GB2225018A - Preparation of flame retardant, fine denier, mass pigmented polypropylene fibers - Google Patents
Preparation of flame retardant, fine denier, mass pigmented polypropylene fibers Download PDFInfo
- Publication number
- GB2225018A GB2225018A GB8924596A GB8924596A GB2225018A GB 2225018 A GB2225018 A GB 2225018A GB 8924596 A GB8924596 A GB 8924596A GB 8924596 A GB8924596 A GB 8924596A GB 2225018 A GB2225018 A GB 2225018A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polypropylene
- flame retardant
- resin
- pelletized
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- -1 polypropylene Polymers 0.000 title claims abstract description 46
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 35
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 35
- 239000003063 flame retardant Substances 0.000 title claims abstract description 27
- 239000000835 fiber Substances 0.000 title claims abstract description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 9
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 239000012141 concentrate Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 6
- 235000006708 antioxidants Nutrition 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 8
- 239000008188 pellet Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 5
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000009877 rendering Methods 0.000 claims description 3
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 claims description 2
- 238000009987 spinning Methods 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052794 bromium Inorganic materials 0.000 abstract description 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract description 4
- 125000001931 aliphatic group Chemical group 0.000 abstract description 2
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 2
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- SCKHCCSZFPSHGR-UHFFFAOYSA-N cyanophos Chemical compound COP(=S)(OC)OC1=CC=C(C#N)C=C1 SCKHCCSZFPSHGR-UHFFFAOYSA-N 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
Abstract
Fine denier mass pigmented polypropylene filaments and fiber is rendered flame retardant by mixing flame retardant compounds such as a product which contains both aliphatic and aromatic bromine with an anti-oxidant and a U.V. stabilizer with polypropylene powder resin in order to make a flame retardant concentrate prior to mixing with polypropylene resin and pigments to make a color concentrate.
Description
METHOD FOR RENDERING FINE DENIER MASS PIGMENTED
POLYPROPYLENE FILAMENTS AND FIBER FLAME RETARDS BACKGROUND AND DISCUSSON OF PRIOR ART
Flame retardancy has become a major consideration for many plastic articles used in industrial, commercial and household products.
Widespread use of plastics in products for industry commerce and household, has created the need to insure that such plastics are flame retardant. The polyolefins have been, and are being further considered in these areas. For example, polyolefins are highly flammable, and when used in the manufacture of fibers for clothing, upholstery, carpeting and the like, the need for flame retardancy is even more apparent. It is likewise well recognized that polyolefin fibers used in upholstery and carpets have in the past incresed the severity of fires, especially in large commercial establishments.
However, the art has not been able to develop a satisfactory fire retardant additive, or additives for extruded polyolefin fibers.
With respect to additives, Hancock Patent 4,532,278, discloses a fire retardant polypropylene fiber which results from combining the polypropylene polymer with a bromophenyl compound and which may include
C12H2Br80; tetrabromobisphenol A; Bis (2-hydroxyethyl ether) of tetrabromo bisphenol A; and octabromobisphenyl oxide. The flame retarding compound according to Hancock, is simply blended into the polypropylene resin prior to or during extrusion.
However, to date, no one has been able to develop a suitable system which will impart fire retardancy to polyolefins without affecting some of the desirable resin properties.
In another aspect, the synthetic textile industry was desirous of obtaining a fire retardant polyolefin fiber or fabric, wherein the presence of the fire retardant in the fiber or frabric would in one respect, be effective as a flame retardant while in another respect, would not alter the desirable properties of the fabric, particularly, color and hand. This is particularly important in fabrics for household and personal use, such as in clothing and furniture coverings.
In Listner, U.S. Patent No. 3,650,300 granted March 21, 1972, polyolefins were rendered flame retardant by the incorporation of an anti-oxidant, a halogen phosphate, a free radical initiator and a dispersant into the thermoplastic melt.
In Versnel, U.S. Patent No. 3,893,870 granted July 8, 1975, a phosphite adjuvant is incorporated into molten polypropylene.
In Goldborn et al I. U.S. Patent No. 3,870,711, granted April 9, 1974; Goldborn et al II, U.S. Patent No. 3,870,771, granted March 11 1975; Goldborn et al III, U.S. Patent No. 3,935,162 and Goldborn et al
IV, U.S. Patent No. 3,976,620, various alkyl-aryl phosphonates were proposed for incorporation into polyolefin thermoplastic melts to provide flame retardancy.
Certain other prior art references were directed to flame proofing specific polymers with a bromine compound. In Ekhhorn, U.S.
Patent No. 3,058,926, there is disclosed a method for making flame proof alkenyl aromatic resin composition by incorporating an organil bromine compound and an organic peroxide.
Fine denier polypropylene fibers are manufactured by extruding the melted polypropylene resin through very fine spinneret orifices; if the flame retardant compound is not completely mixed with the melted polypropylene resin prior to extrusion, the fire retardant compound tends to agglomerate into itself, creating lumps in the extrusion melt which will clog the spinneret filters or orifices and will result in down time on a commercial line. In addition, smaller lumps of the flame retardant compound which can pass through the filter and spinneret die orifice, will displace sufficient polymer in the resulting fine denier filament to create a weak spot in the continuous filament; which may result in breakage that shuts down the production line.Incomplete mixing of the flame retardant compound with the polypropylene resin may also have a deleterious effect on the ability of the flame retardant compound to generate cooling gases within a localized area which serve to render the material flame retardant.
DESCRIPTION OF THE INVENTION
When a fiber producer tries to manufacture fine denier flame retardant polypropylene fiber, he will face two different problems, the first problem is the inability to obtain a good mix of the melted polypropylene with the flame retardant, because, if the compound is not well made, it will agglomerate on itself resulting in clogging the spinneret filters or produce a weak spot on fibers, resulting in broken filaments because of the agglomerates.
The second problem is the lack of tenacity retention during the use of these fibers in the end use, because bromine materials used to manufacture the flame retardant fiber have a very low decomposition temperature, lower than the processing temperature, because of that, free bromine is generated which attacks chemically the polymer and the fiber decomposition starts at the beginning of the fiber manufacture; to avoid that it is necessary to use an anti-oxidant agent to provide heat stability to the polymer and bromine compound, and a hindered amine which could react chemically with the free bromine produced dt the processing step.
Achieving ccmplete dispersion of all the compounds, and avoiding the polymer degradation with the hindered amine, polypropylene fibers can be rendered flame retardant and they will be used to manufacture fabrics or carpets obtaining the desired rate in the common flame retardancy tests, exhibiting no changes in fiber properties.
The preferred method of making the flame retardant polypropylene fibers of the present invention, is carried out in the following steps:
1. The following materials are dry-mixed:
a. aliphatic and aromatic bromine compound - bis
(2,3 dibromopropyl ether) of tetrabromobisphenol A
from 20% to 35t depending on the final application.
b. hindered amine (Cyassorb from Cyanamid or Chimassorb
from Ciba Geigy 25% to 35% depending on the final
application.
c. thermal anti-oxidant (phenolic plus phosphite) Irganox
from Ciba Geigy or Cyanox from Cyanamid 2 to 4%
depending on processing temperature.
d. MFI-12 polypropylene powder resin.
The mixture is dosified in a two screw extruder through a two mouth dosifier merging through one mouth 60% of this dry mixture, and the other mouth 40% of MFI-35 pelletized polypropylene resin, and from the exit of the extruder to a pelletizing line to form pellets.
2. The following materials are dry mixed and extruded to make a color concentrate:
a. 20% of pellets formed by Step 1.
b. adequate percentaye of different pigment dispersions
to provide the necessary color to the final fiber
(pigments used could be organic or inorganic).
c. MFI-35 polypropylene pellets enough to make 100% of
the mix.
d. 20% of pellets formed in Step 2, are dosified to an
extruder with 80% of MFI-35 polypropylene pellets to
obtain the final fiber (staple or continuous
filament).
The standard melt spinning process of Step c, can be carried out at spinning speeds of from 600 to 1400 meters per minute.
Claims (9)
1. A method for rendering fine denier polypropylene fibers flame retardant, comprising a) dispersing fire retardant material, thermal anti-oxidant and hindered amines in a blend of polypropylene powder resin and pelletized polypropylene resin; extruding and pelletizing to form additive pellets;
b) mixing the additive pellets with pigment dispersions and further pelletized polypropylene resin and extruding and pelletizing to obtain a color concentrate; and
c) mixing the color concentrate with further pelletized polypropylene resin and extruding and spinning to obtain the fine polypropylene fibers.
2. The method of claim 1 where the flame retardant material is bis (2,3-dibromopropyl) ether of tetrabromobisphenol A.
3. The method of either of claims 1 and 2 where the flame retardant, the anti-oxidant and hindered amine are dispersed in said polypropylene powder resin to form a dry powder blend comprising from 20 to 35% flame retardant, from 20 to 35% hindered amine, from 2 to 4% of thermal anti-oxidant and the remaining percentages up to 100% of polypropylene powder resin blend and the remaining percentage to cover the 100% is MFI-12 polypropylene powder resin in the powder dry blend.
4. The method of claim 1 where the powder dry blend of claim 3 is blended in approximately a 60% proportion of such dry blend with approximately 40% of MFI-35 pelletized polypropylene resin.
5. The method of claim 1 where the pelletized compound of claim 4 is blended with pigment dispersion and further pelletized polypropylene resin to obtain the color concentrate containing approximately 20% of such pelletized compound.
6. The method of any one of claims 1 to 5 where approximately 20% of the color concentrate is mixed with pelletized polypropylene to complete the 100%.
7. The method of any one of claims 1 to 6 where the hindered amine is a high molecular weight hindered amine.
8. A method for rendering fine denier polypropylene fibers flameretardant substantially as hereinbefore described.
9. Polypropylene fibers made in accordance with the method according to any one of claims 1 to 8.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26578188A | 1988-11-01 | 1988-11-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB8924596D0 GB8924596D0 (en) | 1989-12-20 |
| GB2225018A true GB2225018A (en) | 1990-05-23 |
Family
ID=23011865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8924596A Withdrawn GB2225018A (en) | 1988-11-01 | 1989-11-01 | Preparation of flame retardant, fine denier, mass pigmented polypropylene fibers |
Country Status (2)
| Country | Link |
|---|---|
| AU (1) | AU4398889A (en) |
| GB (1) | GB2225018A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5393812A (en) * | 1993-08-31 | 1995-02-28 | Hercules Incorporated | Flame retardant, light stable composition |
| ES2192135A1 (en) * | 2000-12-12 | 2003-09-16 | Ciba Sc Holding Ag | IMPROVEMENTS AGAINST ALTERATION BY POLYOLEFINE ATMOSPHERIC AGENTS WITH FLAME DELAY. |
| WO2008033410A1 (en) * | 2006-09-14 | 2008-03-20 | Ingenia Polymers Inc. | High concentration pelletized additive concentrates for polymer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0212555A2 (en) * | 1985-08-22 | 1987-03-04 | BASF Aktiengesellschaft | Method for the preparation of flame-resistant polystyrene |
| EP0226467A2 (en) * | 1985-12-12 | 1987-06-24 | Techlon Fibers Corporation | Flame retardant polyolefin material and method |
-
1989
- 1989-11-01 AU AU43988/89A patent/AU4398889A/en not_active Abandoned
- 1989-11-01 GB GB8924596A patent/GB2225018A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0212555A2 (en) * | 1985-08-22 | 1987-03-04 | BASF Aktiengesellschaft | Method for the preparation of flame-resistant polystyrene |
| EP0226467A2 (en) * | 1985-12-12 | 1987-06-24 | Techlon Fibers Corporation | Flame retardant polyolefin material and method |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5393812A (en) * | 1993-08-31 | 1995-02-28 | Hercules Incorporated | Flame retardant, light stable composition |
| ES2192135A1 (en) * | 2000-12-12 | 2003-09-16 | Ciba Sc Holding Ag | IMPROVEMENTS AGAINST ALTERATION BY POLYOLEFINE ATMOSPHERIC AGENTS WITH FLAME DELAY. |
| ES2192135B1 (en) * | 2000-12-12 | 2005-03-01 | Ciba Specialty Chemicals Holding Inc. | IMPROVEMENTS AGAINST ALTERATION BY POLYOLEFINE ATMOSPHERIC AGENTS WITH FLAME DELAY. |
| US6881773B2 (en) | 2000-12-12 | 2005-04-19 | Ciba Specialty Chemicals Corp. | Weatherability of flame retardant polyolefin |
| AU785015B2 (en) * | 2000-12-12 | 2006-08-24 | Ciba Specialty Chemicals Holding Inc. | Improved weatherability of flame retardant polyolefin |
| WO2008033410A1 (en) * | 2006-09-14 | 2008-03-20 | Ingenia Polymers Inc. | High concentration pelletized additive concentrates for polymer |
| EP2397510A1 (en) * | 2006-09-14 | 2011-12-21 | Ingenia Polymers Inc. | High concentration pelletized additive concentrates for polymer |
| EP2061831B1 (en) | 2006-09-14 | 2012-03-28 | Ingenia Polymers Inc. | A method for preparing high concentration pelletized additive concentrates for polymer |
| US9193838B2 (en) | 2006-09-14 | 2015-11-24 | Ingenia Polymers, Inc. | High concentration pelletized additive concentrates for polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| AU4398889A (en) | 1990-05-10 |
| GB8924596D0 (en) | 1989-12-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |