GB2510540A - Method and apparatus for depositing stable crystalline phase coatings of high temperature ceramics - Google Patents
Method and apparatus for depositing stable crystalline phase coatings of high temperature ceramics Download PDFInfo
- Publication number
- GB2510540A GB2510540A GB1409226.6A GB201409226A GB2510540A GB 2510540 A GB2510540 A GB 2510540A GB 201409226 A GB201409226 A GB 201409226A GB 2510540 A GB2510540 A GB 2510540A
- Authority
- GB
- United Kingdom
- Prior art keywords
- high temperature
- torch
- stand
- ceramics
- coatings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000576 coating method Methods 0.000 title abstract 4
- 239000000919 ceramic Substances 0.000 title abstract 3
- 238000000151 deposition Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000007921 spray Substances 0.000 abstract 3
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- WOIHABYNKOEWFG-UHFFFAOYSA-N [Sr].[Ba] Chemical compound [Sr].[Ba] WOIHABYNKOEWFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052863 mullite Inorganic materials 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- -1 rare earth silicates Chemical class 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4523—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied from the molten state ; Thermal spraying, e.g. plasma spraying
- C04B41/4527—Plasma spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
- C23C4/067—Metallic material containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
- C23C4/11—Oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/134—Plasma spraying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/284—Selection of ceramic materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/30—Manufacture with deposition of material
- F05D2230/31—Layer deposition
- F05D2230/311—Layer deposition by torch or flame spraying
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Plasma & Fusion (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
Producing high temperature coatings on ceramics using a high enthalpy air plasma spray torch and supplying in at least 3 passes to deposit the coating is advantageous for spraying high temperature ceramics while avoiding formation of undesirable phases, if the stand off distance is chosen such that a width of a bead produced from a single spray pass on the substrate at ~800°C is less than 70% of a diameter of a plume of the torch at the stand off, and neither assisted heating, nor forced cooling, nor subsequent heat treatment is used. The rapid cooling endemic to thermal spray that leads to amorphous, metastable and other undesirable phases of alkaline earth aluminosilicate (e.g., barium- strontium aluminosilicate (BSAS)), rare earth silicates (RESs), mullite, etc. can be mitigated sufficiently by the close stand off and high enthalpy torch to provide highly crystalline and stable phase coatings.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CA2011/001285 WO2013075202A1 (en) | 2011-11-25 | 2011-11-25 | Method and apparatus for depositing stable crystalline phase coatings of high temperature ceramics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB201409226D0 GB201409226D0 (en) | 2014-07-09 |
| GB2510540A true GB2510540A (en) | 2014-08-06 |
Family
ID=48468930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1409226.6A Withdrawn GB2510540A (en) | 2011-11-25 | 2011-11-25 | Method and apparatus for depositing stable crystalline phase coatings of high temperature ceramics |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20140329021A1 (en) |
| CA (1) | CA2856756A1 (en) |
| GB (1) | GB2510540A (en) |
| WO (1) | WO2013075202A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9410868B2 (en) | 2014-05-30 | 2016-08-09 | General Electric Company | Methods for producing strain sensors on turbine components |
| US9546928B2 (en) | 2014-05-30 | 2017-01-17 | General Electric Company | Methods for producing strain sensors on turbine components |
| US10415964B2 (en) | 2014-05-30 | 2019-09-17 | General Electric Company | Methods for producing passive strain indicator on turbine components |
| US20160133826A1 (en) * | 2014-11-06 | 2016-05-12 | Agency For Science, Technology & Research | Method of making lead-free ceramic coating |
| US10557372B2 (en) | 2015-12-17 | 2020-02-11 | General Electric Company | Systems and methods for assessing strain of components in turbomachines |
| EP3199507A1 (en) | 2016-01-29 | 2017-08-02 | Rolls-Royce Corporation | Plasma spray physical vapor deposition deposited multilayer, multi-microstructure environmental barrier coating |
| CN114592164B (en) * | 2022-01-20 | 2024-03-08 | 华东理工大学 | DVC thermal barrier coating and preparation method and application thereof |
| US12338185B1 (en) * | 2022-04-10 | 2025-06-24 | The United States Of America As Represented By The Secretary Of The Navy | Systems and methods for plasma spray fabrication of textured ceramics |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2073153A1 (en) * | 1991-07-09 | 1993-01-10 | Zbigniew Zurecki | Wear resistant titanium nitride coating and methods of application |
| US5707694A (en) * | 1996-05-31 | 1998-01-13 | Caterpillar Inc. | Process for reducing oxygen content in thermally sprayed metal coatings |
| US6468648B1 (en) * | 1997-11-12 | 2002-10-22 | United Technologies Corporation | Plasma sprayed mullite coatings on silicon based ceramic materials |
| US6787195B2 (en) * | 2003-02-03 | 2004-09-07 | General Electric Company | Method of depositing a coating on Si-based ceramic composites |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6129954A (en) * | 1998-12-22 | 2000-10-10 | General Electric Company | Method for thermally spraying crack-free mullite coatings on ceramic-based substrates |
| US6576861B2 (en) * | 2000-07-25 | 2003-06-10 | The Research Foundation Of State University Of New York | Method and apparatus for fine feature spray deposition |
| JP4645030B2 (en) * | 2003-12-18 | 2011-03-09 | 株式会社日立製作所 | Heat resistant member with thermal barrier coating |
| US20050238807A1 (en) * | 2004-04-27 | 2005-10-27 | Applied Materials, Inc. | Refurbishment of a coated chamber component |
| US20130136915A1 (en) * | 2010-04-30 | 2013-05-30 | Rolls-Royce Corporation | Durable environmental barrier coatings for ceramic substrates |
-
2011
- 2011-11-25 CA CA2856756A patent/CA2856756A1/en not_active Abandoned
- 2011-11-25 US US14/360,487 patent/US20140329021A1/en not_active Abandoned
- 2011-11-25 GB GB1409226.6A patent/GB2510540A/en not_active Withdrawn
- 2011-11-25 WO PCT/CA2011/001285 patent/WO2013075202A1/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2073153A1 (en) * | 1991-07-09 | 1993-01-10 | Zbigniew Zurecki | Wear resistant titanium nitride coating and methods of application |
| US5707694A (en) * | 1996-05-31 | 1998-01-13 | Caterpillar Inc. | Process for reducing oxygen content in thermally sprayed metal coatings |
| US6468648B1 (en) * | 1997-11-12 | 2002-10-22 | United Technologies Corporation | Plasma sprayed mullite coatings on silicon based ceramic materials |
| US6787195B2 (en) * | 2003-02-03 | 2004-09-07 | General Electric Company | Method of depositing a coating on Si-based ceramic composites |
Also Published As
| Publication number | Publication date |
|---|---|
| GB201409226D0 (en) | 2014-07-09 |
| WO2013075202A1 (en) | 2013-05-30 |
| CA2856756A1 (en) | 2013-05-30 |
| US20140329021A1 (en) | 2014-11-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |