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GB2503224A - Electronic ozone generation unit for the preservation of fresh produce in distribution trays - Google Patents

Electronic ozone generation unit for the preservation of fresh produce in distribution trays Download PDF

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Publication number
GB2503224A
GB2503224A GB1210813.0A GB201210813A GB2503224A GB 2503224 A GB2503224 A GB 2503224A GB 201210813 A GB201210813 A GB 201210813A GB 2503224 A GB2503224 A GB 2503224A
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United Kingdom
Prior art keywords
ozone
generating device
ozone generating
electronic unit
sized
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GB1210813.0A
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GB2503224B (en
GB201210813D0 (en
Inventor
Peter Holmes
Nigel Parker
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Priority to GB1210813.0A priority Critical patent/GB2503224B/en
Publication of GB201210813D0 publication Critical patent/GB201210813D0/en
Publication of GB2503224A publication Critical patent/GB2503224A/en
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Publication of GB2503224B publication Critical patent/GB2503224B/en
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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B7/00Preservation of fruit or vegetables; Chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by group A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by group A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23B7/152Preserving or ripening with chemicals not covered by group A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere comprising other gases in addition to CO2, N2, O2 or H2O ; Elimination of such other gases
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2250/00Food ingredients
    • A23V2250/10Gas
    • A23V2250/128Ozone

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Packages (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
  • Cold Air Circulating Systems And Constructional Details In Refrigerators (AREA)

Abstract

An electronic device for generating ozone is deployed within standard, perforated, plastic or cardboard distribution trays of fresh fruit or vegetables. The ozone disables ethylene and destroys airborne and surface contaminating microbial organisms, thus extending the life of the produce. The electronic unit is sized such that it sits within individual palletised trays of produce and may have dimensions of 100m x 60mm x 30mm. Ozone is supplied to the immediate local atmosphere and ensures that adequate ozone reaches all of the produce when packed in shipping containers. The ozone generating unit is portable and preferably battery-powered. It comprises a rigid polymer casing enclosing an electronic unit with discharge needle assembly and grid, which generates and passes both anions and ozone, at predetermined, controlled levels.

Description

A PRESERVATION UNIT FOR FRESH PRODUCE IN SUB-PALLET, DISTRIBUTION OUTERS DURING PROLONGED CONTAINERISED TRANSPORT.
Introduction to the lnventioQ
I Field of the Invention
2. The present invention relates to a device, controfled by an electronic circuit design for the generation of both ozone and anions, to be employed in euro-trays, or similar sub-pallet containers.
3. The device has been designed for use within fresh produce distribution containers to provide the controlled release of ozone and anions, nto the immediate headspace, which will both allow the inhibition or destruction of microbial food spoilage organ'sms present on the product and disablement of ethylene produced by the product.
4. Description of the Related Art
5. Fresh produce, such as top fruits, stone fruits and soft fruits, as weli as a wide rage of whole vegetables, delivered, out of season, into the EU markets are in the main grown in the southern hemisphere and are shipped in refrigerated, containerised loads, with journey times of several weeks.
6. Within the containers, the fresh produce is generally packed in standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents and then palletised.
7. Despite refrigeration, the high humidity within the containers combined with extended journey times promotes the development of microbial spoliage organisms, which can be the cause of a significant reduction in the commercial value of the load, 8. Also, despite refrigeration, if the fresh produce within the container is climacteric, it will generate ethylene into the headspace with the potential of promoting accelerated rpeninq leading to senescence and accelerated deterioration of the product, again leading to a significant reduction in the commercial value of the load.
9. These problems have been recognized and addressed, in the first instance, by the deployment, within the standard, perforated, euro-sized, plastic distribution trays or their card equivalents of pads containing sodium metabisulphite whicn, in tne presence of an elevated relative humidity (RH) will generate sulphur dioxide into the local ambient atmosphere to act as a microbial suppressant.
10. The use, however, of sulphites within the food industry has, on the grounds of food safety, been under review for some time, especially by the EU, where prohibition is* being sought and in some case implemented.
I
11 In the case of ethylene, its removal from the atmosphere within containerised loads has been attempted by the introduction of ozone into this atmosphere 12. Ozone is a powerful oxidising agent and is thus extremely effective, even when at comparatively ow levels, in the oxidative disabflng of ethylene.
13. Unfortunately, due to the pauetised loading of shipping containers, the abUity of ozone dehvered into a shipping container heauspace to penetrate to the product within the standard, perforated euroszed, plastic distribution trays or their cardboard equivalents, which are situated in the centre of stacked pallet loads, at levels that are stM ethylene destructive, is minimal or non-existent, without elevating the initial level of ozone within the container headspace atmosphere to one where it is certain to cause damage to the products in those trays situated on the outside of the pallet stacks.
1.4. In addition, ozone, even at levels of O.Olppm in the atmosphere of a container apart from tne oxidatre disabling of ethylene is also capable of destroying both airborne and surface contaminating, microbial spoilage and pathogenic organisms, thus dispensing with the need to deploy sulphur dioxide generating pads.
15.The device in this invention is deployed, as a portable, independent unit, with a battery operated, low voltage supply and has been designed to be of a scale that allows it to be easily accommodated, inserted amongst the fresh produce contained within the standard perforated, euro-sized (600mm x 400mm x 250mm ann size derivatives) plastic distribution trays or their card board equivalents.
16.The device has the nominal dimensions of 100mm x 60mm x 30mm.
17.The device, in the preferred deployment, is placed amongst the fresh produce concerned in a position that is central and near the top of the packed standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents.
18. The device generates and delivers ozone into the local atmosphere of the standard, perforated, euro-sized, plastic distnbution trays or their cardboard equivalents and the product contained, at levels, which will both oxidatively disable the molecules of ethylene and destroy both airborne and surface contaminating microbial spoilage and pathogenic organisms present.
19.The structure of the device is illustrated in Figures 1 and 2 and shows the general outline of the outer casing of the present invention, within which the electronic unit is housed, wnerein the unit (2) is fitted w,th a grill with openings (1) through which the ozone and anions pass.
20. In the device, the outer casing is injection moulded in high impact polyethylene (PE), or polypropylene (PP) or a polymer of equivalent properties, in order to provide a rugged, impact and crush resistant structure.
21. In the device, the outer casing is injection moulded in high impact polyethylene (FE), or polypropylene (PP) or a polymer of equivalent properties and s designed to enclose and protect the discharge needle assembly and grid, with provision for the free escape of the ozone and anions produced.
22. In the device, the outer casing is injection moulded in high impact polyethylene (PE), or polypropylene PP) or a polymer of equivalent properties and is designed to allow any penetrations required by the enclosed components to have, water resistant seals.
23. In the device, the outer casing is injection moulded j high. impact polyethylene (PE), or polypropylene (PP) or a polymer of equivalent properties, which can be produced in a range of disunctive self-coloured hues in order both to allow ease of recovery and to provide a colour coding system 24. In the device, the unit (2) above, has a battery status dual colour indicator (4), and depending on the battery system selected, optionally fitted with a battery cover (3).
2& In the device, where a battery cover is fitted, the closure will be of a robust, snap-fit' design.
26. In the device, where a. battery cover is fitted, the seal between this and the outer casing will be water-resistant.
271n the device, the unit (2) is equipped with an ozone t.t d. . colour indicator (4).
28. In the device, the unit (2)is equipped with an ozone output indicator (4).
29.ln the device, the power supply (Ii), a rechargeable battery, with an induction charging facility (1 IA), is connected to a voltage stabiliser (12) in order to supply a power generation stage (13), which generates typically 3,4kVolts at tO kHz in order to supply the ozone/anion generator (14).
3Dm the device, a battery holder (10) is provided as an alternative internal power supply.
3tThe voltage stabfliser (42) above, is managed by a micro-controller (15), a t mer (16) and a timer/booster (17) in order to control and mantain the ozone/anion flow to meet the ethylene disabling and mcrobtal suppression requirements of the packed fresh produce within the standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents.
32. lii the device, circuit enhancements have been added to compensate for temperature variations and, where necessary, humidity variations within the immediately local atmosphere in order to maintain a constant effective ethylene disabhng and microbially destructive output level of ozone, within the range of U.D2ppm -O.O5ppm.
33.ln the device, compensation requirements, jn terms of the ozone output levels, for battery variations the temperature and humidity variations within the immediately local atmosphere are automatically identified and initiated by the circuit design.
34. In the device. compensation requirements, in terms of the ozone output levels, for variations in the ozone content of the mmediat&y local atmosphere are automatically identified and initiated by the circuit design.
35. In the device, the output cycling and levels are processor controlled and are optimised, either manually or automatically, to suit the volume of the headspace created by the packing density of the particu1ar fresh produce concerned typically experienced within the packed standard perforated euro-sized, plastic distribution trays or their cardboard equivalents.
36. In the device, the output cyc ling and levels are programmed to ensure that the presence of ozone within the immediately local atmosphere of packed standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents is at levels significantly below the current UK HSE Guidance Note EH (Environmental Hygiene) 38 -Ozone: health hazards and precautionary measures, the occupational exposure standard (OES) requires that the ozone concentration should be cO.2ppm in atmospheres where personnel are to be exposed and not exceed O.2ppm in air when averaged over a 15 minute reference period".
37. In the device, as a safety feature, the ozonelanion generator is designed so that the corona discharge from the needles and grid is both extremely low and cool', in that the temperature produced is very substantially lower than the temperatures required to ignite an accidental build up of any flammable gas, generated either by biological activity of the fresh produce itself such as methane or gassing-off of volatiles from either general packaging, the euro-sized, plastic distribution trays or their cardboard equivalents -.5-ofthe Invention 38. The dev ice in this invention is deployed within the standard, perforated, euro-sized (600mm x 400mm x 250mm and size derivatives), plastic distribution trays or their cardboard equivalents, constituting palletised, containerised loads of whole fresh produce, as an independent unit, comprised of a rigid polymer casing enclosing an electronic unit with discharge needle assembly and grid, which, when supphed with etectncal power, generates and passes both anions and ozone, at predetermined, controlled levels into the immediately local atmosphere, in order to both oxidatively disable ethylene and destroy airborne and surface-contaminating spoilage and pathogenic microbial organisms.
39. The device in this invention consists. of an electronic unit, housed within a rigid, impact and crush resistant polymer casing and fitted with a discharge needle assembly and grid, from which ozone and anions are generated and pass into the immediately local atmosphere.
40,The device in this invention has an outer casing of injection moulded, high impact PE or PP or a polymer of equivalent properties and is designed to enclose and protect the discharge needle assembly and grid, with provision for the free escape of the ozone and anions produced.
41,ln the device in this invention, the outer casing can be produced in a range of distinctive, self-coloured hues in order to provide a colour coding system and is designed 10 allow any penetrations required by the enclosed components to have water resistant seals.
42. The device in this invention, where the electronic unit is battery powered and has a battery status indicator.
43.The device in this invention, where the electronic unit is battery powered with a designed minimum operating life of 28 days.
44.The device in this invention, where the electronic unit is powered by replaceable batteries and is optionally fitted With a battery cover, 45.The device in this invention, where the electronic unit is powered by a replaceable power pack and is optionally fitted with a battery cover.
46.ln the device in this invention, where a battery cover is fitted! the closure will be of a robust, snap-fit' design with the seal between this and the outer casing being water-resistant.
47.The device in this invention, where the electronic unit is powered by a rechargeable battery connected an external charge point embedded in the rigid polymer casing and fitted with a water-resistant seal.
48.The device in this invention, where the external charge point embedded in the rigid polymer casing is an induction charging facility.
49. The device in this invention has been designed to be of a scale that allows it to be easily accommodated within the standard perforated, euro-sized, plastic distribution trays or their cardboard equivalents without being obtrusive and occupying only a minimum amount of the available storage volume..
50. The device in this invention, in the preferred deployment is placed amongst the fresh produce concerned in a position tnat is central and near the top of a packed, standard, perforated, euro-sized plastic distribution tray or 1s cardboard equivalent.
51 The device in this invention has an ozone output indicator fitted integraUy to the electronic unit.
52. The device in this invention has a voltage stabiliser managed by a micro-controller, and a timer to control and maintain the ozone/anion flow.
53. In the device in this invention, circuit enhancements have been added to compensate for battery variations, temperature variations and where necessary humidity varia4ons within the wash chamber of the dishwasher, in order to maintain a constant, effective ethylene disabling and microbially destructive output lev& of ozone.
54. In the device in this invention, compensation requirements in terms of the ozone output levels, for the variations in battery voltage, temperature and humidity as well as that of he ozone content within the immediately local atmosphere are automatically identified and initiated by the circuit design.
55. In the device in this invention, the output cycling and levels are processor controlled and are optimised, either manually or automatically to suit the volume of the headspace created by the packing density of the particular fresh produce concerned and typically experknced within the packed standard, perforated euro-sized, plastic distribution bays or their cardboard equivalents.
56.ln the device in this invention, the presence of ozone within the immediately local atmosphere of packed standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents is at levels that comn1y wth current UK HSE Guidance Note EH (Environmental Hygiene) 38 -Ozone health hazards and precautionary measures, the occupational exposure standard (OES).
57.The device in this invention has an ozone/anion generator, which is desgned so that the corona discharge from the needles and grd is both extremely low and cool', in that the temperature produced is very substantially lower than the temperatures required to ignite an accidental build up of any flammable gas, generated either by biological activity of the fresh pioduce itself such as methane or gassing off of volatiles from either general packaging the euro-sized, plastic dist;ibutlon trays or their cardboard equivalents a

Claims (1)

  1. Claims 1. A device, wherein it is deployed within the standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents, constituting palletised, containerised loads of whole fresh produce, as a portable, independent unit, comprised of a rigid polymer casing enclosing an electronic unit with discharge needle assembly and grid which, when supplied with electrical power, generates and passes both anions and ozone, at predetermined, controlled levels into the immediately local atmosphere, in order to both oxidatively disable ethylene and destroy airborne and surface-contaminating spoilage and pathogenic microbial organisms.
    2. the ozone generating device according to. claim 1, wherein it is a portable, independent unit for deployment within the standard, perforated, euro-sized (600mm x 400mm x 250mm and size derivatives), plastic distribution trays or their cardboard eauvaients, constituting paHetised, containerised loads of whole fresh produce.
    S. The ozone generating device according to claim 1, wherein the electronic unit is battery powered.
    4, The ozone generating device according to claim 1, wherein the electronic unit is battery powered with a designed minimum operating life of 28 days.
    5. The ozone generating device according to claim 1, wherein the electronic unit is battery powered and has a battery status indicator.
    6. The ozone generating device according to claim 1, wherein the electronic unit is powered by replaceable batteries and is fitted with a battery cover.
    7. The ozone generating device according to claim 1, wherein the electronic unit is powered by a replaceable power pack and is fitted with a battery cover.
    8. The ozone generating device according to claim 1, wherein a battery cover is fitted, the closure will be of a robust, snap-fit' design with the seal between this and the outer casing being water-resistant.
    9. The ozone generating device according to claim 1, wherein the electronic unit powered by a rechargeable battery connected to an external charge point embedded in the rigid polymer casing and fitted with a water-resistant seal..
    1OThe ozone generating device according to claim 10, wherein the external charge point embedded in the rigid polymer casing is an induction charging facility.
    11. The ozone generating device according to claim 1, wherein a voltage stabitiser is present. and managed by a micro-controller, a timer to control and maintain the ozone/anion flow.
    12.The ozone generating device according to claim 1, wherein an ozone output indicator is fitted integrally to the electronic unit.
    13.The ozone generating device according to claim 1, wherein it has been designed to be of a scale that allows it to be easily accommodated, inserted amongst the fresh produce contained within a packed, standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents.
    14.The ozone generating device according to claim 1, wherein it generates and delivers ozone into the immediately local atmosphere of the standard, perforated, euro-sized, plastic distnbution trays or their cardboard equivalents and the product contained, at levels, which will both oxidatively disable ethylene and destroys both airborne and surface contaminating microbial spoilage and pathogenic organisms that are present.
    15.The ozone generating device according to claim 1. wherein the outer casing is injection moulded in high impact polyethylene (PE), or polypropylene PP) or a polymer of equivalent properties in order to provide a rugged, impact and crush resistant structure.
    16. The ozone generating device according to claim 1. wherein the outer casing is injection moulded in high impact polyethylene (RE), or polypropylene (PP) or a polymer of equivalent properties and is designed to enclose and protect the discharge needle assembly and grid, with provision for the free escape of the ozone and anions produced.
    17.The ozone generating device according to claim 1, wherein the outer casing is injection moulded in high impact polyethylene (PE), or polypropylene (PR) or a polymer of equivalent properties and s designed to allow any penetrations required by the enclosed components to have water resistant seals.
    18.The ozone generating device according to claim 1, wherein the outer casing is injection moulded in high impact polyethylene (RE), or polypropylene (PP) or a polymer of equivalent properties which can be produced in a range of distinctive self-coloured hues in order both to allow ease of recovery and to provide a colour coding system 19.The ozone generating device according to claim 1, wherein circuit enhancements have been added to compensate for battery variations, temperature variations and, where necessary. humidity variations within the immediately local atmosphere, in order to maintain a constant, effective ethylene disabling and microbially destructive output level of ozone, within the range of UM2ppm O.O5ppm.20. The ozone generating device according to claim 1: wherein the ozone output levels, for the battery voltage, temperature and humidity variations within the immediately local atmosphere are automaticafly identified and initiated by the circuit design.21.The ozone generating device according to claim 1, wherein compensation requirements, in terms of the ozone output levels, for variations in the ozone content of the immediately local atmosphere are automaticafly identified and initiated by the circuit design.22 The ozone generating device accordin9 to claim 1, wherein the ozone output cyling and levels are processor controlled and are optimised, either manually or automatically, to suit the volume of the headspace created by the packing density of the parhcular fresh produce concerned typicafly experienced within the packed standard, perforated, euro-sized. plastic distribution trays or their cardboard equIvalents.23.The ozone generating device according to claim 1, wherein the ozone output cycling and levels are programmed to ensure that the presence of ozone within the immediately local atmosphere of packed standard, perforated, euro-sized, plastic distribution trays or their cardboard equivalents is at levels significantly below tne current UK HSE Guidance Note EH (Environrnen+al Hygiene) 38 -Ozone health hazards and precautionary measures, the occupational exposure standard (OES) requires that the ozone concentration should be cO.2ppm in atmospheres where personnel are to be exposed and not exceed 0,2ppm in air when averaged over a 15 minute reference period.24.The ozone generating device according to claim 1, wherein, as a safety feature, the ozone/anion generator is designed so that the corona discharge from the needles and grid is both extremely low and cool', in that the temperature produced is very substantially lower than the temperatures required to ignite an accidental build up of any flammable gas, generated either by biological activity of the fresh produce itself, such as methane or gassing-oft of volatiles from either general packaging, the euro-sized, plastic distribution trays or their cardboard equivalents
GB1210813.0A 2012-06-19 2012-06-19 A preservation unit for fresh produce in sub-pallet distribution outers during prolonged containerised transport Expired - Fee Related GB2503224B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1210813.0A GB2503224B (en) 2012-06-19 2012-06-19 A preservation unit for fresh produce in sub-pallet distribution outers during prolonged containerised transport

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1210813.0A GB2503224B (en) 2012-06-19 2012-06-19 A preservation unit for fresh produce in sub-pallet distribution outers during prolonged containerised transport

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GB201210813D0 GB201210813D0 (en) 2012-08-01
GB2503224A true GB2503224A (en) 2013-12-25
GB2503224B GB2503224B (en) 2016-10-12

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020037240A1 (en) * 2000-06-15 2002-03-28 Daishin Okada Refrigerator and deodorizer producing ozone by high-voltage discharge
US20020083724A1 (en) * 2000-12-28 2002-07-04 Tarlow Kenneth A. Food storage and preservation system
JP2002335858A (en) * 2001-05-15 2002-11-26 Matsushita Electric Ind Co Ltd Portable ethylene removal equipment
CN101422190A (en) * 2007-10-29 2009-05-06 西北农林科技大学 A kind of apple fruit ozone treatment storage method
US20090258125A1 (en) * 2005-09-28 2009-10-15 Iceman Co., Ltd. Ozone Emitter, Method and Equipment for Producing the Ozone Emitter, and Method for Utilizing the Same
WO2011044355A2 (en) * 2009-10-08 2011-04-14 Microlin, Llc Apparatus and method for sterilizing and deodorizing

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020037240A1 (en) * 2000-06-15 2002-03-28 Daishin Okada Refrigerator and deodorizer producing ozone by high-voltage discharge
US20020083724A1 (en) * 2000-12-28 2002-07-04 Tarlow Kenneth A. Food storage and preservation system
JP2002335858A (en) * 2001-05-15 2002-11-26 Matsushita Electric Ind Co Ltd Portable ethylene removal equipment
US20090258125A1 (en) * 2005-09-28 2009-10-15 Iceman Co., Ltd. Ozone Emitter, Method and Equipment for Producing the Ozone Emitter, and Method for Utilizing the Same
CN101422190A (en) * 2007-10-29 2009-05-06 西北农林科技大学 A kind of apple fruit ozone treatment storage method
WO2011044355A2 (en) * 2009-10-08 2011-04-14 Microlin, Llc Apparatus and method for sterilizing and deodorizing

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Publication number Publication date
GB2503224B (en) 2016-10-12
GB201210813D0 (en) 2012-08-01

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Effective date: 20210619