GB2288808A - Moulding compositions containing a polyamide - Google Patents
Moulding compositions containing a polyamide Download PDFInfo
- Publication number
- GB2288808A GB2288808A GB9407686A GB9407686A GB2288808A GB 2288808 A GB2288808 A GB 2288808A GB 9407686 A GB9407686 A GB 9407686A GB 9407686 A GB9407686 A GB 9407686A GB 2288808 A GB2288808 A GB 2288808A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- moulding
- polyamide
- nylon
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 238000000465 moulding Methods 0.000 title claims abstract description 31
- 239000004952 Polyamide Substances 0.000 title claims abstract description 14
- 229920002647 polyamide Polymers 0.000 title claims abstract description 14
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 10
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 10
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 8
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 6
- 229920002302 Nylon 6,6 Polymers 0.000 claims abstract description 5
- 239000003302 ferromagnetic material Substances 0.000 claims description 2
- 230000003014 reinforcing effect Effects 0.000 claims description 2
- 230000007547 defect Effects 0.000 abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 6
- 239000003063 flame retardant Substances 0.000 abstract description 6
- 229920001778 nylon Polymers 0.000 description 6
- 239000004677 Nylon Substances 0.000 description 5
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical compound CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007676 flexural strength test Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3415—Five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A moulding composition contains a polyamide, eg nylon 6 or nylon 66, and, optionally, a filler, such as magnesium hydroxide which acts as a flame-retardant. In order to reduce surface defects in the moulding, the composition also contains phthalimide.
Description
MOVLDING COMPO < ITIONS CONTAINING A POLYAMIDE This invention is concerned with moulding compositions which contain a polyamide, e.g. nylon 6 or nylon 66, and is especially concerned with such compositions which contain a filler, eg magnesium hydroxide as a flame retardant.
Polyamides, such as nylons, are widely used for moulding components and, for some moulding applications, are mixed with a flame-retardant so that the moulded component exhibits flame retardant characteristics. Such applications include electrical lamp-holders, and switch housings.
Magnesium hydroxide is a flame retardant which has been suggested for use with nylon. This material, when subjected to a flame, decomposes endothermically with the liberation of water. Nylon containing magnesium hydroxide has, however, been found to be difficult to mould because of its high melt viscosity and, furthermore, it is found that the mouldings have obvious surface defects which render them unacceptable commercially. Such surface defects manifest themselves by the appearance of white patches on the surface of the moulding. Various attempts have been made to overcome this problem but without achieving complete success. The most successful previous attempt known to the applicants involves the addition of organic sulphonamide to the moulding composition (see GB 2,237,573A) but even this has not achieved total success.
It is an object of the present invention to provide a moulding composition containing a polyamide which produces mouldings which are substantially free of surface defects of the type referred to.
It is a further object of the invention to provide a moulding composition containing a polyamide and magnesium hydroxide which'produces mouldings which are substantially free of surface defects of the type referred to.
The invention provides a moulding composition containing a polyamide wherein the composition also contains phthalimide.
Phthalimide is recorded in the Chemical Abstract
Service Registry under number CAS 85-41-6.
A moulding composition according to the invention is found to produce mouldings with reduced surface defects.
The composition is also found to be easier to mould making it possible to mould compositions with higher concentrations of fillers.
Preferably, the phthaimide provides 0.1 to 5 per cent by weight of the composition, eg 0.5 to 5 per cent. In some compositions, about 1 per cent of phthalimide is found to result in saleable mouldings, ie with an acceptable level of surface detects, and 2.5 per cent was found to result in substantially no discernable surface defects.
The polyamide may be nylon 6, nylon 66, nylon 6.12, nylon 6.10 or another suitable polyamide. The polyamide may also be a co-polymer of two forms of nylon, eg nylon 6 and nylon 66.
The composition may also comprise a filler, eg flameretardant such as magnesium hydroxide which may be present in 45 to 65 per cent by weight of the composition, or if a lower standard of flame-retardancy is acceptable, the percentage may be 20 to 45. The composition may contain additional fillers, for example, a ferromagnetic material such as strontium ferrite. The composition may also contain reinforcing fibres, e.g. glass fibres, which may be present in up to 35% by weight depending on the amount of magnesium hydroxide or other filler which is present. A plasticiser may also be used, eg butyl benzene sulphonamide which may be present in amounts of approximately 1.25 per cent by weight.
There now follow detailed descriptions of two moulding compositions which are illustrative of the invention.
The first illustrative moulding composition was a formulation of 40 parts nylon 6, 60 parts magnesium hydroxide (Magnifin H5), 0.3 parts calcium stearate (as a mould lubricant), 1 part phthalimide, and 25 parts glass fibre (all parts by weight). The composition was injection moulded into test discs which were subjected to tests in comparison with a comparison composition of the same formulation but with the phthalimide omitted.
The discs made from the comparison composition had very noticeable surface defects in the form of white marks covering the surface. It was considered that mouldings made from the comparison composition would have been unsaleable as their appearance would have been unacceptable to a customer. The discs moulded from the first illustrative composition had noticeable surface defects but these were far less marked than in the comparison composition. It was considered that mouldings made from the first illustrative composition would have been acceptable to customers.
In a flammability test, the discs made from the comparison composition gave a mean burn time of 3.6 seconds which is within acceptable limits. A tensile strength test gave an average value of 120NPa, an elongation at break test gave a value of 1.1%. A flexural strength test gave a value of 192NPa. These tests were repeated using the discs made from the first illustrative composition. The mean burn time was 4.7 seconds (also acceptable), the tensile strength was 126spa, the elongation at break was 1.0%, and the flexural strength was 192spa. Thus, in all the tests, the first illustrative composition substantially equalled the comparison composition. The first illustrative composition was also easier to mould.
The second illustrative composition was the same as the first except that 2.5 parts by weight of phthalimide and 70 parts by weight of magnesium hydroxide were included. Discs injection moulded from the second illustrative composition were found to have no discernable surface defects in the form of white marks. The abovementioned tests were repeated for the second illustrative composition. The mean burn time was measured as 1.5 seconds, the tensile strength as 121MPa, the elongation at break as 1.3%, and the flexural strength as 191spa.
The first and the second illustrative compositions were both easier to mould, ie required less injection force, than the comparison composition.
Claims (10)
1 A moulding composition containing a polyamide wherein
the composition also contains phthalimide.
2 A moulding composition according to Claim 1, wherein
the phthalimide comprises 0.1 to 5 per cent by weight
of the composition.
3 A moulding composition according to either one of
claims 1 and 2, wherein the polyamide is nylon 6.
4 A moulding composition according to either one of
claims 1 and 2, wherein the polyamide is nylon 66.
5 A moulding composition according to any one of Claims
1 to 4, wherein the composition also comprises a
filler.
6 A moulding composition according to claim 5, wherein
filler is magnesium hydroxide.
7 A moulding composition according to any one of claims
1 to 4, wherein the composition also comprises a
ferromagnetic material.
8 A moulding composition according to any one of Claims
1 to 7, wherein the composition also contains
reinforcing fibres.
9 A moulding composition substantially as hereinbefore
described with reference to the first illustrative
composition or the second illustrative composition.
10 A component moulded from a moulding composition
according to any one of claims 1 to 9.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9407686A GB2288808A (en) | 1994-04-19 | 1994-04-19 | Moulding compositions containing a polyamide |
| PCT/GB1995/000875 WO1995028439A1 (en) | 1994-04-19 | 1995-04-18 | Moulding compositions containing a polyamide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9407686A GB2288808A (en) | 1994-04-19 | 1994-04-19 | Moulding compositions containing a polyamide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB9407686D0 GB9407686D0 (en) | 1994-06-15 |
| GB2288808A true GB2288808A (en) | 1995-11-01 |
Family
ID=10753729
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9407686A Withdrawn GB2288808A (en) | 1994-04-19 | 1994-04-19 | Moulding compositions containing a polyamide |
Country Status (2)
| Country | Link |
|---|---|
| GB (1) | GB2288808A (en) |
| WO (1) | WO1995028439A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3016344B2 (en) | 1994-12-19 | 2000-03-06 | 三菱電機株式会社 | Switch |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0247475A2 (en) * | 1986-05-27 | 1987-12-02 | Bayer Ag | Flame-resistant polyamides |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1536081A (en) * | 1966-09-08 | 1968-08-09 | Bayer Ag | Polyamide molding compositions |
| JPS60232610A (en) * | 1984-05-04 | 1985-11-19 | 旭化成株式会社 | Molding material for electric part |
| GB8924804D0 (en) * | 1989-11-03 | 1989-12-20 | T & N Technology Ltd | Polyamide moulding compositions |
| DE4221925A1 (en) * | 1992-07-03 | 1994-01-05 | Bayer Ag | Flame retardant polyamide molding compounds |
-
1994
- 1994-04-19 GB GB9407686A patent/GB2288808A/en not_active Withdrawn
-
1995
- 1995-04-18 WO PCT/GB1995/000875 patent/WO1995028439A1/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0247475A2 (en) * | 1986-05-27 | 1987-12-02 | Bayer Ag | Flame-resistant polyamides |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1995028439A1 (en) | 1995-10-26 |
| GB9407686D0 (en) | 1994-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |