GB700292A - Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compounds - Google Patents
Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compoundsInfo
- Publication number
- GB700292A GB700292A GB3029249A GB3029249A GB700292A GB 700292 A GB700292 A GB 700292A GB 3029249 A GB3029249 A GB 3029249A GB 3029249 A GB3029249 A GB 3029249A GB 700292 A GB700292 A GB 700292A
- Authority
- GB
- United Kingdom
- Prior art keywords
- brominated
- phosphate
- alkene
- triallyl phosphate
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 alkene phosphate compounds Chemical class 0.000 title abstract 6
- 239000000463 material Substances 0.000 title 1
- 239000007787 solid Substances 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 9
- XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical class C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 abstract 5
- 239000000839 emulsion Substances 0.000 abstract 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- 229910019142 PO4 Inorganic materials 0.000 abstract 3
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 3
- 235000021317 phosphate Nutrition 0.000 abstract 3
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 3
- 229920002554 vinyl polymer Polymers 0.000 abstract 3
- 239000004254 Ammonium phosphate Substances 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 229910000148 ammonium phosphate Inorganic materials 0.000 abstract 2
- 235000019289 ammonium phosphates Nutrition 0.000 abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 2
- 229910052794 bromium Inorganic materials 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 230000031709 bromination Effects 0.000 abstract 1
- 238000005893 bromination reaction Methods 0.000 abstract 1
- 125000001246 bromo group Chemical group Br* 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract 1
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 229920001059 synthetic polymer Polymers 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Transparent films of synthetic polymers such as cellulose acetate and vinyl type resins are flameproofed by using as a plasticiser in the film-forming liquid a brominated monomeric phosphoric acid compound made by bromination of an alkene phosphate of formula <FORM:0700292/IV(a)/1> where R is an unsaturated radicle of 3-5 C atoms and X is ONH4 or OR. Brominated triallyl phosphate is mentioned as a particularly suitable compound. Solutions or emulsions of the brominated monomer are used in flameproofing textiles (see Group VIII) and may contain a vinyl resin binder. In Examples (3) triallyl phosphate in aqueous emulsion with polyvinyl alcohol and calcium carbonate is treated with bromine in benzene; (4) triallyl phosphate in aqueous emulsion with polyvinyl alcohol is partially brominated by treatment with bromine in benzene; (5) a hexabromo triallyl phosphate is admixed in methyl ethyl ketone with a vinyl resin e.g. a vinyl chloride-vinyl acetate copolymer containing about 80 per cent. of vinyl chloride and in (6) transparent films are made from a composition containing the ingredients of (5).ALSO:Alkene phosphates of formula <FORM:0700292/IV(b)/1> wherein R is an unsaturated aliphatic radicle of 3-5 C atoms and X is O.NH4 or OR are brominated when dissolved in a solvent or dispersed in a non-solvent medium. Brominated alkene phosphate monomers are obtained. The products are used in flame-proofing (see Group VIII). In examples triallyl phosphate is (1) and (5) brominated in benzene, (2) partially brominated to the equivalent of dibromo-triallyl phosphate and (3) and (4) brominated and partially brominated respectively in an aqueous emulsion of polyvinyl alcohol and in (7) diallyl ammonium phosphate is brominated in aqueous solution to give tetra bromo diallyl ammonium phosphate. Specification 688,372 is referred to.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3029249A GB700292A (en) | 1949-11-25 | 1949-11-25 | Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3029249A GB700292A (en) | 1949-11-25 | 1949-11-25 | Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB700292A true GB700292A (en) | 1953-11-25 |
Family
ID=10305319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3029249A Expired GB700292A (en) | 1949-11-25 | 1949-11-25 | Improvements in or relating to the flameproofing of solid inflammable materials withbrominated alkene phosphate compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB700292A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1013863B (en) * | 1955-12-16 | 1957-08-14 | Hoechst Ag | Flame retardants |
| US3149089A (en) * | 1959-08-27 | 1964-09-15 | Du Pont | Preparation of acrylonitrile fibers |
| FR2079437A1 (en) * | 1970-02-14 | 1971-11-12 | Hoechst Ag | |
| GB2117021A (en) * | 1982-03-16 | 1983-10-05 | Sandoz Products Ltd | Flameproofing compositions |
-
1949
- 1949-11-25 GB GB3029249A patent/GB700292A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1013863B (en) * | 1955-12-16 | 1957-08-14 | Hoechst Ag | Flame retardants |
| US3149089A (en) * | 1959-08-27 | 1964-09-15 | Du Pont | Preparation of acrylonitrile fibers |
| FR2079437A1 (en) * | 1970-02-14 | 1971-11-12 | Hoechst Ag | |
| GB2117021A (en) * | 1982-03-16 | 1983-10-05 | Sandoz Products Ltd | Flameproofing compositions |
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