[go: up one dir, main page]

GB2246662A - Testing photodetector devices - Google Patents

Testing photodetector devices Download PDF

Info

Publication number
GB2246662A
GB2246662A GB9026969A GB9026969A GB2246662A GB 2246662 A GB2246662 A GB 2246662A GB 9026969 A GB9026969 A GB 9026969A GB 9026969 A GB9026969 A GB 9026969A GB 2246662 A GB2246662 A GB 2246662A
Authority
GB
United Kingdom
Prior art keywords
light receiving
signal reading
wiring
photodetector device
receiving part
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9026969A
Other versions
GB9026969D0 (en
GB2246662B (en
Inventor
Yasuaki Yoshida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Publication of GB9026969D0 publication Critical patent/GB9026969D0/en
Publication of GB2246662A publication Critical patent/GB2246662A/en
Application granted granted Critical
Publication of GB2246662B publication Critical patent/GB2246662B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/80Constructional details of image sensors
    • H10F39/809Constructional details of image sensors of hybrid image sensors
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R31/00Arrangements for testing electric properties; Arrangements for locating electric faults; Arrangements for electrical testing characterised by what is being tested not provided for elsewhere
    • G01R31/26Testing of individual semiconductor devices
    • G01R31/2607Circuits therefor
    • G01R31/2632Circuits therefor for testing diodes
    • G01R31/2635Testing light-emitting diodes, laser diodes or photodiodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F39/00Integrated devices, or assemblies of multiple devices, comprising at least one element covered by group H10F30/00, e.g. radiation detectors comprising photodiode arrays
    • H10F39/10Integrated devices
    • H10F39/12Image sensors
    • H10F39/18Complementary metal-oxide-semiconductor [CMOS] image sensors; Photodiode array image sensors
    • H10F39/184Infrared image sensors
    • H10F39/1843Infrared image sensors of the hybrid type

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Solid State Image Pick-Up Elements (AREA)
  • Testing Or Measuring Of Semiconductors Or The Like (AREA)
  • Transforming Light Signals Into Electric Signals (AREA)

Abstract

A photodetector device includes a light receiving part 1 such as a photodiode array, a signal reading-out part 2 such as a silicon charge coupled device first bumps for electrically connecting the light receiving pant and the signal reading-out part, a test element 15, 16 disposed on the light receiving part, a wiring 26 disposed on the signal reading-out part, and a second bump 3 arranged so as to electrically connect the test element and the wiring. A probe card is touched on the wiring of the signal reading out part and a characteristic of a pn junction of the light receiving part is thus measured. Therefore, the characteristic of a test element provided on the light receiving part can be measured after it is flip-chip bonded, whereby fault analysis can be easily performed. The device may be an infra red imager. <IMAGE>

Description

A Photodetector Device FIELD OF THE INVENTION The present invention relates to a photodetector device, and more particularly to a test structure of an infrared imager.
BACKGROUND OF THE INVENTION Figure 8 shows a perspective view of a prior art infrared imager and figure 9 is a schematic diagram of figure 8. In these figures, reference numeral 1 designates a two dimensional photodiode array including, for example, 128 x 128 pieces of pixels. A silicon CCD 2 for conducting signal reading-out is disposed on the two dimensional photodiode array 1. Indium bumps 3 are disposed between the silicon CCD 2 and the two dimensional photodiode array 1 thereby to connect them. Reference numeral 4 designates an incident ray. Reference numeral 5 designates an output circuit, reference numeral 6 designates a vertical CCD, and reference numeral 7 designates a horizontal CCD.
The two dimensional photodiode array 1 and silicon CCD 2 are electrically connected by indium bumps 3. The infrared ray 4 detected by a two dimensional photodiode ~ array 1 is stored for a predetermined time by the silicon CCD 2 and is converted into a time sequence signal, thereby to be output from the output circuit 5.
When Cdo 2Hgo 8Te is used as material of the two dimensional photodiode array 1 constituting the above described infrared imager, it is well known that imaging of infrared ray of 10 micron band is possible.
Figure 4 shows a plan view showing a structure of a two dimensional photodiode array using Cdo 2Hgo 8Te and figure 5 shows a cross-sectional view in lines A-A' of figure 4.
In these figures, a substrate 9 comprises CdTe. A p type semiconductor layer 8 comprising Cdo 2Hgo 8Te is disposed on the substrate 9. N type region 28 is produced at the surface region of the semiconductor layer 8, and forms a pn junction 10 with semiconductor layer 8. Reference numeral 11 designates a incident light receiving region in the photodiode array 1. A test element group (hereinafter referred to as TEG") 12 which is formed n side electrode pads 15 and a p side electrode pad 16 are disposed on the region except for the rectangular light receiving region ll.
A p side electrode 18 is provided on the surface of the semiconductor layer 8 except for the light receiving region ll. N side electrode pads 13 are disposed on the n type region 28 in the light receiving region 11, and p side electrode pad 14 is disposed on the p side electrode 18 confronting to the n side electrode pads. And an insulating film 17 is provided on the surface of the semicondúctor layer 8 and on the p side electrode 18. N+ layer 28-is produced in the semiconductor layer 8.
Figure 4 shows an example of 3 x 3 pixels in the light receiving region 11. Usually a device having such as 128 x 128 pixels is used.
In the two dimensional photodiode array of the above described structure, infrared ray 4 is incident from the side of the substrate 9 and is converted into electron whole pairs in the semiconductor layer 8, and those which have - reached the pn junction 10 by diffusion is detected as a signal.
The TEG 12 monitors the characteristics of the pn junction 10 produced on the two dimensional photodiode array 1 by touching a probe of a probe card on the n side electrode pad 15 and the p side electrode pad 16 of TEG, such as I-V characteristics of the pn junction 10 can be measured.
Figure 6 is a plan view showing silicon CODs connecting two dimensional photodiode arrays of figure 4, figure 7 shows a cross-sectional view in lines B-Bg of figure 6. In these figures, reference numeral 19 designates a p type silicon substrate and an n+ region 20 is produced in the p type silicon substrate 19. An insulating film 22 is provided on the surface of the p type silicon substrate 19 and pads 21 are provided on the p type silicon substrate 19 or on the n+ layer 20 through the insulating film 22.
Reference numeral 23 designates a bonding pad and reference numeral 24 designates a wiring for driving vertical CCD 6 and horizontal CCD 7, and the wiring 24 is schematically shown and the detail thereof is not shown.
A vertical CCD 6 is a CCD for collecting charges in the vertical direction and a horizontal CCD 7 is a CCD for collecting charges in the horizontal direction. An output circuit 5 is provided to output the output of the horizontal CCD 7.
In the above described two dimensional photodiode array 1, when wafer process is concluded, the characteristics of pn junction 10 is evaluated by TEG 12 and make sure of the quality of the photodiode array 1 and selected, and thereafter, an indium bumps 3 is produced on the pad 13 at the side of n side electrode and on the pad 14 at the side of p side electrode. And as shown in figure 3, it is flipchip bonded at high temperature about 150 C and is thermocompression bonded to the silicon CCD 2, thereby completing an infrared imager.
As described above, while a two dimensional photodiode array 1 is flip-chip bonded on a silicon CCD 2, a process of thermocompression bonding at high temperature is required.
Therefore, the two dimensional photodiode array 1 is likely to deteriorate due to the thermal stress and mechanical stress at the bonding and further it is necessity to cool the device at about 77 K when it is really operated. Therefore, there is great possibility that there arises cracks in the two dimensional photodiode array by the thermal stress due to the difference in the thermal expansion coefficient between the silicon substrate 19 of the silicon CCD 2 and the CdTe substrate 9 of the photodiode array 1.
However, in the prior art infrared imager constituted as above, the characteristics of the two dimensional photodiode array 1 can not be directly monitored after the two dimensional photodiode array and the silicon CCD 2 are flip-chip bonded, and therefore the I-V characteristics of the two dimensional photodiode array 1 deteriorates due to the above described cause. Thus even if the sensitivity of the infrared imager is deteriorated, it can not be specified whether the cause of default resides in the two dimensional photodiode array 1 or in the silicon CCD 2.
SUMMARY OF THE INVENT ION The present invention is directed to solving the above described problems and has for its object to provide a photodetector device capable of monitoring the characteristics of the two dimensional photodiode array even after it is flip-chip bonded.
Other objects and advantages of the present invention will become apparent from the detailed description given hereinafter; it should be understood, however, that the detailed description and specific embodiment are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art from this detailed description.
In accordance with the present invention, a test element disposed on a light receiving substrate and a wiring connected to the test element via a bump provided on the signal reading-out substrate are provided. In measuring a characteristics of a photodetector device, a probe of a probe card is touched on the wiring of a signal reading-out substrate and a characteristics of a pn junction of the light receiving substrate is measured. Therefore, even after the light receiving substrate and signal reading out substrate are electrically connected by flip-chip bonding on the characteristics of a test element disposed on a light receiving part substrate can be directly specified.
BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a plan view showing a silicon CCD of a photodetector device in accordance with a first embodiment of the present invention; Figure 2 is a cross-sectional view showing a photodetector device in accordance with the first embodiment of the present invention; Figure 3 is a cross-sectional view showing a photodetector device according to the prior art; Figure 4 is a plan view showing a two dimensional photodiode array which is common through the present invention and the prior art; Figure 5 is a cross-sectional view in line A-A' of figure 4; Figure 6 is a plan view showing a silicon CCD according to the prior art; Figure 7 is a cross-sectional view in line B-B' of figure 6; Figure 8 is a perspective view showing a photodetector device according to the prior art; and Figure 9 is a schematic diagram showing the device of figure 8.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT An embodiment of the present invention will be described in detail with reference to the drawings.
Figure 1 shows a plan view of a silicon CCD of a photodetector device in accordance with a first embodiment of the present invention and figure 2 shows a cross-section of the photodetector device corresponding to C-C' crosssection of figure 1.
In figure 2, the two dimensional photodiode array 1 itself is the same as that of the prior art. An n side electrode pad 15 of the TEG 12 for monitoring the characteristics of the pn junction 10 is produced on the two dimensional photodiode array 1 through the insulating film 17. A p side electrode pad 16 is provided connected with the p side electrode metal 18 through the insulating film 17. A connection pad 25 of the TEG 12 is provided on the substrate 19 of the silicon CCD 2. A wiring 26 for taking out the signal of the TEG 12 is disposed on the insulating film 22 provided on the surface of the p type silicon substrate 19 of silicon CCD 2. A bonding pad 27 is provided at the end of the wiring 26 of the TEG 12.
The n side electrode pad 15 of the TEG 12 of the two dimensional photodiode array 1 is electrically connected with the pad 25 which is newly provided on the insulating film 22 of the silicon CCD 2 via indium bump 3, and the pad 25 is connected with a bonding pad 27 by the wiring 26 on the surface of the insulating film 22 for taking out the detecting signal of the TEG 12.
In the structure of this embodiment, in producing step of silicon CCD 2, the pad 25 for connecting the TEG 12 provided on the photodiode array 1, the wiring 26, and the bonding pad 27 are produced on the insulating film 22 of the silicon CCD at the same step of producing the pad 21 and while flip-chip bonding the silicon CCD 2 and the two dimensional photodiode array 1, the n side electrode pad 15 of the TEG 12 on the two dimensional photodiode array 1 and the TEG connection pad 25 on the CCD 2 are connected by indium bump 3, and thus the structure is easily obtained.
In such structure of the embodiment, even after the photodiode array 1 and the CCD 2 are flip-chip bonded, the characteristics of the pn junction 10 of the photodiode array 1 such as I-V characteristics, can be measured easily by touching a probe of a probe card on the bonding pad part 27, thereby even if the sensitivity of the infrared imager is deteriorated, it is possible to accurately specify whether the cause of default of the photodetector device resides in the light receiving part or the reading-out part after the flip chip bonding, thereby enabling to perform a faulty analysis easily.
While in the above illustrated embodiment a silicon CCD is used in the signal reading-out part, the present invention can be also applied to the other signal readingout method comprising such as MOS system.
While in the above illustrated embodiment an infrared imager element is described, other sensor such as visible imager can be employed by replacing the light receiving section.
As is evident from the foregoing description, according to the present invention, a test element is disposed on the light receiving part substrate, a wiring is arranged on the signal reading-out substrate insulated from the other parts, and the test element and the wiring are connected via bumps.
Therefore, the characteristics of the test element provided on the light receiving part substrate can be measured even after it is flip-chip bonded, thereby enabling to perform faulty analysis easily,

Claims (9)

WHAT IS CLAIMED IS:
1. A photodetector device, comprising: a light receiving part including a pn junction; a signal reading-out part; first bumps for electrically connecting said light receiving part and said signal reading-out part; a test element disposed on said light receiving part; a wiring disposed on said signal reading-out part; and second bump arranged so as to electrically connect said test element and said wiring.
2. A photodetector device of claim 1 wherein said light receiving part comprises a two dimensional photodiode array.
3. A photodetector device of claim 1 wherein said signal reading-out part comprises silicon CCDs or is of MOS type signal reading-out system.
4. A photodetector device of claim 1 wherein said wiring disposed on the signal reading-out part is insulated from other elements.
5. A photodetector device of claim 1 wherein said wiring has a second bump bounding portion and a probe card touching portion.
6. A photodetector device of claim 1 wherein said light receiving part detects infrared ray.
7. A method for measuring a characteristic of a photodetector device, comprising a light receiving part including a pn junction, a signal reading-out part, first bumps for electrically connecting said light receiving part and said signal reading-out part, a test element disposed on said light receiving part, a wiring disposed on said signal reading-out part, and second bump arranged so as to electrically connect said test element and said wiring, which method comprises: touching a probe of a probe card on said wiring of said signal reading-out part; and a characteristics of said pn junction of said light receiving part being measured.
8. A method for measuring a characteristic of a photodetector device of claim 7 wherein said wiring has a second bump bounding portion and a probe card touching portion, and said probe of probe card is touched on said probe card touching portion of said wiring.
9. A photodetector device when constructed, adapted and arranged to perform substantially as described hereinbefore with reference to and as shown in figures 1 and 2 of the drawings.
9. A photodetector device including an array of photodetective elements for light detection together with a plurality of additional photodetective elements, separately wired from the elements of said array, by which means testing can be performed during operational use of the device.
10. A photodetector device when constructed adapted and arranged to perform substantially as described hereinbefore with reference to and as shown in figures 1 and 2 of the drawings.
GB9026969A 1990-07-30 1990-12-12 A photodetector device Expired - Fee Related GB2246662B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2201768A JPH0485961A (en) 1990-07-30 1990-07-30 light detection device

Publications (3)

Publication Number Publication Date
GB9026969D0 GB9026969D0 (en) 1991-01-30
GB2246662A true GB2246662A (en) 1992-02-05
GB2246662B GB2246662B (en) 1994-08-24

Family

ID=16446622

Family Applications (1)

Application Number Title Priority Date Filing Date
GB9026969A Expired - Fee Related GB2246662B (en) 1990-07-30 1990-12-12 A photodetector device

Country Status (3)

Country Link
JP (1) JPH0485961A (en)
FR (1) FR2665302B1 (en)
GB (1) GB2246662B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2263980A (en) * 1992-02-07 1993-08-11 Marconi Gec Ltd Testing integrated circuit dies
GB2274739A (en) * 1993-01-29 1994-08-03 Mitsubishi Electric Corp Testing photodetectors
GB2340997A (en) * 1998-08-26 2000-03-01 Lsi Logic Corp Optoelectronic integrated circuit and method of testing
WO2003017372A1 (en) * 2001-08-14 2003-02-27 Infineon Technologies Ag Photodiode arrangement with two photodiodes
FR2829615A1 (en) * 2001-09-10 2003-03-14 Agere Syst Guardian Corp INTERCONNECTION STRUCTURE BETWEEN HIGH DENSITY CHIPS
WO2019160517A3 (en) * 2018-02-15 2019-09-12 Aselsan Elektroni̇k Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ A method for improving the flip-chip bonding process
EP3624191A1 (en) * 2018-09-12 2020-03-18 Sensors Unlimited, Inc. Interconnect bump structures for photo detectors

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5596222A (en) * 1994-08-12 1997-01-21 The Charles Stark Draper Laboratory, Inc. Wafer of transducer chips
US5756395A (en) * 1995-08-18 1998-05-26 Lsi Logic Corporation Process for forming metal interconnect structures for use with integrated circuit devices to form integrated circuit structures
JP2007258199A (en) * 2006-03-20 2007-10-04 Nec Electronics Corp Image sensor
JPWO2008142968A1 (en) * 2007-05-21 2010-08-05 株式会社島津製作所 Image pickup device and image pickup apparatus including the same
KR101004024B1 (en) * 2009-12-29 2010-12-31 한국지질자원연구원 Non-contact rockfall detection method using optical sensor
JP7555697B2 (en) * 2018-12-14 2024-09-25 キヤノン株式会社 Photoelectric conversion device, method for manufacturing photoelectric conversion device, and method for manufacturing semiconductor device

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4709141A (en) * 1986-01-09 1987-11-24 Rockwell International Corporation Non-destructive testing of cooled detector arrays
EP0271522A1 (en) * 1986-06-26 1988-06-22 Santa Barbara Research Center Backside contact blocked impurity band detector
US4943491A (en) * 1989-11-20 1990-07-24 Honeywell Inc. Structure for improving interconnect reliability of focal plane arrays

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2263980A (en) * 1992-02-07 1993-08-11 Marconi Gec Ltd Testing integrated circuit dies
US5406210A (en) * 1992-02-07 1995-04-11 Gec-Marconi Limited Apparatus and method for testing bare dies with low contact resistance between the die and testing station
GB2263980B (en) * 1992-02-07 1996-04-10 Marconi Gec Ltd Apparatus and method for testing bare dies
GB2274739A (en) * 1993-01-29 1994-08-03 Mitsubishi Electric Corp Testing photodetectors
FR2701164A1 (en) * 1993-01-29 1994-08-05 Mitsubishi Electric Corp Photodetector.
US5371352A (en) * 1993-01-29 1994-12-06 Mitsubishi Denki Kabushiki Kaisha Photodetector comprising a test element group of PN junctions and including a mask having at least one window spaced apart from the PN junctions
GB2274739B (en) * 1993-01-29 1996-09-11 Mitsubishi Electric Corp Photodetector
GB2340997A (en) * 1998-08-26 2000-03-01 Lsi Logic Corp Optoelectronic integrated circuit and method of testing
WO2003017372A1 (en) * 2001-08-14 2003-02-27 Infineon Technologies Ag Photodiode arrangement with two photodiodes
US6853665B2 (en) 2001-08-14 2005-02-08 Infineon Technologies Ag Photodiode configuration having two photodiodes, a laser diode configuration having the photodiode configuration, and method for connecting the photodiode configuration to a substrate
FR2829615A1 (en) * 2001-09-10 2003-03-14 Agere Syst Guardian Corp INTERCONNECTION STRUCTURE BETWEEN HIGH DENSITY CHIPS
US7045835B2 (en) 2001-09-10 2006-05-16 Agere Systems Inc. High-density inter-die interconnect structure
WO2019160517A3 (en) * 2018-02-15 2019-09-12 Aselsan Elektroni̇k Sanayi̇ Ve Ti̇caret Anoni̇m Şi̇rketi̇ A method for improving the flip-chip bonding process
EP3624191A1 (en) * 2018-09-12 2020-03-18 Sensors Unlimited, Inc. Interconnect bump structures for photo detectors
US10727267B2 (en) 2018-09-12 2020-07-28 Sensors Unlimited, Inc. Interconnect bump structures for photo detectors
US10957733B2 (en) 2018-09-12 2021-03-23 Sensors Unlimited, Inc. Interconnect bump structures for photo detectors

Also Published As

Publication number Publication date
FR2665302B1 (en) 1994-01-28
GB9026969D0 (en) 1991-01-30
GB2246662B (en) 1994-08-24
JPH0485961A (en) 1992-03-18
FR2665302A1 (en) 1992-01-31

Similar Documents

Publication Publication Date Title
US6107618A (en) Integrated infrared and visible image sensors
US6232655B1 (en) Semiconductor element having external connection terminals, method of manufacturing the semiconductor element, and semiconductor device equipped with the semiconductor element
US9054010B2 (en) Large-scale X-ray detectors
GB2246662A (en) Testing photodetector devices
KR20030022724A (en) High-density inter-die interconnect structure
Gemme et al. Study of indium bumps for the ATLAS pixel detector
US4792672A (en) Detector buffer board
JP2653550B2 (en) Solid-state imaging device
Barber et al. Development of a 64× 64 CdZnTe array and associated readout integrated circuit for use in nuclear medicine
CN101393151A (en) Method for detecting the connectivity of indium pillars in infrared focal plane interconnection by thermal resistance method
US4871921A (en) Detector array assembly having bonding means joining first and second surfaces except where detectors are disposed
US6559670B1 (en) Backside liquid crystal analysis technique for flip-chip packages
US5371352A (en) Photodetector comprising a test element group of PN junctions and including a mask having at least one window spaced apart from the PN junctions
JP2827934B2 (en) Hybrid type infrared sensor
Gibbons et al. Status of CID InSb detector technology
Hoendervoogt et al. Hybrid InSb focal plane array fabrication
Takemoto et al. Reliable 4 million micro bumps at 7.6-um pitch interconnection technology for 3D stacked 16 million pixel image sensor
Takemoto et al. Characterization of 4 Million Micro-Bump Interconnections at 7.6-$\mu\text {m} $ Pitch for 3-D Stacked 16 Million Pixel Image Sensor
JP2885563B2 (en) Photodetector
Shirouzu et al. 64 x 64 InSb focal plane array with improved two layer structure
US4727406A (en) Pre-multiplexed detector array
JPH0568106B2 (en)
WO2024157624A1 (en) Semiconductor device and electronic apparatus
JPH07321367A (en) Infrared detector
KR200194294Y1 (en) Package for Solid State Imaging Device

Legal Events

Date Code Title Description
746 Register noted 'licences of right' (sect. 46/1977)

Effective date: 19951107

PCNP Patent ceased through non-payment of renewal fee

Effective date: 19991212