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GB2128615A - Platinum 1,3-propane-diamine complexes - Google Patents

Platinum 1,3-propane-diamine complexes Download PDF

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GB2128615A
GB2128615A GB08328084A GB8328084A GB2128615A GB 2128615 A GB2128615 A GB 2128615A GB 08328084 A GB08328084 A GB 08328084A GB 8328084 A GB8328084 A GB 8328084A GB 2128615 A GB2128615 A GB 2128615A
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platinum
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diamine complex
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Francois Verbeek
Jan Berg
Eric Jan Bulten
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Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
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    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086Platinum compounds
    • C07F15/0093Platinum compounds without a metal-carbon linkage
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/28Compounds containing heavy metals
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P35/00Antineoplastic agents

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Abstract

This invention relates to novel platinum compounds, a method for the preparation thereof, a pharmaceutical composition using the novel compounds and a method for the treatment of cancer using the pharmaceutical composition, wherein the platinum-(II)-diamine complexes are characterized by the formula <IMAGE> wherein R1 and R2 are both ethyl or together with the carbon atom, to which they are bonded, a cyclohexyl group, R3 and R4 are both a hydrogen atom and X is a malonate group, an ethylmalonate group, a hydroxymalonate group, a carboxyphthalate group, a bischloro acetate group, a cyclobutane-1,1-dicarboxylate group, a dinitrate group or an oxalate group or a sodium salt of these groups.

Description

SPECIFICATION Platinum diamine complexes The invention relates to novel platinum-diamine complexes, and to a pharmaceutical composition using such a platinum-diamine complex for the treatment of cancer, for example, malignant swellings and malignant tumors, as well as to a shaped composition obtained by using this process.
Such platinum-diamine complexes are known from the article by A. P. Zipp and S. G. Zipp, J.
Chem. Ed., 54 (12), (1977), page 739, which describes the application of cis-platinum diamine dichloride (PDD) for the treatment of cancer. It is mentioned that the platinum compounds have a broad spectrum of activity as antitumor agents, but also that they have serious drawbacks, in particular that they are toxic to the kidneys. As method for counteracting the kidney toxicity a cis-platinum diamine dichloride is often used in combination with another substance or administered with large quantities of liquid or other techniques are used to bring about an adequate flow-through of the kidneys. A number of other platinum amine complexes are known including compounds having the formula 2 of the formula sheet.
Wadley Medical Bulletin, Vol. 7, No. 1, pp. 114-1 34, discloses a large number of platinum diamine complexes, including cis-platinum diamine dichloride, for the treatment of cancer. Here, too, the kidney toxicity is stated as the most important drawback of these compounds.
Chem. and Eng. News, 6th June 1977, pp. 29-30, also describes cis-platinum diamine chloride and its application for the treatment of cancer. Kidney toxicity is also mentioned as the most important drawback of these compounds.
In an article in Cancer Chemotherapy Reports Part 1,viol. 59, No. 3, May/June 1975, pp. 629641 , the kidney toxicity of cis-platinum-ll-diamine dichloride is also reported. Because of the toxicity of PDD to the kidney and its low therapeutic index, other platinum complexes for the treatment of cancer have been sought. For this purpose combinations of cis-platinum diamine-ll-dichloride with other chemotherapeutic agents were tested; novel platinum complexes were also tried, but they were found to be toxic. It was found, for instance, that although cis-dichloro-biscyclopentyl amine platinum (II) is only slightly toxic to the kidneys, it is toxic to the spleen. So-called "platinum blues", a mixture of different amounts of five or more inseparable components have also been disclosed for the treatment of cancer.
Dutch Patent Applications 73,04880; 73,04881; 73,04882 and 77,03752 disclose a large number of platinum diamine complexes, including the compound having formula 2 of the formula sheet. In all of these compounds with a nucleus, nitrogen atoms are linked directly to the nucleus. The compounds of the first three Dutch applications were compared with cis-platinum diamine dichloride and were found to have better effects. None of the patent applications states anything about kidney toxicity.
In Dutch Patent Application 79,04740 platinum diamine complexes are described, which are characterized by the formula 1 of the formula sheet, wherein R1 and R2 are independently of each other a hydrogen atom or a substituted or unsubstituted alkyl, cycloalkyl, aryl or aralkyl group, while R, and R2 may be together a substituted or unsubstituted cycloalkyl group, R3 and R4 independently of each other are a hydrogen atom or a substituted or unsubstituted alkyl, aryl or aralkyl group, and X is an anionic group.
Now novel platinum diamine complexes have been found, which are characterized by the formula 1 of the formula sheet, wherein R1 and R2 are both an ethyl group or together with the carbon atom, to which they are bonded, a cyclohexyl group, R3 and R4 are both a hydrogen atom and X is a malonate group, an ethyl malonate group, a hydroxy malonate group, a carboxy phthalate group, a bis-chloro acetate group, a cyclobutane-1,1-dicarboxylate group, a dinitrate group or an oxalate group, or a sodium salt of one of these groups.
The invention further relates to a process for the preparation in a way known per se of these compounds, to a process for the preparation of a medical composition, wherein these compounds are used as active substance, as well as to the so-obtained shaped medical composition.
An extensive research program carried out by the National Cancer Institute, Bethesda, U.S.A., and the European Organization for Research on the Treatment of Cancer, Brussels, Belgium, has shown that the compounds according to this invention display a high therapeutic activity against cancer in contradiction to the platinum complexes known up to now and used in practice for the combat of cancer, like the cis-platinum diamine dichloride (PDD), therein it also appeared that the compounds according to the invention show little or none kidney toxicity.
As it appears from the therapeutical activity values, mentioned in table A, the novel compounds show an important anti-tumor activity against a large number of different types of tumors, such as P388 lymphocytic leukemia (PS), L-1210 lymphoid leukemia (LE), ependymoblastoma and B 16 melanocarcinoma (Bl). The therapeutical activity of the relative novel compounds is higher than that of the cis-platinum diamine dichloride (PDD) which is used as experimental clinical chemotherapeuticum.
A very serious drawback of the PDD used in practice, as well of all other platinum-ll-complexes with anti-cancer activity and known up to now (with the exception of those, which are described in the Dutch Patent Application 79,04740) is as already mentioned the high toxicity of these compounds, of which the kidney toxicity is the most dangerous and in fact limiting for the dose, which can be used in practice.
Surprisingly the compounds according to the invention do not show detrimental side effects on the kidneys. This was demonstrated by means of histological research of rats after treatment of toxic doses of the compounds described herein below, while in a similar research with PDD serious kidney damages were found.
The new complexes also have no prejudicial influence on the activity of the kidneys. A generally recognized, significant method for the determination of kidney toxicity relates to the evaluation of the percentage urea nitrogen in the blood (blood urea nitrogen, BUN), also indicated as non-protein nitrogen (non protein nitrogen, NPN).
It further appears that the compounds according to the invention have no single influence on the urea-nitrogen contents in the blood. As well for doses corresponding with the LD10 amount as with the LDso amount the urea-nitrogen contents in the blood are identical to the control values. The compound PDD, on the contrary, gives at a LD,o dose after the indicated times already a four times increase of the urea-nitrogen contents, while this at a LD50 dose is increased with a factor of not less than 11.
Table A Anti-cancerous activity in mice a dose/injection Compound mouse codeb tumor mg/kg T/C {%) formula 4 06 LE 36,00 246 LE/cis-PDD 24,00 > 500 (3/6) formula 5 BDFr LE 40,00 200 formula 6 BDF, LE 6,00 207 formula 7 BDF1 LE 128 229 (1/6) LE/cis-PDD 64 144 formula 8 BDF, LE 24 214 LE/cis-PDD 18 144 formula 9 BDF1 LE 128 > 643 (4/6) LE/cis-PDD 96 1 50 formula 10 BDF, LE 128 > 643 (3/6) LE/cis-PDD 96 1 88 formula 11 BDF, LE 8 229 formula 12 BDF, LE 80 283 LE/cis-PDD 80 231 formula 13 BDF, LE 30 217 LE/cis-PDD 1 5 1 88 formula 14 BDF, LE 6 200 LE/cis-PDD 6 163 formula 15 BDF, LE/cis-PDD 16 230 a:More detailed information concerning the testing procedure and interpretation, vide Instruction 14, Screening data summary interpretation and outline of current screen, Maryland, 20014, 1977.
b: 02=mouse code B6D2F, (BDF); 03=mouse code C 57 BL/6; 06=mouse code CD2F, (CDF,).
c: PS=P 388 lymphocytic leukemia; LE=L 1210 Lymphoid leukemia; EM=ependymoblastoma; B,=Bf6 melano-carcinoma.
d: Period of survival is the ratio of survival times of the treated mice (T) to untreated mice (C); the therapeutic activity is significant at T/Cz125.
LE/cis-PDD means resistant to cis-PDD.
The preparation of the above mentioned compounds is illustrated in the following examples.
The compounds were prepared according to the method of S. C. Dhara: Indian J. Chem. 8,193 (1970).
Example I Cis-dichloro-1 1 -di(aminomethyl) cyclohexane platinum(ll) having the formula 3 of the formula sheet.
To a solution of 16 g K2PtCl4 in 160 ml of water a solution of 26.4 g Kl in 20 ml of water were added and the mixture was heated for 5 min. in a water bath.
Hereupon 6.4 g 1,1 -di(aminomethyl) cyclohexane were added and after the mixture had been stirred for 5 minutes, the precipitate was sucked and washed three times with hot water, twice with cold ethyl alcohol and twice with ether.
11.8 g of this formed diiodo derivative were added to a solution of 6.6 g AgNO3 in 48 ml water.
After the mixture had been stirred for 10 minutes at 95--1000C, the Agl was filtered off and washed with water. To the clear filtrate 3.28 g KCI were added and the mixture was stirred for 1 2 min.
at 95-1 000C. After the mixture had been cooled, the precipitate was sucked and washed with water.
Yield: 6.0 g.
Analysis (percentage by weight): Calculated: C: 23.53; H: 4.45; N: 6.87; Pt: 47.80.
Found: 23.32; 4.46; 6.86; 47.63.
Example II Preparation of cis-1 1 -di(aminomethyl)-cyclohexane hydroxymalonate platinum(ll) having the formula 4.
1.6 g of the dichloro derivative, prepared according to example I (formula 3) were added to a solution of 1.28 g AgNO3 in 25 ml of water.
After stirring the mixture during 1 hour at 400C the AgCI was filtered off and washed with water.
To the clear filtrate a solution of 0.456 g hydroxymalonic acid and 0.455 g KOH in 10 ml of water was added.
After stirring during 2 hours at room temperature the precipitate was filtered off and dried.
Yield: 77 weight %.
Analysis (weight %): Calculated: C: 29.01; H: 4.43; N: 6.15; Pt: 42.84; 0: 17.58.
Found: 28.77; 4.38; 6.18; 42.96; 17.54.
Melting point=2480 C (decomposition).
Example Ill Cis-4-carboxyphthalato-1 1 -di(aminomethyl)-cyclohexane-platinum(ll) having the formula 5.
1.2 g of the dichloro derivative prepared according to example I (formula 3), were added to a solution of 1 g AgNO3 in 25 ml of water.
After stirring the mixture during 1 hour at 400C the AgCI was filtered off and washed with water.
To the clear filtrate 0.63 g 1 ,2,4-tricarboxybenzene was added and the mixture was stirred during 2 hours at room temperature. The precipitate was sucked off and washed with water.
Yield: 0.8 g (45 weight %) Analysis (weight %): Calculated: C: 36.24; H: 4.29; N: 4.97; Found: 36.42; 4.13; 4.77.
Example IV Cis-1 1 di(aminomethyI)cyclohexane-bis(chlornacetate)-platinum(ll) having the formula 6.
1.6 g of the dichloro derivative prepared according to example I (formula 3), were added to a solution of 1.28 g AgNO3 in 25 ml of water.
After stirring the mixture during 1 hour at 4O0C the AgCI was filtered off and washed with water.
To the clear filtrate a solution of 0.73 g monochloro acetic acid and 0.45 g KOH in 25 ml water was added and the mixture was stirred during 2 hours at room temperature. The precipitate was sucked off and washed with water.
Yield: 1.3 g (65 weight %).
Analysis (weight %): Calculated: C: 27.49; H: 4.23; H: 5.34; Found: 27.43; 4.21; 5.55.
Example V Cis-1 1 di(aminomethyl)-cyclohexane-malonate-platinum(ll) having the formula 1 5.
This compound has already been mentioned in the Dutch Patent Application 79,04740, but its preparation is important for the following examples.
1.6 g of the dichloro derivative prepared according to example I (formula 3) were added to a solution of 1.28 g AgNO3 in 25 ml water.
After stirring the mixture during 1 hour at 400C the AgCI was filtered off and washed with water.
To the clear filtrate a solution of 0.4 g malonic acid and 0.455 g KOH in 10 ml water was added.
After stirring during 2 hours at room temperature the precipitate was filtered off and dried.
Yield: 1.0 g (59 weight %).
Analysis (weight %): Calculated: C: 30.07; H: 4.59; H: 6.38; Pt: 44.40; 0: 14.57; Found: 29.98; 4.54; 6.32; 44.32; 14.57.
Example VI Cis-2,2-diethyl-1,3-diaminopropane-2-ethylmalonate-platinum(ll), having the formula 7, was prepared according to the method of example V.
Yield: 65 weight %.
Analysis (weight %): Calculated+2 H2O: C: 29.33; H: 5.74; N: 5.70; Found: 29.23; 5.64; 5.71.
Example VII Cis-2,2-diethyl-i ,3-diaminopropane-2-hydroxymalonate-platinum(ll), having the formula 8 was prepared according to the method of example V.
Yield: 87 weight %.
Analysis (weight %): Calculated+1/2 H2O: C: 26.55; H: 4.68; N: 6.19; Found: 26.67; 4.56; 6.23.
The sodium salt of this compound having the formula 13 was prepared according to example IX.
Example VIII Cis-l 1 -di(aminomethyl)cyclohexane-2-ethyl-malonate-platinum(Il) having the formula 10 was prepared according to the method of example V.
Yield: 64 weight %.
Analysis (weight /0): Calculated+1.5 H20: C: 31.57; H: 5.50; N: 5.67; 0: 17.79; Pt: 39.43; Found: 31.36; 5.47; 5.69; 18.02; 39.58.
Example IX Cis-2,2-diethyl-1,3-diaminopropane-2-hydroxymalonate-platinum(ll)-sodium salt having the formula 13.
0.5 g of the hydroxymalonate derivative prepared according to example VII (formula 8) were suspended in 25 ml water.
1.105 ml 0.1 N NaOH were added and the mixtures was stirred during 30 min. at room temperature.
The clear solution was evaporated to dryness and the remaining solid was dried.
Yield: 0.4 g (72 weight %) Analysis (weight %): Calculated+2 H20: C: 23.91; H: 4.61; N: 5.58; Found: 23.75; 4.44; 5.52.
Example X Cis-i 1 -di(aminomethyl)cyclohexane-l 1 -cyclobutanedicarboxylate-platinum(ll) having the formula 12.
2 g of the dichloro compound, prepared according to example I (formula 3) were added to a solution of 1.6 g AgNO3 in 25 ml water.
After stirring the mixture during 1 hour at 400C the AgCI was filtered off and washed with water.
To the clear filtrate a solution of 0.677 g 1.1-cyclobutane dicarboxylic acid and 0.547 g KOH in 10 ml water was added.
After 2 hours at room temperature and 1 hour at OOC the white precipitate was filtered off and dried.
Yield: 1.4 g (62 weight %).
Analysis (weight %): Calculated+H2O: C: 33.80; H: 5.27; N: 5.63; Found: 33.98; 5.02 5.77.
Example XI Cis-2,2-diethyl-i ,3-diaminopropane-l 1 -cyclobutane dicarboxylate platinum(ll), having the formula 9, was prepared according to the method of example X.
Yield: 64 weight %.
Analysis (weight %): Calculated+2.5 H2O: C: 30.46; H: 5.70; N: 5.47; Pt: 38.07; Found: 30.40; 5.44; 5.37; 38.16.
Example XII Cis-i 1 -bis(aminomethyl)cyclohexane platinum(ll)nitrate, having the formula 11.
4 g cis-dichloro-1 ,1-bis(aminomethyl)cyclohexane platinum(ll) (0.0097 mole) were suspended in 30 ml distilled water.
To this 3.1 g AgNO3 (0.0182 mole) were added and subsequently the mixture was heated during 1 hour at 400C while light was excluded.
The formed silverchloride was filtered off and washed with distilled water (10 ml).
The clear filtrate was evaporated under reduced pressure.
Weight solid substance: 4.1 7 g (93.5 weight %).
Melting point: explodes at about 2400 C; decomposes slowly at temperatures below 2400 C.
Analysis (weight %): Calculated: C: 20.83; H: 3.93; N: 12.14; Found: 20.9 ; 4.1 ; 11.9 'H-NMR-spectrum in DMSO-d6 (Varian T60) with respect to TMS: CH2 (ring): 1.37 ppm CH2 (NH2): 2.30 ppm NH2: 5.67 ppm satellites: 5.20 ppm 6.18 ppm J1ssPt 1H 58 Hz Example XIII Cis-i 1 -bis(aminomethyl)cyclohexane platinum(ll)oxalate having the formula 14.
4.1 g Cis-dichloro-l,l -bis(aminomethyl)cyclohexane platinum(ll) (0.01 mole) were suspended in 30 ml distilled water.
To this 3.2 g AgNO3 (0.019 mole) was added and subsequently the mixture was heated during 1 hour at 400C while light was excluded.
The formed silver chloride was filtered off and washed with distilled water (50 ml).
To the filtrate 2.02 g potassium oxalate (0.01 mole) were added, whereafter the mixture was stirred during 1 hour at room temperature.
Subsequently the formed solid was sucked off, washed with distilled water and dried.
Weight dry: 3.7 g (87 weight %) Analysis (weight %): Calculated+1.5 H2O: C: 26.55; H: 4.68; N: 6.19; Pt: 43.13; 0: 19.45; Found: 26.6 ; 4.6 ; 6.2 ; 43.4 ; 19.2 H-NMR-spectrum in DMSO-d6 (Varian T60) with respect to TMS: CH2 (ring): 1.32 ppm CH2(NH2): 2.17ppm NH2: 5.45 ppm satellites: 4.83 ppm 6.08 ppm 19sPt-1H: 76 Hz

Claims (38)

Claims
1. Platinum-(ll)-diamine complexes, characterized by the formula 1 of the formula sheet, wherein R1 and R2 are both ethyl or together with the carbon atom, to which they are bonded, a cyclohexyl group, R3 and R4 are both a hydrogen atom and X is a malonate group, an ethylmalonate group, a hydroxymalonate group, a carboxyphthalate group, a bischloro acetate group, a cyclobutane-1,1-dicarboxylate group, a dinitrate group or an oxalate group or a sodium salt of these groups.
2. Platinum diamine complex according to claim 1, characterized by the formula 4 of the formula sheet.
3. Platinum diamine complex according to claim 1, characterized by the formula 5 of the formula sheet.
4. Platinum diamine complex according to claim 1, characterized by the formula 6 bf the formula sheet.
5. Platinum diamine complex according to claim 1, characterized by the formula 7 of the formula sheet.
6. Platinum diamine complex according to claim 1, characterized by the formula 8 of the formula sheet.
7. Platinum diamine complex according to claim 1, characterized by the formula 9 of the formula sheet.
8. Platinum diamine complex according to claim 1, characterized by the formula 10 of the formula sheet.
9. Platinum diamine complex according to claim 1, characterized by the formula 11 of the formula sheet.
10. Platinum diamine complex according to claim 1, characterized by the formula 12 of the formula sheet.
11. Platinum diamine complex according to claim 1, characterized by the formula 13 of the formula sheet.
1 2. Platinum diamine complex according to claim 1, characterized by the formula 14 of the formula sheet.
1 3. A process for the preparation of a medical composition for the treatment of cancer while
14. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 4 is used.
1 5. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 5 is used.
1 6. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the using a platinum-(ll)-diarnine complex, characterized in that as platinum-(ll)-diamine complex a compound having the formula 1, wherein R1, R2, R3, R4and X have the meaning mentioned in claim 1, is used.
compound having the formula 6 is used.
17. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 7 is used.
1 8. The process according to claim 1 3, characterized in that as platinum-(ll)-diamine complex the compound having the formula 8 is used.
1 9. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 9 is used.
20. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 10 is used.
21. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 11 is used.
22. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 12 is used.
23. The process according to claim 13, characterized in that as platinum-(ll)-diamine complex the compound having the formula 13 is used.
24. The process according to claim 13, characterized in that as platinum-(ll!-diamine complex the compound having the formula 14 is used.
25. A process for the preparation of platinum-(ll)-diamine complexes to be used in the process according to claims 14-24, characterized in that a platinum-(ll)-diamine complex having the formula 1, wherein R,, R2, R3, R4 and X have the meaning mentioned in claim 1, is prepared in a way known per se.
26. The process according to claim 25, characterized in that a compound having the formula 4 of the formula sheet is prepared.
27. The process according to claim 25, characterized in that a compound having the formula 5 of the formula sheet is prepared.
28. The process according to claim 25, characterized in that a compound having the formula 6 of the formula sheet is prepared.
29. The process according to claim 25, characterized in that a compound having the formula 7 of the formula sheet is prepared.
30. The process according to claim 25, characterized in that a compound having the formula 8 of the formula sheet is prepared.
31. The process according to claim 25, characterized in that a compound having the formula 9 of the formula sheet is prepared.
32. The process according to claim 25, characterized in that a compound having the formula 10 of the formula sheet is prepared.
33. The process according to claim 25, characterized in that a compound having the formula 11 of the formula sheet is prepared.
34. The process according to claim 25, characterized in that a compound having the formula 12 of the formula sheet is prepared.
35. The process according to claim 25, characterized in that a compound having the formula 13 of the formula sheet is prepared.
36. The process according to claim 25, characterized in that a compound having the formula 14 of the formula sheet is prepared.
37. A pharmaceutical composition for the treatment of cancer which comprises a platinum (II) diamine complex as claimed in any one of Claims 1 to 13, together with a pharmaceutically acceptable diluent or carrier.
38. A process as claimed in Claim 25 substantially as hereinbefore described with reference to any one of the Examples.
GB08328084A 1982-10-21 1983-10-20 Platinum 1,3-propane diamine complexes Expired GB2128615B (en)

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NL8204067A NL8204067A (en) 1982-10-21 1982-10-21 PLATINUM DIAMINE COMPLEXES, METHOD FOR PREPARING THE SAME, METHOD FOR PREPARING A MEDICINAL PRODUCT USING SUCH PLATINADIAMINE COMPLEX FOR THE TREATMENT OF CANCER, PREVENTLY PREVENTED.

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GB2128615A true GB2128615A (en) 1984-05-02
GB2128615B GB2128615B (en) 1986-07-16

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0176005A1 (en) * 1984-09-12 1986-04-02 Chugai Seiyaku Kabushiki Kaisha Novel platinum complexes
US4661516A (en) * 1983-06-20 1987-04-28 Research Corporation Diaminocyclohexane platinum complexes
EP0174542A3 (en) * 1984-09-03 1987-05-06 Behringwerke Aktiengesellschaft Cis-platinum-complexes having a pentaerythritol derivative as ligand, process for their preparation and pharmaceutical agent containing these compounds
US4758588A (en) * 1983-06-20 1988-07-19 Research Corporation Technologies Diaminocyclohexane platinum complexes
US4760157A (en) * 1986-01-31 1988-07-26 American Cyanamid Company (2,2,-bis(aminomethyl)-1,3-propanediol-N,N')platinum complexes
US4786725A (en) * 1982-06-28 1988-11-22 Engelhard Corporation Solubilized platinum (II) complexes
US4880790A (en) * 1986-01-31 1989-11-14 American Cyanamid Company (Gem-heterocyclodimethanamine-N,N')platinum complexes
EP0357109A3 (en) * 1988-08-31 1990-12-19 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Platinum-(ii)-diamine complex, method for the preparation of this compound, preparation with an anti-tumour action which contains this compound and also shaped preparations with an anti-tumour action
US4987246A (en) * 1987-02-19 1991-01-22 Nippon Kayaku Kabushiki Kaisha Novel platinum complexes
US4992553A (en) * 1986-10-03 1991-02-12 Asta Pharma Aktiengesellschaft Diamine-platinum (II) complex compounds
US5028727A (en) * 1988-08-31 1991-07-02 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Platinum-(IV)-diamine complex
US5068376A (en) * 1985-08-27 1991-11-26 Nippon Kayaku Kabushiki Kaisha Novel platinum complexes
US5091521A (en) * 1986-09-08 1992-02-25 Behringwerke Aktiengesellschaft Cis-platinum complexes, a process for the preparation thereof, and pharmaceuticals containing these compounds

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EP0169645A1 (en) * 1984-06-27 1986-01-29 Johnson Matthey Public Limited Company Platinum co-ordination compounds
AT390065B (en) * 1987-10-08 1990-03-12 Behringwerke Ag cis-Platinum complexes, process for their preparation and pharmaceutical compositions containing these compounds
CN102924528B (en) * 2012-10-29 2015-04-15 东南大学 Anti-tumor bivalent platinum complex and preparation method for complex and ligand of complex

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GB2003468A (en) * 1977-08-29 1979-03-14 Us Commerce 4-carboxyphthalato(1,2-diaminocyclohexane)platinum(ii)and alkali metal salts thereof and its use in alleviating murine leukemia
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EP0041644A2 (en) * 1980-05-27 1981-12-16 Bristol-Myers Company Salts of 2-hydroxymalonato diammine platinum (II) compounds, process for preparing said compounds and pharmaceutical compositions containing said compounds

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4786725A (en) * 1982-06-28 1988-11-22 Engelhard Corporation Solubilized platinum (II) complexes
US4661516A (en) * 1983-06-20 1987-04-28 Research Corporation Diaminocyclohexane platinum complexes
US4758588A (en) * 1983-06-20 1988-07-19 Research Corporation Technologies Diaminocyclohexane platinum complexes
EP0174542A3 (en) * 1984-09-03 1987-05-06 Behringwerke Aktiengesellschaft Cis-platinum-complexes having a pentaerythritol derivative as ligand, process for their preparation and pharmaceutical agent containing these compounds
US4730069A (en) * 1984-09-03 1988-03-08 Behringwerke Aktiengesellschaft Cis-platinum complexes with a pentaerythritol derivative as the ligand, a process for their preparation and a pharmaceutical agent containing these compounds
EP0176005A1 (en) * 1984-09-12 1986-04-02 Chugai Seiyaku Kabushiki Kaisha Novel platinum complexes
US4822892A (en) * 1984-09-12 1989-04-18 Chugai Seiyaku Kabushiki Kaisha N-heterocyclic platinum complexes
US5068376A (en) * 1985-08-27 1991-11-26 Nippon Kayaku Kabushiki Kaisha Novel platinum complexes
US4880790A (en) * 1986-01-31 1989-11-14 American Cyanamid Company (Gem-heterocyclodimethanamine-N,N')platinum complexes
US4900756A (en) * 1986-01-31 1990-02-13 American Cyanamid Company (2,2-bis(aminomethyl)-1,3-propranediol-N,N')platinum complexes
US4760157A (en) * 1986-01-31 1988-07-26 American Cyanamid Company (2,2,-bis(aminomethyl)-1,3-propanediol-N,N')platinum complexes
US5091521A (en) * 1986-09-08 1992-02-25 Behringwerke Aktiengesellschaft Cis-platinum complexes, a process for the preparation thereof, and pharmaceuticals containing these compounds
US4992553A (en) * 1986-10-03 1991-02-12 Asta Pharma Aktiengesellschaft Diamine-platinum (II) complex compounds
US5130308A (en) * 1986-10-03 1992-07-14 Asta Pharma Method of treating hormone dependent tumors with diamine-platinum (ii) complex compounds
US4987246A (en) * 1987-02-19 1991-01-22 Nippon Kayaku Kabushiki Kaisha Novel platinum complexes
US5128493A (en) * 1987-02-19 1992-07-07 Nippon Kayaku Kabushiki Kaisha Platinum complexes
EP0357109A3 (en) * 1988-08-31 1990-12-19 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Platinum-(ii)-diamine complex, method for the preparation of this compound, preparation with an anti-tumour action which contains this compound and also shaped preparations with an anti-tumour action
US5028727A (en) * 1988-08-31 1991-07-02 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno Platinum-(IV)-diamine complex
US5034553A (en) * 1988-08-31 1991-07-23 Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Platinum-(II)-diamine complex, method for the preparation of this compound, preparation with an anti-tumour action which contains this compound and also shaped preparations with an anti-tumour action

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KR840006492A (en) 1984-11-30
JPH0244479B2 (en) 1990-10-04
DK75592D0 (en) 1992-06-09
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FI76351C (en) 1988-10-10
CS242888B2 (en) 1986-05-15
SE8305783L (en) 1984-04-22
PH24077A (en) 1990-03-05
ES8406498A1 (en) 1984-07-01
NZ206018A (en) 1986-02-21
IT1169858B (en) 1987-06-03
AU2027583A (en) 1984-05-03
LU85054A1 (en) 1984-03-22
NO833825L (en) 1984-04-24
FR2534907A1 (en) 1984-04-27
IE832459L (en) 1984-04-21
GB2128615B (en) 1986-07-16
YU43554B (en) 1989-08-31
IE56124B1 (en) 1991-04-24
PT77542A (en) 1983-11-01
JPS5993091A (en) 1984-05-29
PT77542B (en) 1986-02-12
SE8305783D0 (en) 1983-10-20
AU562964B2 (en) 1987-06-25
YU210783A (en) 1986-08-31
DK483083A (en) 1984-04-22
ZA837857B (en) 1984-06-27
DK483083D0 (en) 1983-10-20
FI833842L (en) 1984-04-22
FR2534907B1 (en) 1988-08-19
ES526670A0 (en) 1984-07-01
NL8204067A (en) 1984-05-16
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AT390610B (en) 1990-06-11
KR910002536B1 (en) 1991-04-23
NO171276C (en) 1993-02-17
CA1229618A (en) 1987-11-24
HU188035B (en) 1986-03-28
FI76351B (en) 1988-06-30
CH658244A5 (en) 1986-10-31
NO171276B (en) 1992-11-09
DD217522A5 (en) 1985-01-16
CS775283A2 (en) 1985-08-15
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IT8323359A0 (en) 1983-10-19
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GB8328084D0 (en) 1983-11-23

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