GB516634A - Improvements in or relating to the production of solutions of low substituted cellulose ethers - Google Patents
Improvements in or relating to the production of solutions of low substituted cellulose ethersInfo
- Publication number
- GB516634A GB516634A GB19612/38A GB1961238A GB516634A GB 516634 A GB516634 A GB 516634A GB 19612/38 A GB19612/38 A GB 19612/38A GB 1961238 A GB1961238 A GB 1961238A GB 516634 A GB516634 A GB 516634A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solution
- cellulose
- sodium
- sodium zincate
- caustic soda
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003086 cellulose ether Polymers 0.000 title abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 18
- HVTHJRMZXBWFNE-UHFFFAOYSA-J sodium zincate Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Zn+2] HVTHJRMZXBWFNE-UHFFFAOYSA-J 0.000 abstract 7
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 6
- 229920002678 cellulose Polymers 0.000 abstract 5
- 239000001913 cellulose Substances 0.000 abstract 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 4
- 239000003518 caustics Substances 0.000 abstract 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000003513 alkali Substances 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- -1 alkali metal salt Chemical class 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 2
- 229920000609 methyl cellulose Polymers 0.000 abstract 2
- 239000001923 methylcellulose Substances 0.000 abstract 2
- 235000010981 methylcellulose Nutrition 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000004753 textile Substances 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/02—Alkyl or cycloalkyl ethers
- C08B11/04—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals
- C08B11/10—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals substituted with acid radicals
- C08B11/12—Alkyl or cycloalkyl ethers with substituted hydrocarbon radicals substituted with acid radicals substituted with carboxylic radicals, e.g. carboxymethylcellulose [CMC]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
516,634. Cellulose ether solutions; yarns and films; textile dressings. DU PONT DE NEMOURS & CO., E. I. July 1, 1938, No. 19612. Convention date, July 1, 1937. [Class 2 (ii)] Low substituted cellulose ethers are dissolved in aqueous caustic alkali in the presence of an alkali metal salt of an amphoteric oxide or hydroxide of an element of group II of the Periodic System, e.g. sodium zincate or sodium beryllate. In a modification, the salt is added to a preformed solution of the cellulose derivative. The alkali metal salt may be prepared by dissolving the amphoteric oxide, hydroxide, or salt thereof in the caustic soda solution. and may be present in concentration lying between 0.1 per cent. (calculated on the amphoteric oxide) and the saturation limit. In an example. (1) methyl cellulose soluble in cold caustic soda is slurried in a sodium zincate solution containing 6 per cent. of sodium hydroxide and 1-2 per cent. of zinc oxide, and the slurry cooled. The solution obtained is then brought back to room temperature. In other examples (2) glycol cellulose soluble in cold caustic alkali is slurried with sodium zincate solution and cooled, (3) cellulose glycollic acid soluble in dilute caustic soda is cooled with a solution of sodium zincate, (4) methyl cellulose insoluble in aqueous caustic solution is dissolved in a solution of sodium zincate, (5) glycol cellulose insoluble in aqueous caustic soda even on chilling, is dissolved in sodium zincate solution, and (6) cellulose glycollic acid insoluble in caustic soda solution even on chilling, is dissolved in aqueous sodium zincate. The solutions may be coagulated in yarn or film form or applied as textile or paper dressings and then coagulated.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US516634XA | 1937-07-01 | 1937-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB516634A true GB516634A (en) | 1940-01-08 |
Family
ID=21972646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19612/38A Expired GB516634A (en) | 1937-07-01 | 1938-07-01 | Improvements in or relating to the production of solutions of low substituted cellulose ethers |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB516634A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2420949A (en) * | 1943-09-11 | 1947-05-20 | Rohm & Haas | Carboxyalkyl cellulose ether fibers and films of good wet strength |
| US2495767A (en) * | 1946-08-09 | 1950-01-31 | Reid John David | Preparation of fibers from carboxymethylcellulose |
| DE752686C (en) * | 1940-10-15 | 1953-02-09 | Kalle & Co Ag | Process for the production of cellulose ethers |
-
1938
- 1938-07-01 GB GB19612/38A patent/GB516634A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE752686C (en) * | 1940-10-15 | 1953-02-09 | Kalle & Co Ag | Process for the production of cellulose ethers |
| US2420949A (en) * | 1943-09-11 | 1947-05-20 | Rohm & Haas | Carboxyalkyl cellulose ether fibers and films of good wet strength |
| US2495767A (en) * | 1946-08-09 | 1950-01-31 | Reid John David | Preparation of fibers from carboxymethylcellulose |
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