GB258887A - Method of effecting catalytic reactions for the production of ammonia - Google Patents
Method of effecting catalytic reactions for the production of ammoniaInfo
- Publication number
- GB258887A GB258887A GB23529/26A GB2352926A GB258887A GB 258887 A GB258887 A GB 258887A GB 23529/26 A GB23529/26 A GB 23529/26A GB 2352926 A GB2352926 A GB 2352926A GB 258887 A GB258887 A GB 258887A
- Authority
- GB
- United Kingdom
- Prior art keywords
- zinc
- carbon monoxide
- hydrogen
- gases
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title abstract 4
- 229910021529 ammonia Inorganic materials 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006555 catalytic reaction Methods 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 9
- 239000007789 gas Substances 0.000 abstract 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000011701 zinc Substances 0.000 abstract 5
- 229910052725 zinc Inorganic materials 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 4
- 230000003197 catalytic effect Effects 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000012535 impurity Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 230000002745 absorbent Effects 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical class [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 abstract 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 230000002939 deleterious effect Effects 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 238000007689 inspection Methods 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011667 zinc carbonate Substances 0.000 abstract 1
- 229910000010 zinc carbonate Inorganic materials 0.000 abstract 1
- 235000004416 zinc carbonate Nutrition 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/04—Preparation of ammonia by synthesis in the gas phase
- C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
258,887. Lazote, Inc., (Assignees of Williams, R.). Sept. 24, 1925, [Convention date]. Methyl alcohol; oxygenated organic compounds.- Carbon monoxide is removed from hydrogen - containing gases by passage under pressure over a catalyst capable of forming oxygenated organic compounds such as methyl alcohol and then removing the latter by condensation while the gases are still under pressure. Preferably the pressure employed is that under which the resulting hydrogen-containing gas is to react. Catalytic substances mentioned comprise zinc, zinc and chromium, and zinc and copper; iron may also be employed if the formation of some methane is not deleterious. In condensing out the methyl alcohol &c., impurities such as water, methane and sulphur compounds are simultaneously removed. Any carbon monoxide remaining in the gases is eliminated by passage under pressure over a methaneforming catalyst or through one of the known absorbents. In this manner, up to 10 per cent of carbon monoxide present in hydrogen-containing gases can be removed, whilst carbon dioxide and hydrocarbons such as methane may also be transformed into condensable products by the same process. Oily products and higher alcohols are produced when the gas speed is reduced, the temperature increased, or alkali oxides added to the catalyst. According to the example, a purified mixture of nitrogen and hydrogen in the volume proportions of 1 3 and containing 2 per cent of carbon monoxide is compressed by pump 2 to 900 atmospheres and conducted through a catalytic apparatus 3 containing a heated catalyst comprising zinc oxide prepared by igniting precipitated zinc carbonate, or a mixture of zinc and chromium oxides obtained by adding ammonia to a solution of zinc and chromium nitrates. The products pass through a water-cooled condenser 4, where the oxygenated compounds in which the impurities are dissolved separate out and are collected in the receiver 5. The Specification as open to inspection under Sect. 91 (3) (a) includes also an example according to which hydrogen containing 2 per cent of carbon monoxide and free from sulphur compounds is compressed by the pump 2 to 150 atmospheres and then passed as before through the catalytic apparatus 3 and condenser 4. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US258887XA | 1925-09-24 | 1925-09-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB258887A true GB258887A (en) | 1928-01-23 |
Family
ID=21828594
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB23529/26A Expired GB258887A (en) | 1925-09-24 | 1926-09-23 | Method of effecting catalytic reactions for the production of ammonia |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB258887A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3365268A (en) * | 1964-08-19 | 1968-01-23 | Pulp Paper Res Inst | Production of ammonia from the organic materials present in spent pulping liquors with the simultaneous recovery of the pulping base and sulphur values present in said liquors |
| US4367206A (en) | 1978-11-10 | 1983-01-04 | Imperial Chemical Industries Limited | Method for producing methanol and ammonia |
-
1926
- 1926-09-23 GB GB23529/26A patent/GB258887A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3365268A (en) * | 1964-08-19 | 1968-01-23 | Pulp Paper Res Inst | Production of ammonia from the organic materials present in spent pulping liquors with the simultaneous recovery of the pulping base and sulphur values present in said liquors |
| US4367206A (en) | 1978-11-10 | 1983-01-04 | Imperial Chemical Industries Limited | Method for producing methanol and ammonia |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE4321542C1 (en) | Process for the separate removal of sulphur compounds and CO2 from gas | |
| GB258887A (en) | Method of effecting catalytic reactions for the production of ammonia | |
| US2580068A (en) | Process of removing sulfur compounds and carbon monoxide from hydrogen | |
| US1820417A (en) | Method of effecting catalytic reactions | |
| US1830167A (en) | Production of ammonia | |
| US1698722A (en) | Process of exploiting gases containing nitrogen, hydrogen, and carbon dioxide | |
| US1875920A (en) | Treatment of coal distillation gases | |
| US1716813A (en) | Process for the production of hydrogen-nitrogen mixtures | |
| US2281228A (en) | Process for synthesizing methanol | |
| US1875253A (en) | Process for preparing nitrogen, carbonic oxide, and hydrogen | |
| US1757826A (en) | Purification of gaseous mixtures | |
| US1681702A (en) | Method for purifying gases | |
| US1766763A (en) | Process of producing gases for the manufacture of oxygenated organic compounds | |
| US1912877A (en) | Gas purification | |
| GB380893A (en) | Process for the manufacture of carbon and hydrogen | |
| US1704965A (en) | Process for the production of acetic acid | |
| SU47287A1 (en) | Method for producing iron group catalysts | |
| GB366268A (en) | Process for the transformation of coke oven gas or town gas into ammonia and methyl alcohol | |
| USRE18302E (en) | Method of effecting catalytic reactions | |
| JPS5910921B2 (en) | Hydrogen production method | |
| US1887792A (en) | Process for the manufacture of amorphous carbon | |
| GB276687A (en) | An improved process for purifying hydrogen and gases containing hydrogen | |
| DE390861C (en) | Process for the catalytic production of methane | |
| GB163047A (en) | Improvements in and relating to the process of preparing mixtures of nitrogen and hydrogen such as are suitable for the production of ammonia | |
| SU41945A1 (en) | Hydrogen production process |