GB516344A - Improvements in or relating to the manufacture of artificial resins - Google Patents
Improvements in or relating to the manufacture of artificial resinsInfo
- Publication number
- GB516344A GB516344A GB14720/38A GB1472038A GB516344A GB 516344 A GB516344 A GB 516344A GB 14720/38 A GB14720/38 A GB 14720/38A GB 1472038 A GB1472038 A GB 1472038A GB 516344 A GB516344 A GB 516344A
- Authority
- GB
- United Kingdom
- Prior art keywords
- heated
- resin
- phenol
- hydrocarbons
- resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 title abstract 11
- 229920005989 resin Polymers 0.000 title abstract 11
- 238000004519 manufacturing process Methods 0.000 title 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 6
- 229930195733 hydrocarbon Natural products 0.000 abstract 6
- 150000002430 hydrocarbons Chemical class 0.000 abstract 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 4
- 239000000047 product Substances 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 239000002480 mineral oil Substances 0.000 abstract 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 2
- LCVCUJWKJNFDMY-UHFFFAOYSA-N 2,2-diphenylpropane-1,1-diol Chemical compound C=1C=CC=CC=1C(C(O)O)(C)C1=CC=CC=C1 LCVCUJWKJNFDMY-UHFFFAOYSA-N 0.000 abstract 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 229930003836 cresol Natural products 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 229920001971 elastomer Polymers 0.000 abstract 2
- 239000010685 fatty oil Substances 0.000 abstract 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 abstract 2
- -1 hexyl alcohols Chemical class 0.000 abstract 2
- 235000010446 mineral oil Nutrition 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 abstract 2
- 239000005011 phenolic resin Substances 0.000 abstract 2
- 229920001195 polyisoprene Polymers 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000007670 refining Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000004859 Copal Substances 0.000 abstract 1
- 241000782205 Guibourtia conjugata Species 0.000 abstract 1
- 244000043261 Hevea brasiliensis Species 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- 238000010306 acid treatment Methods 0.000 abstract 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 abstract 1
- 229940073608 benzyl chloride Drugs 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000003763 carbonization Methods 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 239000007799 cork Substances 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 150000001896 cresols Chemical class 0.000 abstract 1
- 239000010779 crude oil Substances 0.000 abstract 1
- 150000001923 cyclic compounds Chemical class 0.000 abstract 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 230000004992 fission Effects 0.000 abstract 1
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 abstract 1
- 150000003944 halohydrins Chemical class 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 150000001261 hydroxy acids Chemical class 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 229920003052 natural elastomer Polymers 0.000 abstract 1
- 229920001194 natural rubber Polymers 0.000 abstract 1
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 238000004073 vulcanization Methods 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F244/00—Coumarone-indene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
516,344. Resinous condensation products. ALBERT PRODUCTS, Ltd. May 17, 1938, No. 14720. Convention date, June 18, 1937. Samples furnished. [Class 2 (iii)] " Alcohol treated phenol resins " are heated with monomeric and/or polymeric unsaturated polymerisable hydrocarbons. " Alcohol treated phenol resins " are phenol artificial resins produced from oil-insoluble hardenable pnenolaldehyde condensates,.- e.g. phenol-alcohols, or such condensates etherified with mono- or poly-alcohols or their halohydrins or hydroxy acids, by heating to above 70‹C. with monoalcohols boiling above 80‹C., simultaneously or subsequently distilling off the alcohol, the products being combined or not with fatty acids or fatty oils. Phenols specified are phenol, cresols, and dihydroxydiphenyldimethylmethane. Polymerizable hydrocarbons specified are: cyclic compounds, e.g. styrene, divinylbenzene, vinyl anisole, cumarone, indene, cyclopentadiene; rubber-producing hydrocarbons, polymers thereof, natural rubber, bodies obtained by chemical or thermal treatment of caoutchouc bodies ; isobutylene ; compounds separated in refining of mineral oils, e.g., by acid-treated clay or selective solvents such as furfurol, aniline, phenol, or nitrobenzene ; " acid resins'' produced by sulphuric acid treatment of crude oil ; mono- and diolefines from mineral oil fission; hydrocarbons formed on carbonization, cracking, or distillation of natural carboniferous materials ; bodies obtained by splitting-off hydrogen or hydrogen halide from organic substances. The materials may be heated together in mixing apparatus or the resin may be dissolved in hydrocarbon monomer, worked up into shaped bodies, coatings, and films and then heated. The products, with or without fillers may be used for moulding, impregnating fibre-boards and woven pressed materials, floor and wall coverings, insulating plates, coatings, binding agents in electrical and metallurgical apparatus, e.g., carbon brushes, mixture resistances, core- and mould-binders, and generally as rubber substitutes. In examples: (1), (4) dihydroxydiphenyldimethylmethane is alkali-condensed with 3.5 mols formaldehyde, the condensate heated with butanol, and the resin is heated with cumarone resin or dissolved in styrene and the mixture heated; (2) phenol is alkali-condensed with 1.5 mols formaldehyde, the condensate heated with amyl and hexyl alcohols, and the resin is heated with unsaturated benzine hydrocarbons from mineral oil refining to a product which may be used, with or without " Albertol " (Registered Trade Mark) resins, copal, or fatty oils, in lacquers, or may be gelatinized and mixed with sawdust, cork dust, dyes, resin, linoxyn, or factice; (3) cresol is alkali-condensed with formaldehyde, the condensate heated with butanol and cyclohexanol, and the resin heated under pressure with caoutchouc, sulphur, zinc oxide and a vulcanization accelerator. Samples have been furnished; under Sect. 2 (5) including the following:- cresol is alkali-condensed with 1.8 mols formaldehyde, the condensate etherified by benzyl chloride and then heated with butanol and hexanol, and the resin heated with an isobutylene polymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE516344X | 1937-06-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB516344A true GB516344A (en) | 1940-01-01 |
Family
ID=6549204
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14720/38A Expired GB516344A (en) | 1937-06-18 | 1938-05-17 | Improvements in or relating to the manufacture of artificial resins |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB516344A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451153A (en) * | 1944-02-02 | 1948-10-12 | Ici Ltd | Reaction of an etherified melamineformaldehyde condensation product with an etherified phenolformaldehyde condensation product |
| DE907696C (en) * | 1949-08-21 | 1954-03-29 | Herberts & Co Gmbh Dr Kurt | Process for the production of phenolic resins |
| US3083174A (en) * | 1958-10-31 | 1963-03-26 | Exxon Research Engineering Co | Treatment of a petroleum resin with a phenolic resol compound |
-
1938
- 1938-05-17 GB GB14720/38A patent/GB516344A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2451153A (en) * | 1944-02-02 | 1948-10-12 | Ici Ltd | Reaction of an etherified melamineformaldehyde condensation product with an etherified phenolformaldehyde condensation product |
| DE907696C (en) * | 1949-08-21 | 1954-03-29 | Herberts & Co Gmbh Dr Kurt | Process for the production of phenolic resins |
| US3083174A (en) * | 1958-10-31 | 1963-03-26 | Exxon Research Engineering Co | Treatment of a petroleum resin with a phenolic resol compound |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3420915A (en) | Phenol modified hydrocarbon resins and blends thereof with epoxy resin,polyurethane or polythiol | |
| US3177166A (en) | Antioxidants comprising reaction products of liquid rubbers and phenols and compositions containing same | |
| DE2652727A1 (en) | NON-CURED VULCANIZABLE ELASTOMER COMPOUNDS AND THEIR USE | |
| GB516344A (en) | Improvements in or relating to the manufacture of artificial resins | |
| PT70536A (en) | METHOD FOR THE PRODUCTION OF REINFORCED RUBBER VULCANES AND THEIR USE | |
| US2438753A (en) | Butadiene-1, 3-acrylonitrile copolymer plasticized with naphthenic acid esters | |
| ES393506A1 (en) | Process for producing resins of weather resistance | |
| DE1745952A1 (en) | Process for the production of polyalkylene-polyphenol furfural resins | |
| US2815296A (en) | Asphalt composition containing a liquid hydrogenated polymer oil | |
| EP0092098B1 (en) | Curable polyester moulding compounds | |
| DE1719279A1 (en) | Preparation based on ethylene-propylene polymers | |
| US3629084A (en) | Method of improving the tack of rubbers | |
| US2009712A (en) | Rubber composition containing asphaltene | |
| US2402189A (en) | Plasticized chlorinated rubbers | |
| US2460724A (en) | Resinous reaction products | |
| US2970985A (en) | Curing catalysts for acrolein pentaerythritol resins | |
| US2468414A (en) | Hydrogenated hydrocarbon resin and resin compositions | |
| US3256368A (en) | Phenolic resins as tackifiers for ethylene-propylene rubbers | |
| RU2151783C1 (en) | Stock for production of industrial carbon | |
| US2379482A (en) | Rubber compositions | |
| US2445737A (en) | Synthetic rubber composition containing a reaction product of sulfur dichloride, an aldehyde and an alkyl phenol | |
| DE1953392C3 (en) | Polymer mixture based on ethylene-propylene mixed polymers | |
| US2615856A (en) | Rubberlike materials and an unsaturated hydrocarbon oil | |
| US2341289A (en) | Rubber composition | |
| US2871206A (en) | Treatment of reclaimed rubber |