract 3
- 239000004606 Fillers/Extenders Substances 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- 229920000877 Melamine resin Polymers 0.000 abstract 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 abstract 2
- 239000007850 fluorescent dye Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 abstract 1
- OWEFOBNFYAPWHD-UHFFFAOYSA-N 2-(1,2-dihydroxyheptan-3-yloxycarbonyl)benzoic acid Chemical compound CCCCC(C(CO)O)OC(=O)C1=CC=CC=C1C(=O)O OWEFOBNFYAPWHD-UHFFFAOYSA-N 0.000 abstract 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 abstract 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 abstract 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- MPFUOCVWJGGDQN-UHFFFAOYSA-N butan-1-ol;1,2-xylene Chemical group CCCCO.CC1=CC=CC=C1C MPFUOCVWJGGDQN-UHFFFAOYSA-N 0.000 abstract 1
- 150000007942 carboxylates Chemical group 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 229940116333 ethyl lactate Drugs 0.000 abstract 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 239000010445 mica Substances 0.000 abstract 1
- 229910052618 mica group Inorganic materials 0.000 abstract 1
- RIFDEYZNUXHVFN-UHFFFAOYSA-N n-cyclohexylnaphthalene-1-carboxamide Chemical compound C=1C=CC2=CC=CC=C2C=1C(=O)NC1CCCCC1 RIFDEYZNUXHVFN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920000193 polymethacrylate Polymers 0.000 abstract 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 229940075065 polyvinyl acetate Drugs 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 239000005033 polyvinylidene chloride Substances 0.000 abstract 1
- 239000012260 resinous material Substances 0.000 abstract 1
- 229940100486 rice starch Drugs 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000007614 solvation Methods 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 abstract 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical class CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A fluorescent coating composition comprises a volatile organic solvent solution of at least one synthetic resinous condensation product in physical or chemical combination with at least one fluorescent dye, and at least one finely-divided solid light diffusing medium (extender), preferably having a particle size not greater than 2 microns and a refractive index not differing from that of the resin by more than 15 per cent, the resin constituting at least 35 per cent by weight of the composition, and the dye being in a proportion not exceeding that at which optimum brightness is achieved. The dye-resin combination may be formed, e.g. by adsorption, solvation or by ester formation between a carboxylate group in the dye and a hydroxyl group of the resin. The compositions may be made by dissolving the resin(s) in a solvent or solvent mixture, adding the dye(s) thereto and heating; the extender(s) is then stirred in and the mixture further heated. Ingredients specified are:-Fluorescent dyes-4 - amino - 1 : 8 - naphthalic acid - 41 - phenylanilide sodium sulphonate, 4-amino-1 : 8-naphthalic acid-41-methylanilide, 4-amino-1 : 8-naphthalic acid - cyclohexylamide, 3 : 6 - diamino - acridine methochloride hydrochloride, dimethyl dehydrothiotoluidine - methochloride, 3 : 6 - bisethylamino - 9 - (21 - carbethoxy - phenyl) - xanthenyl - chloride, 3 : 6 - bis - diethylamino - 9 - (21 - carboxyphenyl) - xanthenyl chloride, 3 : 6 - bis - diethylamino - 9 - (21 - sulphophenyl)-xanthenyl sodium sulphonate. Non-fluorescent dyes and pigments may also be added: resins-glyceryl phthalate (modified and unmodified), alkylated (e.g. butylated) urea-formaldehyde, alkylated (e.g. butylated) melamine-formaldehyde, cyclohexanone - aldehyde, epoxide, sulphonamide-aldehyde and polyurethane (e.g. toluene diisocyanate and butylglyceryl phthalate) resins. Other resinous materials which may be added are nitro-, acetyl-, ethyl-, benzyl-, acetyl-butyryl- and acetyl-propionyl-celluloses; polymethacrylate, polyvinyl - acetate and -chloride, polyvinylidene chloride and their copolymers; extenders-silica, magnesia, alumina, powdered urea- and melamine-formaldehyde resins, mica, china clay, rice starch and acetylated starch; solvents-diacetone alcohol, ethyl acetate, butyl acetate, ethyl lactate, acetone, methyl isobutyl ketone, white spirit and butanol-xylene mixture. Cobalt and lead driers or acid catalysts such as phosphoric and p-toluene sulphonic acids may be added to the compositions. Examples are given. Specification 456,480 is referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2296550A GB721827A (en) | 1950-09-19 | 1950-09-19 | Improvements in or relating to fluorescent coating compositions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2296550A GB721827A (en) | 1950-09-19 | 1950-09-19 | Improvements in or relating to fluorescent coating compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB721827A true GB721827A (en) | 1955-01-12 |
Family
ID=10187924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2296550A Expired GB721827A (en) | 1950-09-19 | 1950-09-19 | Improvements in or relating to fluorescent coating compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB721827A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3153591A (en) * | 1962-06-25 | 1964-10-20 | Minnesota Mining & Mfg | Copysheets and their preparation |
| GB2194244A (en) * | 1981-11-23 | 1988-03-02 | Post Office | Improvements in or relating to phosphorescent materials |
| WO2006133169A3 (en) * | 2005-06-07 | 2007-05-31 | Johnson & Son Inc S C | Composition for application to a surface |
| US7727289B2 (en) | 2005-06-07 | 2010-06-01 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
| US7776108B2 (en) | 2005-06-07 | 2010-08-17 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
| US8061269B2 (en) | 2008-05-14 | 2011-11-22 | S.C. Johnson & Son, Inc. | Multilayer stencils for applying a design to a surface |
| US8557758B2 (en) | 2005-06-07 | 2013-10-15 | S.C. Johnson & Son, Inc. | Devices for applying a colorant to a surface |
| US8846154B2 (en) | 2005-06-07 | 2014-09-30 | S.C. Johnson & Son, Inc. | Carpet décor and setting solution compositions |
| CN112126271A (en) * | 2018-11-23 | 2020-12-25 | 青岛磐诺新材料有限公司 | Preparation method of high-refractive-index nano hybrid extinction material |
| CN119875494A (en) * | 2025-01-22 | 2025-04-25 | 郑州优波科新材料股份有限公司 | Rail radiation heat dissipation coating and preparation method thereof |
-
1950
- 1950-09-19 GB GB2296550A patent/GB721827A/en not_active Expired
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3153591A (en) * | 1962-06-25 | 1964-10-20 | Minnesota Mining & Mfg | Copysheets and their preparation |
| GB2194244A (en) * | 1981-11-23 | 1988-03-02 | Post Office | Improvements in or relating to phosphorescent materials |
| US7776108B2 (en) | 2005-06-07 | 2010-08-17 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
| US7423002B2 (en) | 2005-06-07 | 2008-09-09 | S.C. Johnson & Son, Inc. | Method of neutralizing a stain on a surface |
| US7556841B2 (en) | 2005-06-07 | 2009-07-07 | S. C. Johnson & Son, Inc. | Method of applying a design to a surface |
| US7727289B2 (en) | 2005-06-07 | 2010-06-01 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
| WO2006133169A3 (en) * | 2005-06-07 | 2007-05-31 | Johnson & Son Inc S C | Composition for application to a surface |
| US8557758B2 (en) | 2005-06-07 | 2013-10-15 | S.C. Johnson & Son, Inc. | Devices for applying a colorant to a surface |
| US8734533B2 (en) | 2005-06-07 | 2014-05-27 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
| US8747487B2 (en) | 2005-06-07 | 2014-06-10 | S.C. Johnson & Son, Inc. | Composition for application to a surface |
| US8846154B2 (en) | 2005-06-07 | 2014-09-30 | S.C. Johnson & Son, Inc. | Carpet décor and setting solution compositions |
| US8061269B2 (en) | 2008-05-14 | 2011-11-22 | S.C. Johnson & Son, Inc. | Multilayer stencils for applying a design to a surface |
| US8499689B2 (en) | 2008-05-14 | 2013-08-06 | S. C. Johnson & Son, Inc. | Kit including multilayer stencil for applying a design to a surface |
| CN112126271A (en) * | 2018-11-23 | 2020-12-25 | 青岛磐诺新材料有限公司 | Preparation method of high-refractive-index nano hybrid extinction material |
| CN119875494A (en) * | 2025-01-22 | 2025-04-25 | 郑州优波科新材料股份有限公司 | Rail radiation heat dissipation coating and preparation method thereof |
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