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GB2122413A - Elliptical column type non- aqueous electrolyte battery - Google Patents

Elliptical column type non- aqueous electrolyte battery Download PDF

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Publication number
GB2122413A
GB2122413A GB08315803A GB8315803A GB2122413A GB 2122413 A GB2122413 A GB 2122413A GB 08315803 A GB08315803 A GB 08315803A GB 8315803 A GB8315803 A GB 8315803A GB 2122413 A GB2122413 A GB 2122413A
Authority
GB
United Kingdom
Prior art keywords
column type
aqueous electrolyte
electrolyte battery
elliptical column
elliptical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08315803A
Other versions
GB2122413B (en
GB8315803D0 (en
Inventor
Hironosuka Ikeda
Shigehiro Nakaido
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Electric Co Ltd
Original Assignee
Sanyo Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Electric Co Ltd filed Critical Sanyo Electric Co Ltd
Publication of GB8315803D0 publication Critical patent/GB8315803D0/en
Publication of GB2122413A publication Critical patent/GB2122413A/en
Application granted granted Critical
Publication of GB2122413B publication Critical patent/GB2122413B/en
Expired legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/70Carriers or collectors characterised by shape or form
    • H01M4/78Shapes other than plane or cylindrical, e.g. helical
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • H01M6/06Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/10Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with wound or folded electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00Primary cells; Manufacture thereof
    • H01M6/04Cells with aqueous electrolyte
    • H01M6/06Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H01M6/10Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid with wound or folded electrodes
    • H01M2006/106Elliptic wound cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

The present invention provides an elliptical column type, non-aqueous electrolyte battery, comprising an elliptical column type spiral electrode assembly formed by winding positive (14) and negative (12) electrode plates through a separator (13) and a resilient member (11) positioned at the centre of the electrode assembly and normally expanding the electrode assembly from the centre in outward directions of larger and smaller radius portions. The positive electrode plates may comprise manganese dioxide, carbon fluoride or silver chromate and the negative electrode plate may comprise lithium or sodium. <IMAGE>

Description

SPECIFICATION Elliptical column type non-aqueous electrolyte battery The present invention is concerned with an elliptical column type, non-aqueous electrolyte battery provided with an elliptical column type spiral electrode assembly.
Recently, with rapid technical progress in various kinds of electronic equipment and appliances, batteries have been employed as their power sources. Among these equipment and appliances, comparatively high current has been especially required in the fields of, for example, radio receivers, tape recorders and cameras. In spite of small appliances, for example, two or four cylindrical type alkaline manganese batteries (battery voltage: 1.5 V) have been used as a 3 V- or 6 V-battery by connecting them in series with one another.
As shown by way of example in Fig. 5 of the accompanying drawings, two alkaline manganese batteries (20) are arranged in parallel so that positive and negative terminals (21) and (22) are positioned at one end surface and are placed in a space for batteries in an appliance (30), which includes positive and negative contact strips (31) and (32), respectively.
Recently, lithium non-aqueous electrolyte batteries, which include a negative-active material of lithium and a positive-active material of, for example, manganese dioxide, carbon fluoride or silver chromate, have been used in practice. Such batteries have attracted attention because the battery voltage is 3 V, which is about twice as high as that of the usual alkaline manganese batteries or manganese dry batteries and because such batteries have a high energy density.
We have found the described features of the non-aqueous electrolyte battery and have disclosed the non-aqueous electrolyte battery in our copending Japanese Patent Application No. 49665/1981, which is used instead of arranging two cylindrical type alkaline manganese batteries or manganese dry batteries in parallel. The battery is one which includes an elliptically cylindrical casing which accommodates an elliptical column type spiral electrode assembly formed by winding positive and negative electrode plates through a separator.
The elliptical column type serial electrode assembly is especially provided by winding the electrode group around a plate-shaped core.
The present invention further improves the elliptical column type, non-aqueous battery described above and the object of the present invention is to improve the battery characteristics by lowering the internal resistance.
Thus, according to the present invention, there is provided an elliptical column type, non-aqueous electrolyte battery, comprising an elliptical column type spiral electrode assembly formed by winding positive and negative electrode plates through a separator and a resilient member positioned in the centre of the electrode assembly and normally expanding the electrode assembly from the centre in outward directions of larger and smaller radius portions.
According to the present invention, one battery is not used instead of obtaining high current by employing two cylindrical batteries arranged in parallel as shown in known manner but also the adhesion of the positive electrode plate to the negative electrode plate through the separator is increased by the resilient member located at the centre of the electrode assembly. As a result, the internal resistance is reduced to improve the battery characteristics.
For a better understanding of the present invention, reference is made to the accompanying drawings, in which: Figure 1 is a vertical sectional view of a battery according to one embodiment of the present invention; Figure 2 is a cross-sectional view of the battery taken along the line A-A' in Fig. 1; Figure 3 is a perspective view of the resilient member (11) in Figs. 1 and 2; Figure 4 is a perspective view of another resilient member (11'); and Figure 5 is a view showing two cylindrical type conventional batteries arranged in parallel and located in a space for batteries in an electronic appliance.
The electrode assembly used for the nonaqueous electrolyte battery according to the present invention includes an elliptical column type electrode assembly which is provided by spirally winding belt-shaped negative and positive electrode plates through a belt-shaped separator. The larger radius portion is about twice as large in size as the smaller radius portion.
The resilient member used for the nonaqueous electrolyte battery according to the present invention is made of, for example, a conductive metal plate, such as stainless steel, and is positioned at the centre of the elliptical column type electrode assembly to expand it from the centre in directions of larger and smaller radius portions. The structure of the elliptical resilient member is as follows: 1 ) a gap continuous from one open end to the other is provided in the side walls, as shown in Fig. 3 and 2) one end, cut from one open end to the other, is bent so as to give a Ushaped recessed portion, the other end being engaged with the U-shaped recessed portion, as shown in Fig. 4.
The present invention will now be described, by way of example, with reference to the illustrated embodiments.
In Figs. 1 and 2, (1) is a stainless steel casing, which is elliptical in cross-section, an insulating sheet (2) being provided at the bottom. In this case, the elliptical type cylindrical casing is designed in such a manner that the larger radius portion is about twice as large as the smaller radius portion and corresponds approximately to the size obtained when arranging two conventional 1.5 V-cylindrical-type batteries in parallel. (3) is a stainless steel cover plate for enclosing the open portion of the casing (1), the periphery of which is fixed to the open end of the casing by using, for example, laser welding. (4) is a T-shaped terminal pin, a part of which is inserted through an insulator (5) into a perforation provided in the cover plate (3), the end of which is crimped and secured to a metal ring (6).A negative external terminal plate (7) is secured to the upper surface of a metal ring (6). (8) is an insulating ring for preventing electrical connection between the negative external terminal plate (7) and the cover plate (3). (9) is a positive external terminal cap attached to the cover plate (3) opposite the negative external terminal plate (7). (10) is the elliptical column type spiral electrode assembly which is constituted by spot welding a negative collector net (12'), exposed from one end of a lithium negative electrode plate (12), to an elliptical type conductive resilient member (11) of cylindrical form used as a winding core, superposing a positive electrode plate (14) of manganese dioxide on the negative electrode plate (12) through a separator (13) and winding them around the resilient member.For carrying out the winding, a shaft of a take-up jig is inserted into the centre of the resilient member (11). In this case, the positive electrode plate (14) is positioned at the outermost side of the electrode assembly and the positive collector net (14'), exposed from the positive electrode plate (14), is contacted to the inner surface of the casing (1) so as to be electrically connected. (15) is an insulating sheet arranged on the upper surface of the electrode assembly (10).
In this embodiment, the resilient member (11) located in the central space of the spiral electrode assembly (10) is used as both the winding core in producing the electrode assembly and as the negative collector. One end of a negative lead plate (16), which is secured to the resilient member (11) by spot welding, is fixed to the lower end of the negative terminal pin (4) and is electrically connected thereto. Fig. 4 shows another embodiment of the resilient member (11').
According to the non-aqueous electrolyte battery of the present invention, since the battery is provided with the elliptical column type spiral electrode assembly and the appearance of the shape is of the elliptical column type, the following advantages will be obtained when the battery is used instead of the power supply batteries of electronic equipment and appliances which employ two conventional cylindrical batteries with a battery voltage of 1.5 V arranged in parallel and connected in series with each other as described initially: a) Since the appearance of the shape is of the elliptical column type, the battery is similar in shape to that of two cylindrical type batteries arranged in parallel and it is thus possible to employ the battery in existing electronic equipment and appliances.In addition, because the battery has a structure such that the electrode assembly can be placed in the space required for two cylindrical type batteries arranged in parallel, the volume efficiency is improved.
b) Although previously care had to be taken that two cylindrical type batteries were arranged in given directions, insertion is simplified in the case of the non-aqueous electrolyte battery of the present invention because it can be used instead of two cylindrical type batteries.
Furthermore, the resilient member is positioned in the central space of the elliptical column type spiral electrode assembly and the electrode assembly (10) is usually expanded outwardly from the centre due to the force of restitution of the resilient member (11), as shown in Fig. 2. Consequently, a good adhesion of the positive electrode plate to the negative electrode plate is obtained and the internal resistance is reduced, thereby improving the battery characteristics.

Claims (10)

1. An elliptical column type, non-aqueous electrolyte battery, comprising an elliptical column type spiral electrode assembly formed by winding positive and negative electrode plates through a separator and a resilient member positioned at the centre of the electrode assembly and normally expanding the electrode assembly from the centre in outward directions of larger and smaller radius portions.
2. An elliptical column type non-aqueous electrolyte battery according to claim 1, wherein the resilient member is used as a collector with one polarity.
3. An elliptical column type non-aqueous electrolyte battery according to claim 1 or 2, wherein the resilient member has an elliptical cylindrical form and is used as a winding core for producing the spiral electrode assembly.
4. An elliptical column type non-aqueous electrolyte battery according to any of the preceding claims, wherein the negative electrode plate is provided with an active material which is a light metal.
5. An elliptical column type non-aqueous electrolyte battery according to claim 4, wherein the light metal is lithium or sodium.
6. An elliptical column type non-aqueous electrolyte battery according to any of the preceding claims, wherein the positive electrode plate comprises manganese dioxide, carbon fluoride or silver chromate.
7. An elliptical column type non-aqueous electrolyte battery according to any of the preceding claims, wherein the ratio of the larger radius portion to the smaller radius portion of the elliptical type cylindrical battery is about 2:1.
8. An elliptical column type non-aqueous electrolyte battery according to any of the preceding claims, wherein the resilient member has an elliptical cylindrical form and includes a gap which is continuous from one open end to the other in the side wall thereof.
9. An elliptical column type non-aqueous electrolyte battery according to any of claims 1 to 7, wherein the resilient member has an elliptical cylindrical form, one end of the resilient member, cut from one open end to the other, being bent so as to give a U-shaped recessed portion, the other end being engaged with the U-shaped recessed portion.
10. An elliptical column type non-aqueous electrolyte battery according to claim 1, substantially as hereinbefore described and exemplified and with reference to any of Figs. 1 to 4.
GB08315803A 1982-06-11 1983-06-09 Elliptical column type non-aqueous electrolyta battery Expired GB2122413B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57101247A JPS58218768A (en) 1982-06-11 1982-06-11 Battery

Publications (3)

Publication Number Publication Date
GB8315803D0 GB8315803D0 (en) 1983-07-13
GB2122413A true GB2122413A (en) 1984-01-11
GB2122413B GB2122413B (en) 1986-07-16

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
GB08315803A Expired GB2122413B (en) 1982-06-11 1983-06-09 Elliptical column type non-aqueous electrolyta battery

Country Status (6)

Country Link
JP (1) JPS58218768A (en)
CA (1) CA1196376A (en)
CH (1) CH662008A5 (en)
DE (1) DE3321129A1 (en)
FR (1) FR2528631B1 (en)
GB (1) GB2122413B (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4663247A (en) * 1985-11-04 1987-05-05 Union Carbide Corporation Coiled electrode assembly cell construction with pressure contact member
US5175066A (en) * 1988-12-26 1992-12-29 Centre National De La Recherche Scientifique (Cnrs) Rechargeable battery with solid electrolyte
EP0756345A3 (en) * 1995-07-28 1997-04-16 Daewoo Electronics Co Ltd Lithium battery and method for manufacturing an electrode of the lithium battery
EP0991132A3 (en) * 1998-09-17 2000-05-17 Kabushiki Kaisha Toshiba Nonaqueous electrolyte secondary battery and method of manufacturing nonaqueous electrolyte secondary battery
WO2001022511A1 (en) * 1999-09-22 2001-03-29 The Gillette Company Electrochemical cell
US6506514B1 (en) * 1999-11-25 2003-01-14 Nec Mobile Energy Corporation Nonaqueous electrolyte secondary battery
EP1348237A4 (en) * 2000-11-21 2004-04-21 Mann Alfred E Found Scient Res Compliant mandrel for a battery electrode assembly
US10714713B2 (en) 2014-09-01 2020-07-14 Robert Bosch Gmbh Clamping device for battery cells as well as battery module, battery, battery system, vehicle and method for producing a battery module

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US4565752A (en) * 1984-12-24 1986-01-21 Gte Government Systems Corporation Electrochemical cell having wound electrode structures
FR2616970B1 (en) * 1987-06-18 1995-05-19 Elf Aquitaine MULTI-LAYERED ASSEMBLY FOR PRODUCING THE ASSEMBLY OF A GENERATOR, METHOD FOR PREPARING THE SAME AND PRODUCING THE COMPLETE GENERATOR, AND GENERATOR THUS PRODUCED
JPH01227363A (en) * 1988-03-07 1989-09-11 Hitachi Ltd Secondary battery and its electrode
DE3829419C1 (en) * 1988-08-31 1989-12-28 Accumulatorenwerke Hoppecke Carl Zoellner & Sohn Gmbh & Co Kg, 5790 Brilon, De
DE69432392T2 (en) * 1993-11-19 2004-03-04 Medtronic, Inc., Minneapolis High reliability electrochemical cell and electrode arrangement therefor
JP3489265B2 (en) * 1995-05-19 2004-01-19 ソニー株式会社 Semiconductor device manufacturing method
ES2202675T3 (en) * 1998-03-30 2004-04-01 Renata Ag ACCUMULATOR OR PRISMATIC BATTERY WITH WINDING WINDING.
ATE526694T1 (en) 2003-10-28 2011-10-15 Johnson Controls Tech Co BATTERY SYSTEM WITH IMPROVED HEAT DISSIPATION
DE102012018128A1 (en) 2012-09-13 2014-03-13 Daimler Ag Single cell e.g. lithium ion cell, for use in elliptic column-type non-aqueous electrolyte battery for electric car, has electrode film arrangement pressed against wall of cell housing by elastic element that is designed as hollow body

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GB1531225A (en) * 1974-10-31 1978-11-08 Chloride Group Ltd Lead acid cells and batteries
GB2042788A (en) * 1979-12-28 1980-09-24 Saft Leclanche A cylindrical electric cell

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FR2148741A5 (en) * 1971-08-02 1973-03-23 Gates Rubber Co Separator for electro-chemical cell - esp zinc nickel alkaline cell using esp three sandwiched layers
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DE2403222A1 (en) * 1974-01-24 1975-08-07 Walter Nimmerrichter Plates for light-weight accumulators - wound from plus and minus metal foils with two separator strips
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Publication number Priority date Publication date Assignee Title
GB1531225A (en) * 1974-10-31 1978-11-08 Chloride Group Ltd Lead acid cells and batteries
GB2042788A (en) * 1979-12-28 1980-09-24 Saft Leclanche A cylindrical electric cell

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4663247A (en) * 1985-11-04 1987-05-05 Union Carbide Corporation Coiled electrode assembly cell construction with pressure contact member
US5175066A (en) * 1988-12-26 1992-12-29 Centre National De La Recherche Scientifique (Cnrs) Rechargeable battery with solid electrolyte
EP0756345A3 (en) * 1995-07-28 1997-04-16 Daewoo Electronics Co Ltd Lithium battery and method for manufacturing an electrode of the lithium battery
US5720781A (en) * 1995-07-28 1998-02-24 Daewoo Electronics Co., Ltd. Method for manufacturing an electrode of the lithium battery
EP0991132A3 (en) * 1998-09-17 2000-05-17 Kabushiki Kaisha Toshiba Nonaqueous electrolyte secondary battery and method of manufacturing nonaqueous electrolyte secondary battery
EP1098378A1 (en) * 1998-09-17 2001-05-09 Kabushiki Kaisha Toshiba Nonaqueous electrolyte secondary battery
US6465125B1 (en) 1998-09-17 2002-10-15 Kabushiki Kaisha Toshiba Nonaqueous electrolyte secondary battery and method of manufacturing nonaqueous electrolyte secondary battery
WO2001022511A1 (en) * 1999-09-22 2001-03-29 The Gillette Company Electrochemical cell
US6506514B1 (en) * 1999-11-25 2003-01-14 Nec Mobile Energy Corporation Nonaqueous electrolyte secondary battery
EP1348237A4 (en) * 2000-11-21 2004-04-21 Mann Alfred E Found Scient Res Compliant mandrel for a battery electrode assembly
US10714713B2 (en) 2014-09-01 2020-07-14 Robert Bosch Gmbh Clamping device for battery cells as well as battery module, battery, battery system, vehicle and method for producing a battery module

Also Published As

Publication number Publication date
FR2528631A1 (en) 1983-12-16
GB2122413B (en) 1986-07-16
JPS58218768A (en) 1983-12-20
FR2528631B1 (en) 1987-02-06
CH662008A5 (en) 1987-08-31
DE3321129A1 (en) 1983-12-15
CA1196376A (en) 1985-11-05
GB8315803D0 (en) 1983-07-13

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PCNP Patent ceased through non-payment of renewal fee

Effective date: 20010609