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GB2582086A - Method for adjusting the ionic features of soil and composition suitable for the purpose - Google Patents

Method for adjusting the ionic features of soil and composition suitable for the purpose Download PDF

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Publication number
GB2582086A
GB2582086A GB2007420.9A GB202007420A GB2582086A GB 2582086 A GB2582086 A GB 2582086A GB 202007420 A GB202007420 A GB 202007420A GB 2582086 A GB2582086 A GB 2582086A
Authority
GB
United Kingdom
Prior art keywords
soil
sulphur
hydrophilic
aqueous suspension
suspension
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB2007420.9A
Other versions
GB202007420D0 (en
GB2582086B (en
Inventor
Renato De Angelis Alberto
Pollesel Paolo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni SpA
Original Assignee
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni SpA filed Critical Eni SpA
Publication of GB202007420D0 publication Critical patent/GB202007420D0/en
Publication of GB2582086A publication Critical patent/GB2582086A/en
Application granted granted Critical
Publication of GB2582086B publication Critical patent/GB2582086B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • B09C1/085Reclamation of contaminated soil chemically electrochemically, e.g. by electrokinetics

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A method to change and optimise the level of acidity and the mineral composition of a soil that has undergone salinization or changes in the optimal level of acidity as a result of natural phenomena or anthropic activities, said method comprising the treatment of the soil with an aqueous suspension of hydrophilic sulphur having peculiar features of acidity and granulometry of the suspended phase. The above treatment allows at the same time a rapid fertilisation of the soil and is a faster and more effective way of disposing of excess sulphur resulting from the processes of purification of fossil fuels.

Claims (12)

1. Method for modifying the chemical composition of a soil, comprising the treatment of said soil with a suitable amount of an aqueous suspension of hydrophilic sulphur with a concentration in S comprised between 0.5 and 300 g/L, preferably between 5 and 200 g/L, more preferably between 15 and 150 g/L, pH comprised between 0 and 4, more preferably between 0.5 and 2, said sulphur having an average granulometry of between 2 and 100 Î1⁄4ιη (micron), measured with the "light scattering" method.
2. Method according to claim 1 , wherein said treatment comprises the distribution on the soil's surface of a quantity of said hydrophilic sulphur aqueous suspension such that the average quantity of S distributed on the soil is between 10 and 500, preferably between 50 and 300, g/m2 of soil.
3. Method according to any of the claims 1 or 2, wherein said aqueous sulphur suspension comprises from 0.05 to 10.0 %, preferably from 0.1 to 5 %, by weight of polythionic acids, with respect to the total weight of the suspension.
4. Method according to any of the preceding claims, wherein said soil comprises an overall ion concentration such as to result in an electrical conductivity of the medium greater than 1.0 dS m-1, preferably greater than 2.0 dS m-1.
5. Method according to any of the previous claims, wherein said soil has a pH higher than 6.5, preferably higher than 7.0.
6. Method according to any of the preceding claims, wherein said hydrophilic sulphur suspension also comprises at least one suspension agent.
7. Aqueous suspension of hydrophilic sulphur, having the following features: concentration in S between 15 and 300 g/L, preferably between 15 and 150 g/L, pH between 0 and 4, preferably between 0.2 and 2.0, said sulphur having an average particle size between 2 and 100 Î1⁄4ιη (microns), measured with the "light scattering" method.
8. Aqueous suspension of hydrophilic sulphur according to claim 7, having a PZC comprised between 1 and 3.
9. Aqueous suspension of hydrophilic sulphur according to claims 7 or 8, which is obtained by a process which includes making an aqueous solution of S02 react with H2S, at a temperature equal to or lower than 100°C, preferably between 5°C and 40°C.
10. Aqueous suspension of hydrophilic sulphur according to any of the preceding claims from 7 to 9, for use as soil improver.
11. Aqueous suspension of hydrophilic sulphur according to any of the preceding claims from 7 to 10, having a pH comprised between 0.5 and 1.95
12. Method according to any of the previous claims from 1 to 6, in which the treatment of the soil is carried out with an aqueous suspension of hydrophilic sulphur according to any of the claims from 7 to 9.
GB2007420.9A 2017-11-13 2018-11-13 Method for adjusting the ionic features of a soil and composition suitable for the purpose Expired - Fee Related GB2582086B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT201700128986 2017-11-13
PCT/IB2018/058889 WO2019092671A1 (en) 2017-11-13 2018-11-13 Method for adjusting the ionic features of soil and composition suitable for the purpose

Publications (3)

Publication Number Publication Date
GB202007420D0 GB202007420D0 (en) 2020-07-01
GB2582086A true GB2582086A (en) 2020-09-09
GB2582086B GB2582086B (en) 2022-04-13

Family

ID=61581466

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2007420.9A Expired - Fee Related GB2582086B (en) 2017-11-13 2018-11-13 Method for adjusting the ionic features of a soil and composition suitable for the purpose

Country Status (2)

Country Link
GB (1) GB2582086B (en)
WO (1) WO2019092671A1 (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB202613A (en) * 1922-08-16 1923-12-27 Heinrich Vogel Process for the manufacture of colloidal sulphur
US3186826A (en) * 1963-10-09 1965-06-01 Rendon Margarita Del Muro De Soil improver and process for preparing same
GB2228490A (en) * 1989-02-23 1990-08-29 Sandoz Ltd Oxidised sulfur dye dispersions purified by membrane separation
EP0949221A1 (en) * 1998-04-06 1999-10-13 Holland Chemical International N.V. Composition suitable as fertilizer containing sulphur as a polythionic acid compound or a salt thereof
WO2000078893A1 (en) * 1999-06-18 2000-12-28 Ultimate Products (Aust) Pty Ltd Liquid soil conditioner
WO2005095271A2 (en) * 2004-03-31 2005-10-13 Eni S.P.A. Process for the production of sulfur, starting from the hydrogen sulphide contained in the natural gas, or in the associated gas and possi­ble disposal of the thus obtained sulfur
EP2629606A2 (en) * 2010-10-18 2013-08-28 Ceradis B.V. Novel biosulfur formulations
WO2016097378A1 (en) * 2014-12-19 2016-06-23 Shell Internationale Research Maatschappij B.V. Process for preparing a sulphur-containing soil improver

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB202613A (en) * 1922-08-16 1923-12-27 Heinrich Vogel Process for the manufacture of colloidal sulphur
US3186826A (en) * 1963-10-09 1965-06-01 Rendon Margarita Del Muro De Soil improver and process for preparing same
GB2228490A (en) * 1989-02-23 1990-08-29 Sandoz Ltd Oxidised sulfur dye dispersions purified by membrane separation
EP0949221A1 (en) * 1998-04-06 1999-10-13 Holland Chemical International N.V. Composition suitable as fertilizer containing sulphur as a polythionic acid compound or a salt thereof
WO2000078893A1 (en) * 1999-06-18 2000-12-28 Ultimate Products (Aust) Pty Ltd Liquid soil conditioner
WO2005095271A2 (en) * 2004-03-31 2005-10-13 Eni S.P.A. Process for the production of sulfur, starting from the hydrogen sulphide contained in the natural gas, or in the associated gas and possi­ble disposal of the thus obtained sulfur
EP2629606A2 (en) * 2010-10-18 2013-08-28 Ceradis B.V. Novel biosulfur formulations
WO2016097378A1 (en) * 2014-12-19 2016-06-23 Shell Internationale Research Maatschappij B.V. Process for preparing a sulphur-containing soil improver

Also Published As

Publication number Publication date
GB202007420D0 (en) 2020-07-01
WO2019092671A1 (en) 2019-05-16
GB2582086B (en) 2022-04-13

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 20241113