GB679562A - Polymers and a process for the preparation thereof - Google Patents
Polymers and a process for the preparation thereofInfo
- Publication number
- GB679562A GB679562A GB29343/49A GB2934349A GB679562A GB 679562 A GB679562 A GB 679562A GB 29343/49 A GB29343/49 A GB 29343/49A GB 2934349 A GB2934349 A GB 2934349A GB 679562 A GB679562 A GB 679562A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl
- polymers
- allyl
- chloride
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 13
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 5
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 abstract 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 3
- JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 abstract 2
- JESXATFQYMPTNL-UHFFFAOYSA-N 2-ethenylphenol Chemical compound OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 abstract 2
- 206010001497 Agitation Diseases 0.000 abstract 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 abstract 2
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 abstract 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Natural products OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 2
- 238000013019 agitation Methods 0.000 abstract 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract 2
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 abstract 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003701 inert diluent Substances 0.000 abstract 2
- 239000012442 inert solvent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 2
- -1 vinyl allyl phthalate Chemical compound 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 abstract 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 abstract 1
- OYLCUJRJCUXQBQ-UHFFFAOYSA-N 1-hepten-3-one Chemical compound CCCCC(=O)C=C OYLCUJRJCUXQBQ-UHFFFAOYSA-N 0.000 abstract 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 abstract 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- GBURUDXSBYGPBL-UHFFFAOYSA-N 2,2,3-trimethylhexanedioic acid Chemical compound OC(=O)C(C)(C)C(C)CCC(O)=O GBURUDXSBYGPBL-UHFFFAOYSA-N 0.000 abstract 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 abstract 1
- PIGJZPZYWKFDBR-UHFFFAOYSA-N 2,5-dimethyl-1-(4-methylpyridin-2-yl)pyrrole-3-carbaldehyde Chemical compound CC1=CC(C=O)=C(C)N1C1=CC(C)=CC=N1 PIGJZPZYWKFDBR-UHFFFAOYSA-N 0.000 abstract 1
- DGXAGETVRDOQFP-UHFFFAOYSA-N 2,6-dihydroxybenzaldehyde Chemical compound OC1=CC=CC(O)=C1C=O DGXAGETVRDOQFP-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- FEUFEGJTJIHPOF-UHFFFAOYSA-N 2-butyl acrylic acid Chemical compound CCCCC(=C)C(O)=O FEUFEGJTJIHPOF-UHFFFAOYSA-N 0.000 abstract 1
- TVONJMOVBKMLOM-UHFFFAOYSA-N 2-methylidenebutanenitrile Chemical compound CCC(=C)C#N TVONJMOVBKMLOM-UHFFFAOYSA-N 0.000 abstract 1
- OHXAOPZTJOUYKM-UHFFFAOYSA-N 3-Chloro-2-methylpropene Chemical compound CC(=C)CCl OHXAOPZTJOUYKM-UHFFFAOYSA-N 0.000 abstract 1
- ZXABMDQSAABDMG-UHFFFAOYSA-N 3-ethenoxyprop-1-ene Chemical compound C=CCOC=C ZXABMDQSAABDMG-UHFFFAOYSA-N 0.000 abstract 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 abstract 1
- FKWUKKNHLHTXJE-UHFFFAOYSA-N 5-o-ethenyl 1-o-methyl pentanedioate Chemical compound COC(=O)CCCC(=O)OC=C FKWUKKNHLHTXJE-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 abstract 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004641 Diallyl-phthalate Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical group CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229940050390 benzoate Drugs 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- AJCHRUXIDGEWDK-UHFFFAOYSA-N bis(ethenyl) butanedioate Chemical compound C=COC(=O)CCC(=O)OC=C AJCHRUXIDGEWDK-UHFFFAOYSA-N 0.000 abstract 1
- JZQAAQZDDMEFGZ-UHFFFAOYSA-N bis(ethenyl) hexanedioate Chemical compound C=COC(=O)CCCCC(=O)OC=C JZQAAQZDDMEFGZ-UHFFFAOYSA-N 0.000 abstract 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 abstract 1
- HABAXTXIECRCKH-UHFFFAOYSA-N bis(prop-2-enyl) butanedioate Chemical compound C=CCOC(=O)CCC(=O)OCC=C HABAXTXIECRCKH-UHFFFAOYSA-N 0.000 abstract 1
- FPODCVUTIPDRTE-UHFFFAOYSA-N bis(prop-2-enyl) hexanedioate Chemical compound C=CCOC(=O)CCCCC(=O)OCC=C FPODCVUTIPDRTE-UHFFFAOYSA-N 0.000 abstract 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000004651 carbonic acid esters Chemical class 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-M chloroacetate Chemical compound [O-]C(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-M 0.000 abstract 1
- 229940089960 chloroacetate Drugs 0.000 abstract 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- IEPRKVQEAMIZSS-AATRIKPKSA-N diethyl fumarate Chemical compound CCOC(=O)\C=C\C(=O)OCC IEPRKVQEAMIZSS-AATRIKPKSA-N 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 abstract 1
- IYNRVIKPUTZSOR-HWKANZROSA-N ethenyl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC=C IYNRVIKPUTZSOR-HWKANZROSA-N 0.000 abstract 1
- FFYWKOUKJFCBAM-UHFFFAOYSA-N ethenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC=C FFYWKOUKJFCBAM-UHFFFAOYSA-N 0.000 abstract 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 abstract 1
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 abstract 1
- 238000009775 high-speed stirring Methods 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- 238000010030 laminating Methods 0.000 abstract 1
- 229940070765 laurate Drugs 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 125000005394 methallyl group Chemical group 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 abstract 1
- WLJVNTCWHIRURA-UHFFFAOYSA-L pimelate(2-) Chemical compound [O-]C(=O)CCCCCC([O-])=O WLJVNTCWHIRURA-UHFFFAOYSA-L 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical class CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- UBLMWQYLVOVZMT-UHFFFAOYSA-N tert-butyl n-(3-acetylphenyl)carbamate Chemical compound CC(=O)C1=CC=CC(NC(=O)OC(C)(C)C)=C1 UBLMWQYLVOVZMT-UHFFFAOYSA-N 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
- 229940070710 valerate Drugs 0.000 abstract 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 abstract 1
- 229940117958 vinyl acetate Drugs 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Polymers are made by subjecting a mixture of a polymerizable monomeric olefinic compound and a linear polymer of M.W. at least 1 X 104, in the absence of oxygen, and optionally in the presence of an inert solvent or diluent, and/or light, to an agitation treatment sufficient to degrade the linear polymer whereby a polymer is obtained in the molecular structure of which the olefinic compound forms a part. The agitation treatment used may be high speed stirring, e.g. 4000 r.p.m., shaking, e.g. at 330 strokes per minute, milling, kneading, grinding, ultrasonic vibrations, e.g. at a frequency of 500 kilocycles, and passage through a filter or capillary tubes at high linear velocity, e.g. under a pressure of 1000 lb./sq. inch at the rate of about 100 parts per minute. The linear polymers may be cellulose acetate or nitrate or propionate or butyrate or acetobutyrate, ethyl or butyl or propyl cellulose, phenol-aldehydes, resorcinol-formaldehyde, alkyd resins, e.g. polyesters of glycol and phthalic acid, 1 : 3-pentanediol and succinic acid, glycol and glutaric acid, linear polyamides, e.g. by reacting trimethyladipic acid with hexamethylenediamine, polymers of ethylene oxide and tetrahydrofuran, polymers of carbonic acid esters of unsaturated diols such as butadiene-3 : 4-carbonate, polymers of diethyl fumarate or maleate, polymers of butadiene - 1 : 3, 2 : 3 - dimethyl butadiene-1 : 3, piperylene, isoprene, chloroprene, styrene, alpha - methylstyrene, dichlorostyrene, vinyl naphthalene, vinyl phenol, acrylic acid, alphamethyl and butyl acrylic acid, methyl and propyl acrylates, methyl methacrylate, butyl methacrylate, vinylidene chloride and bromide, vinyl chloride and bromide, acrylonitrile, methacrylonitrile, vinyl acetate, or chloroacetate, or benzoate, or laurate, or valerate, or caproate, divinyl succinate, divinyl adipate, vinyl allyl phthalate, vinyl methallyl pimelate, vinyl methyl glutarate, vinyl acrylate, vinyl crotonate, vinyl methacrylate, vinyl ethyl ether, vinyl butyl ether, vinyl allyl ether, vinyl butyl ketone, vinyl ethyl ketone, isobutylene and copolymers of vinyl chloride/vinylidene chloride, methacrylonitrile/methyl methacrylate, styrene/vinyl chloride, vinyl fluoride/ethacrylonitrile, methyl methacrylate / methyl - styrene/methacrylonitrile, vinylidene chloride/vinyl chloride/methyl methacrylate, and vinyl acetate/vinyl butyrate / methyl methacrylate / methacrylonitrile. The monomeric olefinic compounds may be the monomers of the polymers mentioned above from butadiene-1 : 3 to isobutylene and in addition allyl acetate or butyrate, diallyl phthalate, diallyl adipate, diallyl succinate, allyl chloride, methallyl chloride, allyl acrylate, allyl crotonate, methallyl methacrylate and allyl ketones and ethers. The polymers may be made in batches, semi-continuously or continuously. The inert solvents or diluents specified are water, benzene, toluene, cyclohexanone, cyclohexane, xylene, hexane, methyl ethyl ketone, dibutyl ether and mixtures. The polymer may be moulded, and machined, e.g. into buttons, table tops and containers, or used in the molten state, or in a solvent solution, as an impregnant, or a laminating or coating agent.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US286509XA | 1948-11-16 | 1948-11-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB679562A true GB679562A (en) | 1952-09-17 |
Family
ID=21844655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB29343/49A Expired GB679562A (en) | 1948-11-16 | 1949-11-16 | Polymers and a process for the preparation thereof |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE492180A (en) |
| CH (1) | CH286509A (en) |
| DE (1) | DE842407C (en) |
| FR (1) | FR999594A (en) |
| GB (1) | GB679562A (en) |
Cited By (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2763631A (en) * | 1952-05-23 | 1956-09-18 | Eastman Kodak Co | Acrylonitrile polymers containing vinyl chloride or vinylidene chloride |
| US2779025A (en) * | 1953-08-27 | 1957-01-29 | Firestone Tire & Rubber Co | New polymeric material containing copolymerized monochlorotrifluoroethylene and an alkyl vinyl ether |
| US2794793A (en) * | 1952-10-21 | 1957-06-04 | Eastman Kodak Co | Copolymerization of ethenoid monomers in the presence of polyacrylonitrile |
| US2816087A (en) * | 1954-02-10 | 1957-12-10 | Eastman Kodak Co | Modified polyvinyl alcohol polymers and their preparation |
| US2830032A (en) * | 1954-01-15 | 1958-04-08 | Basf Ag | Cross-linked copolymers of a polymerizable monomer with an unsaturated copolymer of a vinyl ether and vinyl allyl ether and process for making same |
| US2835645A (en) * | 1955-01-05 | 1958-05-20 | Goodyear Tire & Rubber | High styrene-low diene resins of high heat softening point |
| US2837496A (en) * | 1952-12-31 | 1958-06-03 | Hercules Powder Co Ltd | Graft copolymers and preparation thereof from polymer hydroperoxides |
| US2838470A (en) * | 1954-02-03 | 1958-06-10 | Eastman Kodak Co | Copolymerization of acrylonitrile and another unsaturated monomer in the presence ofpreformed interpolymer |
| US2842518A (en) * | 1954-09-13 | 1958-07-08 | Borg Warner | Product produced by polymerization of vinylidene chloride-acrylonitrile mixtures onto polychloroprene |
| US2849419A (en) * | 1954-04-15 | 1958-08-26 | Firestone Tire & Rubber Co | Oriented filaments of graft copolymer of polyacrylate polymerized on vinylidene chloride resin |
| US2858281A (en) * | 1954-01-22 | 1958-10-28 | Goodrich Co B F | Insoluble, acid and alkali-resistant carboxylic polymers |
| US2859201A (en) * | 1953-11-09 | 1958-11-04 | Phillips Petroleum Co | Graft-type polymer of conjugated diene and acrylic acid and process of preparation |
| US2861973A (en) * | 1956-01-31 | 1958-11-25 | Borden Co | Moldable slurry comprising vinyl butyrate and polyethyl methacrylate and molding obtained therefrom |
| US2879254A (en) * | 1954-02-03 | 1959-03-24 | Eastman Kodak Co | Copolymerization of acrylonitrile and another monomer in the presence of preformed polymers and products obtained thereby |
| US2883360A (en) * | 1954-02-03 | 1959-04-21 | Eastman Kodak Co | Polymerization process for preparing modified acrylonitrile polymers |
| US2886551A (en) * | 1954-06-10 | 1959-05-12 | Diamond Alkali Co | Polymerization employing a phthalic glycerol alkyd resin as a suspension stabilizer |
| US2886552A (en) * | 1954-06-10 | 1959-05-12 | Diamond Alkali Co | Polymerization employing polyvinyl alkyl ethers as suspension stabilizers |
| US2903440A (en) * | 1958-04-08 | 1959-09-08 | Exxon Research Engineering Co | Thermo setting resin from a liquid butadiene polymer and styrene |
| US2908661A (en) * | 1957-01-11 | 1959-10-13 | Borg Warner | Polymerization of acrylonitrile-alpha methyl styrene mixtures onto polybutadiene and products produced thereby |
| US2941990A (en) * | 1957-07-15 | 1960-06-21 | American Cyanamid Co | Cyanoethylated polymers |
| US2949437A (en) * | 1957-10-02 | 1960-08-16 | Chemstrand Corp | Composition containing blend of acrylonitrile copolymers and chlorine-containing polymer |
| US2961423A (en) * | 1958-04-03 | 1960-11-22 | Monsanto Chemicals | Crossed-linked styrene-allyl alcohol copolymers as binders for fibrous fillers and structural units manufactured therefrom |
| US2961432A (en) * | 1952-11-19 | 1960-11-22 | Basf Ag | Bulk polymerization comprising polymerizing a liquid monomer in the presence of a polymer powder |
| US2961421A (en) * | 1958-02-17 | 1960-11-22 | Monsanto Chemicals | Interpolymer latices comprising acrylates and monovinylidene aromatic hydrocarbons, process of preparing same and cellulose coated therewith |
| US2963453A (en) * | 1957-03-15 | 1960-12-06 | Rohm & Haas | Acrylic and methacrylic acid resins controllably crosslinked with polyallyl acrylate, its substituted derivatives, and copolymers thereof |
| US2981650A (en) * | 1955-02-25 | 1961-04-25 | Degussa | Adhesives, cements and the like |
| US2992203A (en) * | 1957-03-25 | 1961-07-11 | Rohm & Haas | High impact resistant polymers derived primarily from esters of acrylic and methacrylic acids |
| US3019208A (en) * | 1954-01-18 | 1962-01-30 | Firestone Tire & Rubber Co | Method of making graft copolymers of vinyl chloride and polyacrylate |
| US3020257A (en) * | 1958-02-12 | 1962-02-06 | Haris Co Ltd | Method for manufacture of polyisobutylene-vinyl acetate graft copolymer |
| DE1123476B (en) * | 1953-09-08 | 1962-02-08 | Phil Oliver Wallis Burke Jun D | Process for the production of insoluble, crosslinked high polymers of colloidal particle size |
| US3041309A (en) * | 1959-04-24 | 1962-06-26 | Monsanto Chemicals | Blend of styrene copolymer with a graft-copolymer of an alkyl methacrylate upon an alkyl acrylate polymer |
| US3055859A (en) * | 1956-09-28 | 1962-09-25 | Basf Ag | Impact-resistant plastic compositions comprising a styrene polymer and a cross-linked acrylic acid ester polymer, and process for preparing same |
| US3061581A (en) * | 1959-07-09 | 1962-10-30 | Nat Distillers Chem Corp | Vinyl modification of branched chain polyamides |
| US3061582A (en) * | 1959-07-09 | 1962-10-30 | Nat Distillers Chem Corp | Ethylenic modification of branched chain polyamides |
| US3062777A (en) * | 1953-04-14 | 1962-11-06 | Union Carbide Corp | Graft copolymers of styrene on butadiene rubbers and method for making same |
| US3074866A (en) * | 1958-01-06 | 1963-01-22 | Alelio Gaetano F D | Irradiated polymers |
| US3075905A (en) * | 1958-01-06 | 1963-01-29 | Alelio Gaetano F D | Irradiated polymers |
| US3075904A (en) * | 1958-01-06 | 1963-01-29 | Alelio Gaetano F D | Irradiated polymers |
| US3081168A (en) * | 1954-03-26 | 1963-03-12 | Time Inc | Polyamide photographic printing plate and method of using same |
| US3082161A (en) * | 1958-01-06 | 1963-03-19 | Alelio Gaetano F D | Irradiated polymers |
| US3091595A (en) * | 1956-03-22 | 1963-05-28 | Shell Oil Co | Cyano-substituted polyamides and their use as curing agents for polyepoxides |
| US3092512A (en) * | 1957-10-31 | 1963-06-04 | Table ii | |
| US3099631A (en) * | 1958-03-06 | 1963-07-30 | Du Pont | Nitrogenous condensation polymer containing grafted acid |
| US3113912A (en) * | 1959-07-16 | 1963-12-10 | Phillips Petroleum Co | Preparation of vulcanizates by irradiation of block copolymers |
| US3128528A (en) * | 1960-04-28 | 1964-04-14 | Du Pont | Preparation of hydroset textile material |
| US3135717A (en) * | 1960-02-10 | 1964-06-02 | Grace W R & Co | Process of forming graft copolymers of polystyrene and polyvinyl chloride |
| US3177269A (en) * | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and acrylic and methacrylic acid and method of making the same |
| US3177270A (en) * | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and monovinyl aromatic compounds and method of making the same |
| US3188228A (en) * | 1958-05-14 | 1965-06-08 | Du Pont | Method of graft polymerizing an organic compound to a solid shaped condensation polymer structure |
| US3261887A (en) * | 1958-02-14 | 1966-07-19 | Us Rubber Co | Transparent gum plastic composition containing methyl methacrylate resin and graft copolymer |
| US3261885A (en) * | 1960-10-07 | 1966-07-19 | Roemmler Gmbh H | Production of block-graft copolymers from polyolefines and synthetic polyamides |
| US3294711A (en) * | 1963-04-22 | 1966-12-27 | Bayer Ag | Graft polymers of vinyl acetate or vinyl chloride onto a saturated polyester backbone, and polyurethane foams therefrom |
| US3296339A (en) * | 1966-01-20 | 1967-01-03 | Rohm & Haas | Thermoplastic compositions formed by polymerizing methacrylic acid esters and polybutadiene latices |
| US3297471A (en) * | 1965-04-08 | 1967-01-10 | Du Pont | Acrylic or methacrylic acid grafting copolymerized on nylon and forming salt of said graft |
| US3413378A (en) * | 1966-11-14 | 1968-11-26 | Du Pont | Graft copolymers of nitrile groups on polyamide substrates |
| EP0344699A3 (en) * | 1988-06-02 | 1991-03-27 | Bromine Compounds Ltd. | Process for the polymerization of pentabromobenzylester monoacrylate |
| US6228948B1 (en) | 1998-01-16 | 2001-05-08 | E. I. Du Pont De Nemours And Company | High melt flow, highly-grafted polypropylene |
| DE102007011825B3 (en) * | 2007-03-12 | 2008-05-15 | Deutsche Gumtec Ag | Preparing polar modified rubber and thermoplastic wastes, useful e.g. as adsorbents, comprises grinding vulcanized elastomer or olefinic thermoplast and mixing the grounded material with an organic peroxide and a polar monomer |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2899405A (en) * | 1959-08-11 | Polymerization of vinyl chloride or | ||
| US2741650A (en) * | 1951-11-08 | 1956-04-10 | Shawinigan Resins Corp | Styrene-modified polyvinyl acetate resins |
| US2719136A (en) * | 1951-11-29 | 1955-09-27 | Eastman Kodak Co | Compositions from polymerizing acrylonitrile in the presence of maleic anhydride copolymers |
| US2773050A (en) * | 1952-04-30 | 1956-12-04 | Eastman Kodak Co | Water vapor permeable compositions and articles containing a polyacrylic ester and polyvinyl alcohol |
| US2879253A (en) * | 1954-02-03 | 1959-03-24 | Eastman Kodak Co | Copolymerization of acrylonitrile and another unsaturated monomer, in the presence of preformed homopolymers and products obtained thereby |
| US2713568A (en) * | 1953-03-04 | 1955-07-19 | Firestone Tire & Rubber Co | Stripping vinylidene-vinyl chloride copolymers with aid of alkyl acrylate and product |
| US2784172A (en) * | 1953-04-27 | 1957-03-05 | Monsanto Chemicals | Acrylonitrile copolymers stabilized with acrylic acid salts |
| US2879256A (en) * | 1954-11-26 | 1959-03-24 | Eastman Kodak Co | Continuous process for preparing vinyl or vinylidene chloride graft polymers of improved solubility |
| DE1012071B (en) * | 1955-02-22 | 1957-07-11 | Courtaulds Ltd | Process for the production of block copolymers |
| NL104706C (en) * | 1955-12-09 | 1963-05-15 | ||
| US2991269A (en) * | 1956-02-21 | 1961-07-04 | Shell Oil Co | Process for preparing block copolymers by degrading a preformed polymer in the presence of dissimilar monomer |
| US2905653A (en) * | 1957-05-14 | 1959-09-22 | Firestone Tire & Rubber Co | Oriented products from graft copolymers of vinyl ester on acrylonitrile polymer |
| NL301879A (en) * | 1962-12-26 |
-
0
- BE BE492180D patent/BE492180A/xx unknown
-
1949
- 1949-11-04 DE DEN124A patent/DE842407C/en not_active Expired
- 1949-11-15 FR FR999594D patent/FR999594A/en not_active Expired
- 1949-11-15 CH CH286509D patent/CH286509A/en unknown
- 1949-11-16 GB GB29343/49A patent/GB679562A/en not_active Expired
Cited By (60)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2763631A (en) * | 1952-05-23 | 1956-09-18 | Eastman Kodak Co | Acrylonitrile polymers containing vinyl chloride or vinylidene chloride |
| US2794793A (en) * | 1952-10-21 | 1957-06-04 | Eastman Kodak Co | Copolymerization of ethenoid monomers in the presence of polyacrylonitrile |
| US2961432A (en) * | 1952-11-19 | 1960-11-22 | Basf Ag | Bulk polymerization comprising polymerizing a liquid monomer in the presence of a polymer powder |
| US2837496A (en) * | 1952-12-31 | 1958-06-03 | Hercules Powder Co Ltd | Graft copolymers and preparation thereof from polymer hydroperoxides |
| US3062777A (en) * | 1953-04-14 | 1962-11-06 | Union Carbide Corp | Graft copolymers of styrene on butadiene rubbers and method for making same |
| US2779025A (en) * | 1953-08-27 | 1957-01-29 | Firestone Tire & Rubber Co | New polymeric material containing copolymerized monochlorotrifluoroethylene and an alkyl vinyl ether |
| DE1123476B (en) * | 1953-09-08 | 1962-02-08 | Phil Oliver Wallis Burke Jun D | Process for the production of insoluble, crosslinked high polymers of colloidal particle size |
| US2859201A (en) * | 1953-11-09 | 1958-11-04 | Phillips Petroleum Co | Graft-type polymer of conjugated diene and acrylic acid and process of preparation |
| US2830032A (en) * | 1954-01-15 | 1958-04-08 | Basf Ag | Cross-linked copolymers of a polymerizable monomer with an unsaturated copolymer of a vinyl ether and vinyl allyl ether and process for making same |
| US3019208A (en) * | 1954-01-18 | 1962-01-30 | Firestone Tire & Rubber Co | Method of making graft copolymers of vinyl chloride and polyacrylate |
| US2858281A (en) * | 1954-01-22 | 1958-10-28 | Goodrich Co B F | Insoluble, acid and alkali-resistant carboxylic polymers |
| US2879254A (en) * | 1954-02-03 | 1959-03-24 | Eastman Kodak Co | Copolymerization of acrylonitrile and another monomer in the presence of preformed polymers and products obtained thereby |
| US2883360A (en) * | 1954-02-03 | 1959-04-21 | Eastman Kodak Co | Polymerization process for preparing modified acrylonitrile polymers |
| US2838470A (en) * | 1954-02-03 | 1958-06-10 | Eastman Kodak Co | Copolymerization of acrylonitrile and another unsaturated monomer in the presence ofpreformed interpolymer |
| US2816087A (en) * | 1954-02-10 | 1957-12-10 | Eastman Kodak Co | Modified polyvinyl alcohol polymers and their preparation |
| US3081168A (en) * | 1954-03-26 | 1963-03-12 | Time Inc | Polyamide photographic printing plate and method of using same |
| US2849419A (en) * | 1954-04-15 | 1958-08-26 | Firestone Tire & Rubber Co | Oriented filaments of graft copolymer of polyacrylate polymerized on vinylidene chloride resin |
| US2886551A (en) * | 1954-06-10 | 1959-05-12 | Diamond Alkali Co | Polymerization employing a phthalic glycerol alkyd resin as a suspension stabilizer |
| US2886552A (en) * | 1954-06-10 | 1959-05-12 | Diamond Alkali Co | Polymerization employing polyvinyl alkyl ethers as suspension stabilizers |
| US2842518A (en) * | 1954-09-13 | 1958-07-08 | Borg Warner | Product produced by polymerization of vinylidene chloride-acrylonitrile mixtures onto polychloroprene |
| US2835645A (en) * | 1955-01-05 | 1958-05-20 | Goodyear Tire & Rubber | High styrene-low diene resins of high heat softening point |
| US2981650A (en) * | 1955-02-25 | 1961-04-25 | Degussa | Adhesives, cements and the like |
| US2861973A (en) * | 1956-01-31 | 1958-11-25 | Borden Co | Moldable slurry comprising vinyl butyrate and polyethyl methacrylate and molding obtained therefrom |
| US3091595A (en) * | 1956-03-22 | 1963-05-28 | Shell Oil Co | Cyano-substituted polyamides and their use as curing agents for polyepoxides |
| US3055859A (en) * | 1956-09-28 | 1962-09-25 | Basf Ag | Impact-resistant plastic compositions comprising a styrene polymer and a cross-linked acrylic acid ester polymer, and process for preparing same |
| US2908661A (en) * | 1957-01-11 | 1959-10-13 | Borg Warner | Polymerization of acrylonitrile-alpha methyl styrene mixtures onto polybutadiene and products produced thereby |
| US2963453A (en) * | 1957-03-15 | 1960-12-06 | Rohm & Haas | Acrylic and methacrylic acid resins controllably crosslinked with polyallyl acrylate, its substituted derivatives, and copolymers thereof |
| US2992203A (en) * | 1957-03-25 | 1961-07-11 | Rohm & Haas | High impact resistant polymers derived primarily from esters of acrylic and methacrylic acids |
| US2941990A (en) * | 1957-07-15 | 1960-06-21 | American Cyanamid Co | Cyanoethylated polymers |
| US2949437A (en) * | 1957-10-02 | 1960-08-16 | Chemstrand Corp | Composition containing blend of acrylonitrile copolymers and chlorine-containing polymer |
| US3092512A (en) * | 1957-10-31 | 1963-06-04 | Table ii | |
| US3074866A (en) * | 1958-01-06 | 1963-01-22 | Alelio Gaetano F D | Irradiated polymers |
| US3075905A (en) * | 1958-01-06 | 1963-01-29 | Alelio Gaetano F D | Irradiated polymers |
| US3075904A (en) * | 1958-01-06 | 1963-01-29 | Alelio Gaetano F D | Irradiated polymers |
| US3082161A (en) * | 1958-01-06 | 1963-03-19 | Alelio Gaetano F D | Irradiated polymers |
| US3020257A (en) * | 1958-02-12 | 1962-02-06 | Haris Co Ltd | Method for manufacture of polyisobutylene-vinyl acetate graft copolymer |
| US3261887A (en) * | 1958-02-14 | 1966-07-19 | Us Rubber Co | Transparent gum plastic composition containing methyl methacrylate resin and graft copolymer |
| US2961421A (en) * | 1958-02-17 | 1960-11-22 | Monsanto Chemicals | Interpolymer latices comprising acrylates and monovinylidene aromatic hydrocarbons, process of preparing same and cellulose coated therewith |
| US3099631A (en) * | 1958-03-06 | 1963-07-30 | Du Pont | Nitrogenous condensation polymer containing grafted acid |
| US2961423A (en) * | 1958-04-03 | 1960-11-22 | Monsanto Chemicals | Crossed-linked styrene-allyl alcohol copolymers as binders for fibrous fillers and structural units manufactured therefrom |
| US2903440A (en) * | 1958-04-08 | 1959-09-08 | Exxon Research Engineering Co | Thermo setting resin from a liquid butadiene polymer and styrene |
| US3188228A (en) * | 1958-05-14 | 1965-06-08 | Du Pont | Method of graft polymerizing an organic compound to a solid shaped condensation polymer structure |
| US3041309A (en) * | 1959-04-24 | 1962-06-26 | Monsanto Chemicals | Blend of styrene copolymer with a graft-copolymer of an alkyl methacrylate upon an alkyl acrylate polymer |
| US3041308A (en) * | 1959-04-24 | 1962-06-26 | Monsanto Chemicals | Blend of styrene copolymer with a graft-copolymer of styrene and an alkyl methacrylate upon an alkyl acrylate polymer |
| US3041306A (en) * | 1959-04-24 | 1962-06-26 | Monsanto Chemicals | Blend of a styrene copolymer with a graft-copolymer of styrene upon an alkyl acrylate polymer |
| US3061581A (en) * | 1959-07-09 | 1962-10-30 | Nat Distillers Chem Corp | Vinyl modification of branched chain polyamides |
| US3061582A (en) * | 1959-07-09 | 1962-10-30 | Nat Distillers Chem Corp | Ethylenic modification of branched chain polyamides |
| US3113912A (en) * | 1959-07-16 | 1963-12-10 | Phillips Petroleum Co | Preparation of vulcanizates by irradiation of block copolymers |
| US3135717A (en) * | 1960-02-10 | 1964-06-02 | Grace W R & Co | Process of forming graft copolymers of polystyrene and polyvinyl chloride |
| US3128528A (en) * | 1960-04-28 | 1964-04-14 | Du Pont | Preparation of hydroset textile material |
| US3261885A (en) * | 1960-10-07 | 1966-07-19 | Roemmler Gmbh H | Production of block-graft copolymers from polyolefines and synthetic polyamides |
| US3177270A (en) * | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and monovinyl aromatic compounds and method of making the same |
| US3177269A (en) * | 1960-10-10 | 1965-04-06 | Dow Chemical Co | Graft copolymers of polyolefins and acrylic and methacrylic acid and method of making the same |
| US3294711A (en) * | 1963-04-22 | 1966-12-27 | Bayer Ag | Graft polymers of vinyl acetate or vinyl chloride onto a saturated polyester backbone, and polyurethane foams therefrom |
| US3297471A (en) * | 1965-04-08 | 1967-01-10 | Du Pont | Acrylic or methacrylic acid grafting copolymerized on nylon and forming salt of said graft |
| US3296339A (en) * | 1966-01-20 | 1967-01-03 | Rohm & Haas | Thermoplastic compositions formed by polymerizing methacrylic acid esters and polybutadiene latices |
| US3413378A (en) * | 1966-11-14 | 1968-11-26 | Du Pont | Graft copolymers of nitrile groups on polyamide substrates |
| EP0344699A3 (en) * | 1988-06-02 | 1991-03-27 | Bromine Compounds Ltd. | Process for the polymerization of pentabromobenzylester monoacrylate |
| US6228948B1 (en) | 1998-01-16 | 2001-05-08 | E. I. Du Pont De Nemours And Company | High melt flow, highly-grafted polypropylene |
| DE102007011825B3 (en) * | 2007-03-12 | 2008-05-15 | Deutsche Gumtec Ag | Preparing polar modified rubber and thermoplastic wastes, useful e.g. as adsorbents, comprises grinding vulcanized elastomer or olefinic thermoplast and mixing the grounded material with an organic peroxide and a polar monomer |
Also Published As
| Publication number | Publication date |
|---|---|
| DE842407C (en) | 1952-06-26 |
| BE492180A (en) | |
| FR999594A (en) | 1952-02-01 |
| CH286509A (en) | 1952-10-31 |
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