GB586637A - Process for stabilizing textile material - Google Patents
Process for stabilizing textile materialInfo
- Publication number
- GB586637A GB586637A GB5257/44A GB525744A GB586637A GB 586637 A GB586637 A GB 586637A GB 5257/44 A GB5257/44 A GB 5257/44A GB 525744 A GB525744 A GB 525744A GB 586637 A GB586637 A GB 586637A
- Authority
- GB
- United Kingdom
- Prior art keywords
- viscose
- urea
- fibres
- solution
- formaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 9
- 239000004753 textile Substances 0.000 title abstract 5
- 230000000087 stabilizing effect Effects 0.000 title 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 6
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 abstract 6
- 229920000297 Rayon Polymers 0.000 abstract 5
- 239000004744 fabric Substances 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 229920002301 cellulose acetate Polymers 0.000 abstract 3
- 229940015043 glyoxal Drugs 0.000 abstract 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000005018 casein Substances 0.000 abstract 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 2
- 235000021240 caseins Nutrition 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 235000006408 oxalic acid Nutrition 0.000 abstract 2
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 abstract 2
- 235000018102 proteins Nutrition 0.000 abstract 2
- 102000004169 proteins and genes Human genes 0.000 abstract 2
- 108090000623 proteins and genes Proteins 0.000 abstract 2
- 239000004627 regenerated cellulose Substances 0.000 abstract 2
- 229920001187 thermosetting polymer Polymers 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- PUMIBBNWDCWIKR-UHFFFAOYSA-M 1-(octadecoxymethyl)pyridin-1-ium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCOC[N+]1=CC=CC=C1 PUMIBBNWDCWIKR-UHFFFAOYSA-M 0.000 abstract 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 abstract 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- 235000017060 Arachis glabrata Nutrition 0.000 abstract 1
- 244000105624 Arachis hypogaea Species 0.000 abstract 1
- 235000010777 Arachis hypogaea Nutrition 0.000 abstract 1
- 235000018262 Arachis monticola Nutrition 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- -1 acridinium compound Chemical class 0.000 abstract 1
- 239000013543 active substance Substances 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 239000001166 ammonium sulphate Substances 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-O hydron;quinoline Chemical compound [NH+]1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-O 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 235000020232 peanut Nutrition 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 1
- 239000012262 resinous product Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 210000002268 wool Anatomy 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/123—Polyaldehydes; Polyketones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Textile material formed predominantly of regenerated cellulose is stabilized with respect to dimensional shrinkage and is rendered resistant to wrinkling, crushing and creasing without impairing its original softness, by treating it with an aqueous solution containing the equivalent of 15-120 c.c. of 30 per cent by weight glyoxal solution and 0.125 to 4 grams of an acidic catalyst and 12-50 grams in all of one or more amino-aldehyde water-dispersible thermosetting resinous condensation products per litre of treating solution, and baking the treated textile material at 212-350 DEG F. for 40-2 minutes so as to effect a reaction between the glyoxal and the fibres of the material. A soft hand or feel may be imparted to the material by including in the treating bath a cation-active softener. The textile material may be in the form of fibres, yarns, fabrics or garments. The acidic catalyst may be oxalic acid, ammonium chloride, ammonium sulphate, or ammonium nitrate. In an example, viscose rayon fabric is impregnated with a solution in water of glyoxal with oxalic acid and urea-formaldehyde condensed to a stage such that it is completely dispersible in water but not sufficiently soluble to produce a clear solution. The fabric is squeezed, dried on a tenter frame and then cured in a hot oven. In other examples, fabric of viscose and cellulose acetate, and fabric of viscose and casein fibres, are subjected to the treatment. Urea-formaldehyde, a urea - butyl - urea - formaldehyde p co-condensation product, or melamine-formaldehyde is used as the thermosetting resinous product. Mixtures of these compounds may be used. In another example, the impregnating solution contains a quaternary ammonium compound, octadecyl oxymethyl pyridinium chloride. The cation-active substance may be a quinolinium, or acridinium compound. It may be the salt of a strong or weak acid, e.g. hydrochloric, acetic or formic acid. The treatment may be applied to viscose, cuprammonium and completely saponified cellulose acetate materials. It is also applicable to materials containing regenerated cellulose and other fibres, e.g. viscose and cellulose acetate, casein, soyabean protein, peanut protein, wool or cotton. Specification 585,679 is referred to. The Specification as open to inspection under Sect. 91 comprises also the treatment of cotton and other textile materials. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US508368A US2412832A (en) | 1943-10-30 | 1943-10-30 | Textile material and method of preparing it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB586637A true GB586637A (en) | 1947-03-26 |
Family
ID=24022474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5257/44A Expired GB586637A (en) | 1943-10-30 | 1944-03-21 | Process for stabilizing textile material |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2412832A (en) |
| GB (1) | GB586637A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1042517B (en) * | 1953-09-03 | 1958-11-06 | Basf Ag | Process for the crease-proof finishing of textiles made of cellulose with dialdehydes |
| US4269602A (en) | 1979-05-07 | 1981-05-26 | Riegel Textile Corporation | Buffered non-formaldehyde durable press textile treatment |
| US4269603A (en) | 1979-05-04 | 1981-05-26 | Riegel Textile Corporation | Non-formaldehyde durable press textile treatment |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2484545A (en) * | 1947-01-18 | 1949-10-11 | Alrose Chemical Company | Shrinkage control of cellulosic fibers |
| US2574114A (en) * | 1948-04-26 | 1951-11-06 | Bozel Maletra Prod Chimiques | Amide-glyoxal-formaldehyde reaction product and shrinkproofing cellulose textile fibers therewith |
| US2521328A (en) * | 1948-10-14 | 1950-09-05 | Alrose Chemical Company | Stabilizing cellulosic textile materials against shrinkage employing glyoxal and a metal silicofluoride as a catalyst |
| US2549177A (en) * | 1949-03-21 | 1951-04-17 | Strathmore Paper Company | Sized paper, composition therefor, and method of making same |
| GB692258A (en) * | 1949-11-22 | 1953-06-03 | Stevensons Dyers Ltd | Improvements relating to the anti-shrink and anti-felt treatment of wool |
| US2922728A (en) * | 1956-11-05 | 1960-01-26 | American Enka Corp | Prevention of yellowing in freshly spun viscose rayon with tartaric, citric or gluconic acid |
| US3089747A (en) * | 1958-04-04 | 1963-05-14 | American Viscose Corp | Method of preparing rayon plisse |
| NL247426A (en) * | 1958-09-24 | |||
| BE600443A (en) * | 1958-12-24 | |||
| US3175874A (en) * | 1959-01-29 | 1965-03-30 | Deering Milliken Res Corp | Method of creaseproofing cellulosic fabrics by wet creaseproofing followed by dry creaseproofing and the resulting product |
| US3175875A (en) * | 1960-04-25 | 1965-03-30 | Deering Milliken Res Corp | Cellulosic fabrics and methods for making the same |
| US4304564A (en) * | 1980-05-05 | 1981-12-08 | The United States Of America As Represented By The Secretary Of Agriculture | Wrinkle-resistant and durable-press cotton-containing fabric by treatment with acrylamide and glyoxal |
| CN117344543A (en) * | 2023-11-06 | 2024-01-05 | 盐城工学院 | A method and application of in-situ preparation of conjugated Schiff base on cotton fabric |
-
1943
- 1943-10-30 US US508368A patent/US2412832A/en not_active Expired - Lifetime
-
1944
- 1944-03-21 GB GB5257/44A patent/GB586637A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1042517B (en) * | 1953-09-03 | 1958-11-06 | Basf Ag | Process for the crease-proof finishing of textiles made of cellulose with dialdehydes |
| US4269603A (en) | 1979-05-04 | 1981-05-26 | Riegel Textile Corporation | Non-formaldehyde durable press textile treatment |
| US4269602A (en) | 1979-05-07 | 1981-05-26 | Riegel Textile Corporation | Buffered non-formaldehyde durable press textile treatment |
Also Published As
| Publication number | Publication date |
|---|---|
| US2412832A (en) | 1946-12-17 |
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