GB468157A - Improvements in and relating to the preparation of complex iron compounds - Google Patents
Improvements in and relating to the preparation of complex iron compoundsInfo
- Publication number
- GB468157A GB468157A GB20544/36A GB2054436A GB468157A GB 468157 A GB468157 A GB 468157A GB 20544/36 A GB20544/36 A GB 20544/36A GB 2054436 A GB2054436 A GB 2054436A GB 468157 A GB468157 A GB 468157A
- Authority
- GB
- United Kingdom
- Prior art keywords
- urea
- acetato
- hexa
- dihydroxy
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000002506 iron compounds Chemical class 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 3
- 239000004202 carbamide Substances 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 1
- 150000001242 acetic acid derivatives Chemical class 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000001632 sodium acetate Substances 0.000 abstract 1
- 235000017281 sodium acetate Nutrition 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Hexa - acetato - dihydroxy - carbamidotriferric salts which are useful as tanning agents, are prepared by reacting ferric salts with soluble acetates and urea in aqueous solution and adding alkaline substances before, during or after the reaction. One to three molecules of urea may be introduced into the complex, an excess of the theoretical amount being preferably employed. The reaction is desirably effected in highly concentrated solution at a temperature below 35 DEG C. According to the example, a mixture of sodium acetate, urea and sodium hydroxide in water is slowly stirred into an aqueous solution of ferric chloride, whereupon hexa-acetato-dihydroxy-tricarbamido-triferric chloride is precipitated; it can be crystallized from alcohol. Other alkaline substances, such as sodium carbonate, ammonia and amines, may be used in place of caustic alkali.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE468157X | 1936-01-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB468157A true GB468157A (en) | 1937-06-30 |
Family
ID=6540813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB20544/36A Expired GB468157A (en) | 1936-01-22 | 1936-07-24 | Improvements in and relating to the preparation of complex iron compounds |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB468157A (en) |
-
1936
- 1936-07-24 GB GB20544/36A patent/GB468157A/en not_active Expired
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