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GB2613166B - A method for the removal of impurities from a pyrolysis oil - Google Patents

A method for the removal of impurities from a pyrolysis oil Download PDF

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Publication number
GB2613166B
GB2613166B GB2116988.3A GB202116988A GB2613166B GB 2613166 B GB2613166 B GB 2613166B GB 202116988 A GB202116988 A GB 202116988A GB 2613166 B GB2613166 B GB 2613166B
Authority
GB
United Kingdom
Prior art keywords
impurities
removal
pyrolysis oil
pyrolysis
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
GB2116988.3A
Other versions
GB202116988D0 (en
GB2613166A (en
Inventor
Moreau Pierre
Hargreaves George
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Plastic Energy Ltd
Original Assignee
Plastic Energy Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plastic Energy Ltd filed Critical Plastic Energy Ltd
Priority to GB2116988.3A priority Critical patent/GB2613166B/en
Publication of GB202116988D0 publication Critical patent/GB202116988D0/en
Priority to PCT/EP2022/083355 priority patent/WO2023094629A1/en
Publication of GB2613166A publication Critical patent/GB2613166A/en
Application granted granted Critical
Publication of GB2613166B publication Critical patent/GB2613166B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
GB2116988.3A 2021-11-25 2021-11-25 A method for the removal of impurities from a pyrolysis oil Active GB2613166B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB2116988.3A GB2613166B (en) 2021-11-25 2021-11-25 A method for the removal of impurities from a pyrolysis oil
PCT/EP2022/083355 WO2023094629A1 (en) 2021-11-25 2022-11-25 A method for the removal of impurities from a pyrolysis oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2116988.3A GB2613166B (en) 2021-11-25 2021-11-25 A method for the removal of impurities from a pyrolysis oil

Publications (3)

Publication Number Publication Date
GB202116988D0 GB202116988D0 (en) 2022-01-12
GB2613166A GB2613166A (en) 2023-05-31
GB2613166B true GB2613166B (en) 2024-07-17

Family

ID=80038530

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2116988.3A Active GB2613166B (en) 2021-11-25 2021-11-25 A method for the removal of impurities from a pyrolysis oil

Country Status (2)

Country Link
GB (1) GB2613166B (en)
WO (1) WO2023094629A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2627968B (en) * 2023-03-09 2025-04-23 Plastic Energy Ltd A method for the production of a pyrolysis oil from end-of-life plastics
WO2025106984A1 (en) 2023-11-16 2025-05-22 Ergon, Inc. Methods for preparing naphthenic process oils and lube oils from pyrolysis oil
WO2025106985A1 (en) 2023-11-16 2025-05-22 Ergon, Inc. Methods for producing api group iii, technical white oil from rubber derived pyrolysis oil

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2163177A (en) * 1984-08-17 1986-02-19 Chevron Res Method of catalytically producing high aromatic content products
EP0361681A1 (en) * 1988-08-31 1990-04-04 Exxon Chemical Patents Inc. Process for the purification of linear paraffins
WO2008013519A2 (en) * 2006-07-24 2008-01-31 Uop Llc Process for removal of oxygenates from a paraffin stream
WO2012170034A1 (en) * 2011-06-10 2012-12-13 Bechtel Hydrocarbon Technology Solutions, Inc. Systems and methods for removing elemental sulfur from a hydrocarbon fluid
US20180230361A1 (en) * 2017-02-14 2018-08-16 David Ian Foster Dry liquid concentrate slurries for hydraulic fracturing operations
WO2021080899A1 (en) * 2019-10-24 2021-04-29 Exxonmobil Chemical Patents Inc. Mercury and silicon removal from plastic-derived pyrolysis oil
EP3907267A1 (en) * 2020-05-08 2021-11-10 Basf Se Process for purifying a crude pyrolysis oil originating from the pyrolysis of plastic waste

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862900A (en) 1973-04-09 1975-01-28 Phillips Petroleum Co Removal of chemically combined chlorine and other impurities from hydrocarbons
US4721824A (en) 1984-09-24 1988-01-26 Mobil Oil Corporation Guard bed catalyst for organic chloride removal from hydrocarbon feed
US5107061A (en) 1990-04-06 1992-04-21 Exxon Chemical Patents Inc. Removal of organochlorides from hydrocarbon feed streams
DE59401485D1 (en) 1993-07-20 1997-02-13 Basf Ag METHOD FOR RECYCLING PLASTIC WASTE IN A STEAMCRACKER
FR2886557B1 (en) 2005-06-02 2007-10-19 Inst Francais Du Petrole USE OF FAUJASITE TYPE ZEOLITES EXCHANGED WITH CESIUM FOR PUSHED DESULFURATION OF FUEL CUTTING
EP2516592B1 (en) 2009-12-22 2018-06-13 Cynar Plastics Recycling Limited Conversion of waste plastics material to fuel
PL3186556T3 (en) 2014-08-28 2020-05-18 Plastic Energy Limited Improvements relating to pyrolysis reactor systems
GB2589936B (en) 2019-12-20 2021-12-29 Plastic Energy Ltd A method for pyrolysing plastic material and a system therefor
FI4133036T3 (en) * 2020-04-07 2024-08-22 Totalenergies Onetech Belgium Purification of waste plastic based oil via a two steps hydrotreatment

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2163177A (en) * 1984-08-17 1986-02-19 Chevron Res Method of catalytically producing high aromatic content products
EP0361681A1 (en) * 1988-08-31 1990-04-04 Exxon Chemical Patents Inc. Process for the purification of linear paraffins
WO2008013519A2 (en) * 2006-07-24 2008-01-31 Uop Llc Process for removal of oxygenates from a paraffin stream
WO2012170034A1 (en) * 2011-06-10 2012-12-13 Bechtel Hydrocarbon Technology Solutions, Inc. Systems and methods for removing elemental sulfur from a hydrocarbon fluid
US20180230361A1 (en) * 2017-02-14 2018-08-16 David Ian Foster Dry liquid concentrate slurries for hydraulic fracturing operations
WO2021080899A1 (en) * 2019-10-24 2021-04-29 Exxonmobil Chemical Patents Inc. Mercury and silicon removal from plastic-derived pyrolysis oil
EP3907267A1 (en) * 2020-05-08 2021-11-10 Basf Se Process for purifying a crude pyrolysis oil originating from the pyrolysis of plastic waste

Also Published As

Publication number Publication date
WO2023094629A1 (en) 2023-06-01
GB202116988D0 (en) 2022-01-12
GB2613166A (en) 2023-05-31

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