GB2118188A - Powder coating compositions - Google Patents
Powder coating compositions Download PDFInfo
- Publication number
- GB2118188A GB2118188A GB08310032A GB8310032A GB2118188A GB 2118188 A GB2118188 A GB 2118188A GB 08310032 A GB08310032 A GB 08310032A GB 8310032 A GB8310032 A GB 8310032A GB 2118188 A GB2118188 A GB 2118188A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxy resin
- composition
- curable
- curing agent
- ground
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims abstract description 23
- 239000008199 coating composition Substances 0.000 title claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 41
- 239000003822 epoxy resin Substances 0.000 claims abstract description 26
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 11
- 230000000996 additive effect Effects 0.000 claims abstract description 11
- 239000004606 Fillers/Extenders Substances 0.000 claims abstract description 10
- 239000000049 pigment Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 18
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 16
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 claims description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 6
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 6
- 239000001095 magnesium carbonate Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 2
- 238000007590 electrostatic spraying Methods 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021652 non-ferrous alloy Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
A curable powder coating composition suitable for electrostatic spraying to produce a "structure" finish is prepared from a ground, extruded mixture of an epoxy resin, a curing agent therefor and optionally one or more of pigments and extenders and a ground blend of a silicone flow additive and a portion of epoxy resin mixed together.
Description
SPECIFICATION
Powder coating compositions
This invention concerns powder coating compositions such as are used to form "structure" finishes on for example, metal surfaces by spraying the composition onto the surface and curing the sprayed composition. The invention also concerns a method of producing such compositions.
A "structure" finish is usually defined as one having a base layer of material which when cured has formed therein valleys and pits providing the structure.
"Structure" compositions are known which are based on silicones. One problem with these compositions is that when sprayed onto surfaces some of the composition enters the atmosphere and can settle on other surfaces to be coated. The silicone can reduce adhesion of other coatings, such as paint, to surfaces causing formation of socalled "fish-eyes" and other blemishes. Thus spraying of silicone based compositions can contaminate factories and workshops.
Also, such silicone based coating compositions can require relatively high temperatures of the order of 2000C for curing. Lower curing temperatures are desirable for economy.
The object of this invention is to provide a powder coating composition for producing a "structure" finish which causes little or no atmospheric contamination and which is curable at relatively lower temperatures than hitherto.
According to this invention there is provided a curable powder coating composition comprising a curable epoxy resin, a curing agent for the epoxy resin and a silicone flow addition, the silicone flow additive being added to the composition in ground form after grinding of the other components thereof.
The invention also provides a method of producing a powder coating composition comprising mixing, extruding and grinding a curable epoxy resin and a curing agent therefor, and adding to the ground mixture a ground silicane flow additive.
The compositions of the invention may also comprise one or more of pigments and extenders which will usually be mixed with the epoxy resin
and curing agent.
The silicone flow additive is preferably first
blended with a portion of epoxy resin to form a
master-batch which is then ground to the same
size as the mixture of the other components and
mixed with the mixture of the other components.
The grinding is best carried out at very low temperatures so that usually the grinder is cooled
with liquid nitrogen. An average particle size of the
order of 10-75 microns is preferred.
The epoxy resin is preferably one which will
cure at relatively low temperatures, say at or
below 1 400C. and may be of the solid Bisphenol A
epichlorohydrin type. Any suitable curing agent
may be used such as an accelerated amine or a
resinous phenolic compound.
The silicone flow additive may be a silicone oil, such as that sold under the trade name
BAYSILONE by Bayer AG.
Suitable extenders are calcium carbonate, say in the form of chalk, barium sulphate say in the form of blanc fixe, and magnesium carbonate. The pigment will be chosen according to the desired colour but in any case inorganic compounds, usually oxides are preferred to organic compounds.
The ratio of pigment to extender will depend on the colour required. For example, a white composition will require very little extender whilst on the other hand a black composition will require very little pigment.
The compositions of this invention are suitable for spraying onto most surfaces but are particularly suitable for electrostatic spraying onto steel and non-ferrous alloy surfaces. After spraying the compositions may be cured by heat say at 1 400C for 10 minutes and gives a "structure" finish.
This invention will now be further described by means of the following Examples.
EXAMPLE 1
A white powder coating composition was prepared by mixing solid bisphenol A epichlorohydrin type epoxy resin of low molecular weight, solid resinous phenolic curing agent, a coprecipitate of calcium carbonate and magnesium carbonate and titanium dioxide. The mixture was extruded and then ground in a grinder cooled with liquid nitrogen. The ground mixture was sieved to leave a powder having an average particle size of from 10 to 75 microns.
Then, a mixture of solid bisphenol A epichlorohydrin type epoxy resin and silicone oil was extruded, ground in a grinder cooled by liquid nitrogen, and sieved to leave a powder also having an average particle size of from lotto 75 microns.
This powder was then mixed with first-mentioned powder to give the following composition in percent by weight:
Solid bisphenol A epichlorohydrin 37.0 type epoxy resin (low molecular weight)
Solid resinous phenolic curing 12.5 agent
Co-precipitate of calcium sulphate 1 9.9 and barium sulphate (MICRODOLX)
Titanium dioxide 30.0
Silicone oil (BAYSILONE) 0.6
The powder composition of this Example was sprayed onto a surface and found to cure satisfactorily at 1 40 C in 10 minutes giving a "structure" finish.
EXAMPLE 2
A black powder coating composition was prepared by mixing solid bisphenol A epichlorohydrin type epoxy resin (low molecular weight), solid resinous phenolic curing agent, coprecipitate of calcium carbonate and magnesium carbonate and carbon black. The mixture was extruded and then ground in a grinder cooled with liquid nitrogen. The ground mixture was sieved to leave a powder having an average particle size of from 10 to 75 microns.
Then, a mixture of solid bisphenol A epichlorohydrin type epoxy resin (low molecular weight) and silicone oil was extruded, ground in a grinder cooled with liquid nitrogen, and sieved to leave a powder having an average particle size of from 10 to 75 microns. This powder was then mixed with the first mentioned powder to give the following composition in percent by weight:
Solid bisphenol A epichlorohydrin 37.0 type epoxy resin (low molecular weight)
Solid resinous phenolic curing 1 2.5 agent
Coprecipitate of calcium carbonate 48.4 and magnesium carbonate
Silicone oil (BAYSILONE) 0.6
Carbon black 1.5
The powder composition of this Example was sprayed onto a surface and found to cure satisfactorily at 1 400C in 10 minutes giving a "structure" finish.
Claims (29)
1. A curable powder coating composition comprising a curable epoxy resin, a curing agent for the epoxy resin and a silicone flow additive, the silicone flow additive having been added to the pomposition in ground form after grinding of the other components thereof.
2. A composition as claimed in claim 1 wherein the epoxy resin is curable at a relatively low temperature.
3. A composition as claimed in claim 2 wherein the epoxy resin is curable at or below 1400 C.
4. A composition as claimed in claim 2 or 3 wherein the epoxy resin is of the solid Bisphenol A epichlorohydrin type.
5. A composition as claimed in any one of claims 1 to 4 wherein the curing agent is an accelerated amine or a resinous phenolic compound.
6. A composition as claimed in any one of claims 1 to 5 wherein the flow additive comprises a silicone oil.
7. A composition as claimed in any one of claims 1 to 6 further comprising one or more of pigments and extenders.
8. A composition as claimed in claim 7 wherein
the extender is calcium carbonate, barium
sulphate or magnesium carbonate.
9. A composition as claimed in claim 8 wherein
the calcium carbonate is in the form of chalk.
10. A composition as claimed in claim 8
wherein the barium sulphate is in the form of
blanc fixe.
11 A composition as claimed in any one of claims 7 to 10 wherein the pigment is an inorganic oxide.
12. A composition as claimed in any one of claims 1 to 11 having an average particle size of from 10 to 75 microns.
13. A method of producing a curable powder coating composition comprising mixing, extruding and grinding a curable epoxy resin and a curing agent therefor, and adding to the ground mixture a ground silicone flow additive.
14. A method as claimed in claim 13 wherein one or more of pigments and extenders are mixed with the epoxy resin and curing agent prior to extruding.
15. A method as claimed in claim 13 or 14 wherein the silicone flow additive is first blended with a portion of epoxy resin before grinding and adding to the ground mixture of other components.
16. A method as claimed in claim 13, 14 or 15 wherein grinding is carried out in a grinder cooled with liquid nitrogen.
17. A method as claimed in any one of claims 13 to 1 6 wherein the components are ground to an average particle size of from 10 to 75 microns.
1 8. A method as claimed in any one of claims 13 to 1 7 wherein the epoxy resin is curable at a relatively low temperature.
19. A method as claimed in claim 18 wherein the epoxy resin is curable at or below 1400 C.
20. A method as claimed in claim 1 8 or 19 wherein the epoxy resin is of the solid Bisphenol A epichlorohydrin type.
21. A method as claimed in any one of claims 1 3 to 20 wherein the curing agent is an accelerated amine or a resinous phenolic compound.
22. A method as claimed in any one of claims 13 to 21 wherein the flow additive comprises a silicone oil.
23. A method as claimed in any one of claims 13 to 22 further comprising mixing one or more of pigments and extenders with the epoxy resin and curing agent.
24. A method as claimed in claim 23 wherein the extender is calcium carbonate, barium sulphate or magnesium carbonate.
25. A method as claimed in claim 24 wherein the calcium carbonate is in the form of chalk.
26. A method as claimed in claim 24 wherein the barium sulphate is in the form of blanc fixe.
27. A method as claimed in any one of claims 23 to 26 wherein the pigment is an inorganic oxide.
28. A curable powder coating composition substantially as hereinbefore described with reference to Example 1 or Example 2.
29. A method of producing a curable powder coating composition substantially as hereinbefore described with reference to Example 1 or
Example 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB08310032A GB2118188B (en) | 1982-04-14 | 1983-04-13 | Powder coating compositions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8210831 | 1982-04-14 | ||
| GB08310032A GB2118188B (en) | 1982-04-14 | 1983-04-13 | Powder coating compositions |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8310032D0 GB8310032D0 (en) | 1983-05-18 |
| GB2118188A true GB2118188A (en) | 1983-10-26 |
| GB2118188B GB2118188B (en) | 1985-07-24 |
Family
ID=26282547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08310032A Expired GB2118188B (en) | 1982-04-14 | 1983-04-13 | Powder coating compositions |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2118188B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0735118A4 (en) * | 1994-10-14 | 1998-08-12 | Dow Corning Toray Silicone | COMPOSITION FOR POWDER COATING RESIN |
| EP0916709A3 (en) * | 1997-11-04 | 2000-11-08 | Morton International, Inc. | A one-component, low temperature curable coating powder |
| CN100347250C (en) * | 2005-10-10 | 2007-11-07 | 湘潭市至诚涂料有限公司 | Cryogenic curing powdery coating for heat-sensitive substrate material |
| WO2009034112A2 (en) | 2007-09-14 | 2009-03-19 | Akzo Nobel Coatings International B.V. | Powder coating extrusion process using liquid |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB899394A (en) * | 1959-03-13 | 1962-06-20 | Polymer Corp | Coating composition for a fluidized bed |
| GB963777A (en) * | 1961-08-24 | 1964-07-15 | Dow Corning | Coating powders |
| GB1211686A (en) * | 1966-11-21 | 1970-11-11 | Midland Silicones Ltd | Resinous compositions |
| GB1492753A (en) * | 1974-04-02 | 1977-11-23 | Dow Corning Ltd | Coating powders |
| GB2077271A (en) * | 1980-06-10 | 1981-12-16 | Bicc Ltd | Electrical insulation material |
-
1983
- 1983-04-13 GB GB08310032A patent/GB2118188B/en not_active Expired
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB899394A (en) * | 1959-03-13 | 1962-06-20 | Polymer Corp | Coating composition for a fluidized bed |
| GB963777A (en) * | 1961-08-24 | 1964-07-15 | Dow Corning | Coating powders |
| GB1211686A (en) * | 1966-11-21 | 1970-11-11 | Midland Silicones Ltd | Resinous compositions |
| GB1492753A (en) * | 1974-04-02 | 1977-11-23 | Dow Corning Ltd | Coating powders |
| GB2077271A (en) * | 1980-06-10 | 1981-12-16 | Bicc Ltd | Electrical insulation material |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0735118A4 (en) * | 1994-10-14 | 1998-08-12 | Dow Corning Toray Silicone | COMPOSITION FOR POWDER COATING RESIN |
| US6090890A (en) * | 1994-10-14 | 2000-07-18 | Dow Corning Toray Silicone Co., Ltd. | Resin composition for powder paints |
| EP0916709A3 (en) * | 1997-11-04 | 2000-11-08 | Morton International, Inc. | A one-component, low temperature curable coating powder |
| CN100347250C (en) * | 2005-10-10 | 2007-11-07 | 湘潭市至诚涂料有限公司 | Cryogenic curing powdery coating for heat-sensitive substrate material |
| WO2009034112A2 (en) | 2007-09-14 | 2009-03-19 | Akzo Nobel Coatings International B.V. | Powder coating extrusion process using liquid |
| WO2009034112A3 (en) * | 2007-09-14 | 2009-10-22 | Akzo Nobel Coatings International B.V. | Powder coating extrusion process using liquid |
| US8377346B2 (en) | 2007-09-14 | 2013-02-19 | Akzo Nobel Coatings International B.V. | Powder coating extrusion process using liquid |
| CN101802055B (en) * | 2007-09-14 | 2013-04-17 | 阿克佐诺贝尔国际涂料股份有限公司 | Powder coating extrusion process using liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2118188B (en) | 1985-07-24 |
| GB8310032D0 (en) | 1983-05-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |