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GB2138438A - Shaving composition - Google Patents

Shaving composition Download PDF

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Publication number
GB2138438A
GB2138438A GB08310640A GB8310640A GB2138438A GB 2138438 A GB2138438 A GB 2138438A GB 08310640 A GB08310640 A GB 08310640A GB 8310640 A GB8310640 A GB 8310640A GB 2138438 A GB2138438 A GB 2138438A
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GB
United Kingdom
Prior art keywords
component
shaving composition
weight percent
shaving
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08310640A
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GB2138438B (en
GB8310640D0 (en
Inventor
George Herman Michel
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to GB08310640A priority Critical patent/GB2138438B/en
Publication of GB8310640D0 publication Critical patent/GB8310640D0/en
Publication of GB2138438A publication Critical patent/GB2138438A/en
Application granted granted Critical
Publication of GB2138438B publication Critical patent/GB2138438B/en
Expired legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00Preparations for removing hair or for aiding hair removal
    • A61Q9/02Shaving preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dermatology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

A solid shaving composition comprising: a. a water soluble polyethylene oxide polymer of a molecular weight of 400,000 or less in an amount ranging from 1 to 65 weight percent. b. a trackability component in an amount ranging from 20 to 80 weight percent. c. a preservative component in an amount ranging from 0.005 to 7.5 weight percent and d. an anti-caking component in an amount ranging from 1 to 20 weight percent. The composition of the invention may include a humectant component in an amount of up to 20 weight percent and/or a lubricant component in an amount of up to 10 weight percent.

Description

SPECIFICATION Shaving composition This invention relates to shaving compositions useful in application during the shaving process.
More particularly, this invention relates to shaving compositions comprising water soluble polyethylene oxide polymers. Still more particularly, this invention relates to shaving compositions comprising water soluble polyethylene oxide polymers having a molecular-weight of 400,000 or less, a trackability component, a preservative component, an anti-caking component, and, optionally, a lubricant component, and/or a humectant component.
The American marketplace is replete with a wide variety of shaving compositions. The vast majority of these shaving compositions are soap or surfactant based aerosol foams. These products are heavily advertized and widely used in the USA. The more traditionally inclined shaver often employs the shaving brush/soap dish method for applying a preparation to the skin surface prior to the shaving process. However, whatever the process, the shaver must store and handle the relatively bulky containers necessary for these shaving compositions. It would be desirable for a variety of applications if the bulk and weight of the shaving composition could be reduced.
To this end, workers in the field have developed a variety of new shaving compositions.
Several of these compositions contain high molecular weight, water soluble polymers and other ingredients to facilitate the passage of the razor blade over the skin surface and to protect the skin from the abrading action of the razor edge. U.S. Patent Nos. 3,811,349 and 3,956,951 disclose shaving compositions comprising high molecular weight polyethylene oxide polymers of a molecular weight of about 4,000,000. U.S. Patent No. 3,811,349 discloses a solid aqueous solution of the polyethylene oxide polymer while U.S. Patent No. 3,956,951 discloses a simple solvent-free polyethylene oxide tablet. Testing has shown that neither of these compositions is particularly effective.
A somewhat different approach is illustrated in U.S. Patent No. 4,291,463 which teaches a polyethylene oxide coating applied to a razor blade for lubrication purposes.
The shaving composition of the invention comprises a water soluble polyethylene polymer having a molecular weight of 400,000 or less, a suitable trackability component, a preservative component and an anti-caking component. Optionally, a lubricant component and/or a humectant component may also be employed. This composition is particularly useful when moulded into an effective solid form which can be rubbed over the surface of the user's skin prior to the application of the blade razor. Application of the shaving composition of this invention acts to soften the hair, add moisture to the skin, retain it in place by the action of a micro-protective polymer film layer which, in turn, provides a visual indication to the user trackability) of the path of the razor blade over the skin surface as well as the extent of the initial coverage of the composition upon application.
According to the present invention there is provided a solid shaving composition comprising: a. a water soluble polyethylene oxide polymer of a molecular weight of 400,000 or less in an amount ranging from 1 to 65 weight percent; b. a trackability component in an amount ranging from 20 to 80 weight percent: c. a preservative component in an amount ranging from 0.005 to 7.5 weight percent and d. an anti-caking component in an amount ranging from 1 to 20 weight percent.
The composition of the present invention may further include a humectant component in an amount of up to 20 weight percent. Furthermore, the composition may additionally include a lubricant component in an amount of up to 10 weight percent.
A major component in this shaving composition is water soluble polyethylene oxide having a molecular weight of 400,000 or less. The polyethylene oxide polymer is composed of repeating units of the form:
wherein the degree of polymerization, n, is such that the molecular weight of the corresponding high polymer is less than about 400,000. This polymer hydrogen bonds strongly with water.
One particularly suitable source of supply for this polymer has been Polyox WSR N series of resins produced by the UNION Carbide Company. In particular, Polyox WSR N-3000 having an approximate molecular weight of 400,000 has been effective. The polyethylene oxides of molecular weight of 400,000 or less have proven to be particularly effective due to their shear stability characteristics which are necessary for shaving applications, particularly at temperatures in the range of 40"C to 80"C, especially when compared to polyethylene oxides of higher molecular weight such as those found in the Polyox WSR series which have molecular weights of 600,000 and above.The improved shear stability characteristic allows for consistent uniformity of the polymeric film which is produced when the shaving composition is applied to the skin surface of the user.
The prior art shaving compositions, particularly those which employ polyethylene oxides having molecular weights in the range of 4,000,000, have been shown through testing to be significantly inferior in performance to the shaving composition of this invention which utilizes polyethylene oxides of molecular weights of 400,000 or less. In particular, the high molecular weight polyethylene oxides, when employed as shaving compositions, dry out very rapidly on the skin surface and, consequently, do not allow sufficient time to complete a shaving operation.
Additionally, the high molecular weight polyethylene oxide shaving compositions cause the blade razor to clog easily in that these polymers form a gel-like, stringy mixture on the skin surface of the user due to the longer length of these particular molecules. This stringyness problem is not unique to the polyethylene oxides having molecular weights of 4,000,000 and above, since the problem extends down to the range of molecular weights of about 900,000.
The use, therefore, of polyethylene oxide polymers of 400,000 molecular weight or less is, therefore, a significant improvement over the water-based polymers disclosed in the prior art.
It has also been found that it is very desirable to provide a trackability characteristic to the shaving composition such that the user can ascertain those portions of the skin surface to which the shaving composition has been applied, and also those portions of the skin surface over which the razor has already passed during the shaving operation. In some instances, it may be desirable to combine a pigment with a fatty acid-based molecule to produce a trackability agent for inclusion into the shaving composition. In general, the longer carbon chain fatty acid molecules will produce compositions with better lubrication and dispersion characteristics, reaching an optimum with lauric acid. The pigments for use in such a trackability agent should be very fine in particle size, in the range of 200 to 400 mesh or finer.A few of the suitable pigments for use in the trackability agent are titanium oxide, zinc oxide, calcium sulphate, calcium carbonate, talc, and diatomaceous earth. In addition to the use of pigments in the trackability agent, it is also possible to incorporate dyes which complex directly with the water soluble polymer. Such dyes, however, should bond semi-permanently to the polyethylene oxide such that the dye is not released to the surface of the skin or elsewhere in order that the overall cleanliness of the shaving operation be maximized. One tracking agent that has displayed excellent characteristics is Igepon, produced and marketed by GAF Corporation. Igepon is a sulfa ethyl ester derived from isothionic acid and a coconut oil-based fatty acid of the general formula RCOOCH2CH2SO3Na, where R is an alkyl group.The use of Igepon provides for a shaving composition with excellent tracking characteristics and, further, does not require the addition of a pigment to the compoition. Substitutes for Igepon include stearic acid and other soap-forming fatty acids and their alkali metal salts. Detergents suitable for topical application such as Naccoral may also be used as a part of the trackability component.
Additionally, since the prior art compositions do not contain trackability components, such compositions are essentially invisible upon application. When trackability agents are incorporated into these compositions, the stringy texture of the applied composition becomes visually apparent to the user. This visual characteristic has been found to have a decidedly negative effect during consumer testing.
It is common in the formulation of such polymeric compositions to provide for a preservative component within the system such that bacterial and fungal growth are prevented within the composition. Many ingredients are known in the art for this use, including potassium sorbate, glutaraldehyde, methylparaben, propylparaben, sodium edetate, and various combinations thereof. One such combination which has proved to be highly satisfactory for use in the shaving composition of this invention is the combination of methylparaben (p-hydrozy benzoic acid methyl ester), propylparaben (p-hydroxy benzoic acid propyl ester), and an anti-microbic composition produced by Sutton Labs of Chatham, New Jersey, comprising imidazolidinylurea, labelled Germall 11 5.
Another component which has been found to be desirable for inclusion within this shaving composition is an anti-caking agent which aids in flow during the forming of the shaving composition into suitably shaped solids and also prevents lumping during the compression step.
Many such chemicals are well known in the art. Particularly useful are silica gels, one of the most effective of which is a synthetic composition produced by Davidson Chemical, a Division of Grace Chemicals, Baltimore, Md., called Syloid 244. Other useful anti-caking chemicals include calcium phosphate, magnesium carbonate, calcium silicate, magnesium silicate, and talc.
Additionally, a lubricant component may be included in the composition. In some situations when the composition is formed into its desired final shape by compression within a mould, the addition of a lubricant component such as magnesium stearate or zinc stearate will act to effectively prevent sticking, packing or capping of a tablet or wafer during its formation.
A further component which may be included in the shaving composition is a humectant material. The humectant aids in providing moisturization for the skin during a shaving operation.
One such chemical which has proved to be particularly effective is glycerin. Other useful chemicals include propylene glycol and sorbitol.
The various components may be combined into the shaving composition of this invention in the proportions set forth in Table 1 below.
TABLE 1 COMPONENT USABLE RANGE (WT %) Igepon 20%-80% Polyox WSR N-3000 (Polyethelene Oxide) 1 %-65% Methylparaben 0.05%-2.5% Propylparaben 0.05%-2.5% Germall 115 0.05%-2.5% Syloid 244 1%-20% Magnesium Stearate 0%-10% One formulation of the shaving composition of this invention comprises the following components in the following weight percentages.
PART A COMPONENT (WT %) Igepon AC-78 66.45 Polyox WSR N-3000 (Polyethylene Oxide) 28.16 Methylparaben 0.30 Propylparaben 0.10 Germall 115 0.20 PART B COMPONENT (WT %) Syloid 244 4.79 100.00 TOTAL The method of preparation for this particular formulation is as follows: 1. Weigh out Part A in a Hobart mixer and blend thoroughly.
2. Wet granulate Part A by adding 20% by weight isopropyl aicohol (99.5% pure) to the above formula for part A. (NOTE: The granulation step is critical. The isopropyl alcohol should be added slowly but continuously in order that the granulation does not assume a gummy texture.) 3. The granulated mixture is then dried either by spreading it out in trays at room temperature or by oven drying at about 1 ooh for about 24 hours. In either case, the mixture, if prepared correctly, will be sufficiently dry after about 24 hours. Suitable preparation and drying will be evidenced by the relative ease in the handling of the mixture in the following steps.
4. The dried granulation is then screened by passing the composition through a 20-mesh screen.
5. Part B is then added to the screened formulation of Part A. The two components are blended well such that a free-flowing granular powder is formed.
6. The composition is then compressed into the desired solid form using a suitable press.
The present invention will be further illustrated, by way of example, with reference to the accompanying drawings, in which: Figure 1 is a perspective view of a first embodiment of this invention; and Figure 2 is a perspective view of a second embodiment of this invention.
The shaving composition of this invention may be readily formed into a variety of solid configurations, each adapted to a particular end use. One such configuration, as illustrated in Fig. 1 is a round disc shaped form of a diameter ranging from about 1 inch to about 3 inches (2.54 cm to 7.62 cm) and being from about 1/16 to about 1/4 inch (0.16 cm to 0.64 cm) thick. The thickness of the disc would be tailored such that a sufficient amount of shaving composition would be present to provide the anticipated number of shaving applications envisioned by the manufacturer of the device. Another suitable form, as illustrated in Fig. 2, is a rectangular sliver designed to be of suitable size to be adhered to either the razor head or the razor guard of a particular blade type razor. The exact dimensions of the rectangular sliver would, of course, vary depending upon the exact configuration of the blade type razor for which it was designed to be used. However, suitable sizes would range from about 1 inch to about 1-3/4 inches (2.54 cm to 4.46 cm) long by 1/4 inch to about 3/8 inch (0.64 cm to 0.96 cm) wide by about 1/16 to about 1 /4 inch (0.16 cm to 0.64 cm) thick. The shaving composition of this invention, however, may be readily formed into a variety of other shapes, and the scope of the invention herein should not be read as being limited to the two specificshapes disclosed hereinabove.

Claims (11)

1. A solid shaving composition comprising: a. a water soluble polyethylene oxide polymer of a molecular weight of 400,000 or less in an amount ranging from 1 to 65 weight percent.
b. a trackability component in an amount ranging from 20 to 80 weight percent.
c. a preservative component in an amount ranging from 0.005 to 7.5 weight percent and d. an anti-caking component in an amount ranging from 1 to 20 weight percent.
2. A shaving composition as claimed in claim 1, further comprising a humectant component in an amount of up to 20 weight percent.
3. A shaving composition as claimed in claim 1 or 2, further comprising a lubricant component in an amount of up to 10 weight percent.
4. A shaving composition as claimed in claim 1, 2 or 3, wherein the trackability component comprises a sulfa ethyl ester derived from isothionic acid and a coconut oil-based fatty acid of the general formula. RCOOCH2 CH2 SO3 Na, where R is an alkyl group.
5. A shaving composition as claimed in claim 1, 2 or 3, wherein the trackability component is selected from stearic acid, other soap-forming fatty acids, alkali metal salts of stearic acid and other soap-forming fatty acids, detergents suitable for topical application, and combinations thereof.
6. A shaving composition as claimed in any preceding claim, wherein the preservative component is selected from potassium sorbate, glutaraldehyde methylparaben, propylparaben, sodium edetate, imidazolidinylurea, and combinations thereof.
7. A shaving composition as claimed in any preceding claim, wherein the anti-caking component is selected from silica gel, calcium phosphate, magnesium carbonate, calcium silicate, magnesium silicate and talc.
8. A shaving composition as claimed in claim 3 wherein the lubricant component is selected from magnesium stearate, zinc stearate and combinations thereof.
9. A shaving composition as claimed in claim 2, wherein the humectant component is selected from glycerin, propylene glycol and sorbitol.
10. A shaving composition as claimed in any preceding claim, in the form of a disc having a diameter of from 1.0 to 3.0 inches (2.54 to 7.62 cm) and a thickness of from 1/16 to 1/4 inch (0.16 to 0.64 cm).
11. A shaving composition as claimed in any one of claims 1 to 9 in the form of a rectangular prism having a length of from 1.0 to 1.75 inches (2.54 to 4.46 cm), a width of from 0.25 to 0.375 inches, (0.64 to 0.96 cm) and a thickness of from 0.0625 to 0.25 inches (0.16 to 0.64 cm).
1 2. A shaving composition as claimed in claim 10 or 11 wherein the solid is operably attached to a blade razor or razor guard.
1 3. A solid shaving composition, substantially as hereinbefore described, exemplified and illustrated.
GB08310640A 1983-04-20 1983-04-20 Shaving composition Expired GB2138438B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB08310640A GB2138438B (en) 1983-04-20 1983-04-20 Shaving composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB08310640A GB2138438B (en) 1983-04-20 1983-04-20 Shaving composition

Publications (3)

Publication Number Publication Date
GB8310640D0 GB8310640D0 (en) 1983-05-25
GB2138438A true GB2138438A (en) 1984-10-24
GB2138438B GB2138438B (en) 1986-11-05

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2423494A (en) * 2006-03-23 2006-08-30 Unilever Plc Razor head including acyl isethionate surfactant dispenser
EP2218437A1 (en) * 2009-02-17 2010-08-18 The Gillette Company Shaving compositions comprising dye-loaded particles
US20110041339A1 (en) * 2009-08-21 2011-02-24 The Gillette Company Hair Removal Device
WO2016100001A1 (en) 2014-12-18 2016-06-23 The Gillette Company Lubricating members for razor cartridges
WO2016100000A1 (en) 2014-12-18 2016-06-23 The Gillette Company Lubricating members having hydrophobic components for razor cartridges

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3231565B1 (en) 2016-03-31 2019-09-18 The Gillette Company LLC Razor cartridge with fluid management
EP3231564B1 (en) 2016-03-31 2020-07-01 The Gillette Company LLC Razor cartridge with fluid management system

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1566810A (en) * 1976-06-04 1980-05-08 Colgate Palmolive Co Soap bar manufacture

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1566810A (en) * 1976-06-04 1980-05-08 Colgate Palmolive Co Soap bar manufacture

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2423494A (en) * 2006-03-23 2006-08-30 Unilever Plc Razor head including acyl isethionate surfactant dispenser
EP2218437A1 (en) * 2009-02-17 2010-08-18 The Gillette Company Shaving compositions comprising dye-loaded particles
WO2010096322A1 (en) * 2009-02-17 2010-08-26 The Gillette Company Shaving compositions comprising dye-loaded particles
US20110041339A1 (en) * 2009-08-21 2011-02-24 The Gillette Company Hair Removal Device
WO2011022321A3 (en) * 2009-08-21 2011-04-14 The Gillette Company Hair removal device
CN102481241A (en) * 2009-08-21 2012-05-30 吉列公司 hair removal device
EP2286787A3 (en) * 2009-08-21 2012-10-24 The Gillette Company Hair removal device
WO2016100001A1 (en) 2014-12-18 2016-06-23 The Gillette Company Lubricating members for razor cartridges
WO2016100000A1 (en) 2014-12-18 2016-06-23 The Gillette Company Lubricating members having hydrophobic components for razor cartridges

Also Published As

Publication number Publication date
GB2138438B (en) 1986-11-05
GB8310640D0 (en) 1983-05-25

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