GB460009A - Method of producing monomeric methacrylic acid esters - Google Patents
Method of producing monomeric methacrylic acid estersInfo
- Publication number
- GB460009A GB460009A GB20101/36A GB2010136A GB460009A GB 460009 A GB460009 A GB 460009A GB 20101/36 A GB20101/36 A GB 20101/36A GB 2010136 A GB2010136 A GB 2010136A GB 460009 A GB460009 A GB 460009A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid esters
- methacrylic acid
- polymeric
- substances
- sand
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000005397 methacrylic acid ester group Chemical group 0.000 title abstract 3
- 239000000126 substance Substances 0.000 abstract 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000004576 sand Substances 0.000 abstract 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Monomeric methacrylic acid esters are manufactured by heating one or more polymethacrylic acid esters, or one or more mixed polymers of one or more methacrylic acid esters with one or more other polymerizable substances or of two or more of the said esters, to about 250--300 DEG C., advantageously in the presence of inert substances, e.g. sand, barium sulphate or heavy spar, or of substances having an alkaline reaction, e.g. sodium carbonate or chalk, or, with reduced yield, in the presence of oxygen or of stabilizing agents. The monomeric compounds can be reconverted into the polymeric form, e.g. by the action of peroxides. Examples describe the treatment, in the presence of sand, of: (1) polymeric methyl methacrylate; (2) polymeric ethyl methacrylate; (3) a mixed polymer of methyl methacrylate and butyl acrylate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE460009X | 1935-07-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB460009A true GB460009A (en) | 1937-01-19 |
Family
ID=6539665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20101/36A Expired GB460009A (en) | 1935-07-20 | 1936-07-20 | Method of producing monomeric methacrylic acid esters |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR809386A (en) |
| GB (1) | GB460009A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2587558A (en) * | 1948-06-25 | 1952-02-26 | Goodrich Co B F | Preparation of novel 2-carboalkoxy-1, 3-butadienes and polymers thereof |
| US2858255A (en) * | 1953-03-23 | 1958-10-28 | Segui Esteban Domingo | Process and device for the regeneration of monomers starting from polymethacrylate and, more especially, methyl polymethacrylate |
| US5663420A (en) * | 1992-12-04 | 1997-09-02 | Vaughan; Patrick William | Depolymerisation |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19843112C2 (en) * | 1998-09-21 | 2002-07-18 | Roehm Gmbh | Process for the recovery of monomeric esters of substituted or unsubstituted acrylic acid from corresponding structural units of polymer material, preferably by depolymerization of polymethyl methacrylate |
-
1936
- 1936-07-10 FR FR809386D patent/FR809386A/en not_active Expired
- 1936-07-20 GB GB20101/36A patent/GB460009A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2587558A (en) * | 1948-06-25 | 1952-02-26 | Goodrich Co B F | Preparation of novel 2-carboalkoxy-1, 3-butadienes and polymers thereof |
| US2858255A (en) * | 1953-03-23 | 1958-10-28 | Segui Esteban Domingo | Process and device for the regeneration of monomers starting from polymethacrylate and, more especially, methyl polymethacrylate |
| US5663420A (en) * | 1992-12-04 | 1997-09-02 | Vaughan; Patrick William | Depolymerisation |
Also Published As
| Publication number | Publication date |
|---|---|
| FR809386A (en) | 1937-03-02 |
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