GB607978A - Improvements in and relating to method of producing vanillin - Google Patents
Improvements in and relating to method of producing vanillinInfo
- Publication number
- GB607978A GB607978A GB1014/46A GB101446A GB607978A GB 607978 A GB607978 A GB 607978A GB 1014/46 A GB1014/46 A GB 1014/46A GB 101446 A GB101446 A GB 101446A GB 607978 A GB607978 A GB 607978A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxygen
- gas
- vanillin
- lignin
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 title abstract 4
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 title abstract 4
- 235000012141 vanillin Nutrition 0.000 title abstract 4
- 239000007789 gas Substances 0.000 abstract 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 4
- 239000001301 oxygen Substances 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- 229920005610 lignin Polymers 0.000 abstract 3
- 239000007800 oxidant agent Substances 0.000 abstract 3
- 239000000126 substance Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 abstract 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- 229910000420 cerium oxide Inorganic materials 0.000 abstract 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 abstract 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 abstract 1
- 229910000428 cobalt oxide Inorganic materials 0.000 abstract 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 229910000464 lead oxide Inorganic materials 0.000 abstract 1
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000035484 reaction time Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
- C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
<PICT:0607978/IV(b)/1> Vanillin is obtained by suspending or dissolving lignin-containing substances in an alkaline medium and subjecting the same to the action of a finely divided gas containing oxygen such as air such that the partial pressure of oxygen in the raction vessel is less than 20 pounds per square inch at a temperature in excess of 150 DEG C., the reaction time being less than four hours. In a preferred feature of the invention the treatment with the oxidizing gas is carried out in the presence of a catalyst. The catalyst which is used consists either of the sludge residual in a reaction mixture in which vanillin has been produced by subjecting lignin-containing substances to the action of an oxygen containing gas in an alkaline medium to which has been added an auxiliary oxidizing agent, or of one of certain specific auxiliary oxidizing agents which have been used to obtain vanillin from lignin containing substances. Such oxidizing agents comprise inorganic oxides and salts which are easily reduced under alkaline conditions and include copper oxide, copper sulphate, cobalt oxide, cobalt nitrate, cerium oxide, lead oxide, manganese dioxide, and ferric chloride. The reaction is preferably carried out in an apparatus which comprises a bomb 1, fitted with an exit 3 in the cover 2 through which vapours pass to the condensing system 4 which terminates in a control relief valve 5 set to a predetermined pressure. An oxygen-containing gas is introduced through a porous plate 6. The bomb is also fitted with a pressure gauge 11 and a thermometer 13, and heated by gas flame 14. Examples are given of varying reaction conditions within the invention.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA607978X | 1945-07-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB607978A true GB607978A (en) | 1948-09-08 |
Family
ID=4171939
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1014/46A Expired GB607978A (en) | 1945-07-09 | 1946-01-11 | Improvements in and relating to method of producing vanillin |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB607978A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2598311A (en) * | 1952-05-27 | Manufacture of vanillin | ||
| US2692291A (en) * | 1950-06-06 | 1954-10-19 | Monsanto Chemicals | Manufacture of vanillin from lignin |
| DE1009472B (en) * | 1953-04-16 | 1957-05-29 | Waldhof Zellstoff Fab | Process for the production of cellulose with the recovery of other valuable substances such as vanillin, acetovanillon and dioxystilbene |
-
1946
- 1946-01-11 GB GB1014/46A patent/GB607978A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2598311A (en) * | 1952-05-27 | Manufacture of vanillin | ||
| US2692291A (en) * | 1950-06-06 | 1954-10-19 | Monsanto Chemicals | Manufacture of vanillin from lignin |
| DE1009472B (en) * | 1953-04-16 | 1957-05-29 | Waldhof Zellstoff Fab | Process for the production of cellulose with the recovery of other valuable substances such as vanillin, acetovanillon and dioxystilbene |
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