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GB2116709A - Detecting surface mildew - Google Patents

Detecting surface mildew Download PDF

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Publication number
GB2116709A
GB2116709A GB08206873A GB8206873A GB2116709A GB 2116709 A GB2116709 A GB 2116709A GB 08206873 A GB08206873 A GB 08206873A GB 8206873 A GB8206873 A GB 8206873A GB 2116709 A GB2116709 A GB 2116709A
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United Kingdom
Prior art keywords
bioluminescence
atp
agent
contamination
image
Prior art date
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Granted
Application number
GB08206873A
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GB2116709B (en
Inventor
Brian Joseph Mccarthy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wira and Mather and Platt Ltd
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Wira and Mather and Platt Ltd
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Priority to GB08206873A priority Critical patent/GB2116709B/en
Publication of GB2116709A publication Critical patent/GB2116709A/en
Application granted granted Critical
Publication of GB2116709B publication Critical patent/GB2116709B/en
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12QMEASURING OR TESTING PROCESSES INVOLVING ENZYMES, NUCLEIC ACIDS OR MICROORGANISMS; COMPOSITIONS OR TEST PAPERS THEREFOR; PROCESSES OF PREPARING SUCH COMPOSITIONS; CONDITION-RESPONSIVE CONTROL IN MICROBIOLOGICAL OR ENZYMOLOGICAL PROCESSES
    • C12Q1/00Measuring or testing processes involving enzymes, nucleic acids or microorganisms; Compositions therefor; Processes of preparing such compositions
    • C12Q1/02Measuring or testing processes involving enzymes, nucleic acids or microorganisms; Compositions therefor; Processes of preparing such compositions involving viable microorganisms
    • C12Q1/04Determining presence or kind of microorganism; Use of selective media for testing antibiotics or bacteriocides; Compositions containing a chemical indicator therefor
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/36Textiles
    • G01N33/367Fabric or woven textiles
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12QMEASURING OR TESTING PROCESSES INVOLVING ENZYMES, NUCLEIC ACIDS OR MICROORGANISMS; COMPOSITIONS OR TEST PAPERS THEREFOR; PROCESSES OF PREPARING SUCH COMPOSITIONS; CONDITION-RESPONSIVE CONTROL IN MICROBIOLOGICAL OR ENZYMOLOGICAL PROCESSES
    • C12Q2304/00Chemical means of detecting microorganisms
    • C12Q2304/60Chemiluminescent detection using ATP-luciferin-luciferase system

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Immunology (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Food Science & Technology (AREA)
  • General Engineering & Computer Science (AREA)
  • Pathology (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • General Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Biophysics (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Toxicology (AREA)
  • Genetics & Genomics (AREA)
  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)

Abstract

A method has been developed for detecting the presence and even the location of mildew on textile fabrics, and by extension the presence of any living organism at the surface of any object, by the application of an agent for the release, from the cells of the organism, of a substance, exemplified by adenosine triphosphate, which is capable of reaction with a specific enzyme to produce bioluminescence. The bioluminescence is visualised by an image intensifier. The released substance may be allowed to migrate from the surface and be quantitatively determined, or it may be visualised in situ to show the location of the contamination.

Description

SPECIFICATION Microbiological testing The invention relates to methods of testing for the presence of living organisms at the surface of an object.
It has been known for several years that all living organisms contain substances contain adenosine triphosphate (ATP), and that hydrolytic reaction of ATP with certain enzymes results in the production of light, although the mechanism of the reaction is not necessarily fully understood. The amount of light, referred to as bioluminescence, emitted is very small, and it has been the practice, in laboratory experiments with the reaction, to determine the light emission by use of a photometer.
The ATP is contained in cells within the organisms, and can be released from the cells by the application of a reagent capable of attacking the cell membrane.
It has now been realised that the reaction can be adapted to provide a simple, rapid and essentially non-destructive test for the contamination by microorganisms of the surface of objects such as pieces of textile fabric.
ATP is, in fact, only one of a group of biochemical substances, each of which is capable of reaction with a specific enzyme to produce bioluminescence, and although in the following specification reference will be made for the sake of simplicity primarily to ATP, it should be understood that the term is to be contrued as extending to any member of the aforementioned group or a derivative thereof.
According to the invention there is provided a method of test for the presence of living organisms having ATP-bearing cells at the surface of an object, comprising applying to the surface an agent for the release of ATP from the cells, providing a bioluminescent agent for reaction with released ATP to produce bioluminescence, and observing the luminescence produced.
The releasing agent may be in solution or suspension in a liquid, and may be applied by spraying or may be poured onto the surface. The said releasing agent may be applied to the surface first whereby the ATP is released into the liquid and the bioluminescent agent is then added to the liquid.
Alternatively, the bioluminescent agent, in solution or suspension, may be applied to the surface first and the releasing agent is then applied to the thus moistened surface.
The observation may be made by the use of an image intensifier.
Embodiments of the invention will now be described by way of example, with reference to two techniquesforthevisualisation of microbiological contamination of the surface of a piece of textile fabric.
In the first example, a solution of NRB nucleotide releasing reagent for microbial cells is poured onto the surface of the sample in a shallow dish. The reagent has the effect of disrupting the membranes of the cells in any living organism present on or near the surface, such organism being, for example, that responsible for the defect commonly known as mildew. The disruption of the cell membranes allows ATP, which is known to occur in living organisms, to be released from within the cells and to enter the solution so as to spread over substantially the whole area of the dish.
A bioluminescent agent, Firefly luciferinluciferase, such as Limit HS (trade mark), is rehydrated with a buffer to give a solution of pH 7.75, a chelating agent is then added, and the solution is added, at a temperature in the range 20-25 degrees C, to the liquid in the dish.
The effect of the bioluminescent agent is to react with released ATP in the liquid so as to produce light in quantity proportional to the quantity of ATP released from the sample. It is understood that only about one photon of light is produced from a single molecule of ATP, and unless the sample had been heavily contaminated, and thus a large quantity of ATP had been released, the light emitted would be hardly visible to the naked eye though possibly sufficient to affect a sensitive photographic film.
However, even in the case of relatively slight contamination, the luminescence of the liquid in the dish can be visualised by the use of an image intensifier, such as Mullard (trade mark) XX1500TV which has a gain of approximately 65,000. By the use of the intensifier the luminescence provided by the sample can thus be directly observed by the eye and a semi-quantitative estimate can be made of the contamination present relative to that present in a standard or another unknown sample. A permanent record of the intensified image of the luminescent liquid can be produced by use of a camera or video recorder.
In a particularly advantageous application of the method, a visual image showing the precise location of contamination at a surface is provided. The method is particularly suitable for the examination of surfaces in situ and may be used to follow variations in contamination with time.
The method involves first applying the Firefly luciferin-luciferase enzyme, prepared as mentioned above, onto the surface to be investigated, conveniently by spraying. No significant reaction with ATP from surface contamination occurs at this stage because the ATP is predominantly enclosed within cell membranes. Commercially available firefly enzyme may itself be slightly contaminated with ATP however and there may be a slight bioluminescent background from reaction of the enzyme with such traces of ATP, and such background luminescence should be discounted in considering that revealed after the next subsequent step.
NRB nucleotide releasing reagent is then sprayed onto the surface wetted with the enzyme solution. As the ATP-bearing cells of any micro organisms present at the surface of the sample are disrupted by the releasing agent, the ATP is released into an environment of firefly enzyme whereby bioluminescence is emitted in the immediate vicinity of the cell from which the ATP was released.
If sufficient quantities of liquid were added, the bioluminescence would eventually spread over the whole wetted area, but in the presence of minimum liquid and over a relatively short period of time, the bioluminescence provides a substantially accurate image of the location and concentration of ATPbearing cells and thus of microbiological contamination.
By use of an image intensifier, the image can be seen by the eye or recorded by a camera. The image intensifier may be provided with a video camera and recording system, and provided that the reagents applied do not inhibit the growth of the microorganism, the technique would appear to provide a method for observing and recording the developing extent of contamination as a function of time.
A particularly advantageous aspect of the invention lies in the fact that the sample can be examined without any handling, which would involve the risk of itself adding undesirable microbilogical contamination, and without resorting to masseration as employed in the laboratory techniques hitherto employed for demonstrating bioluminescence.
Whilst in the forgoing description reference has been made to the use only of Firefly enzyme to act as a bioluminescence agent with the ATP occuring in living organisms to produce bioluminescence, methods are to be regarded as being within the scope of the invention which employ other agents which result in the emission of bioluminescence on reaction with biochemical molecules or derivatives thereof.
CLAIMS (Filed on 3 March 83) 1. A method oftesting forthe presence, at the surface of an object, of living organisms having ATP-bearing cells, comprising applying to said surface an agent for releasing ATP from the cells, providing agent for reaction with released ATP to produce bioluminescence, and observing the bioluminescence produced.
2. A method according to Claim 1 wherein the releasing agent is applied to the surface in solution or suspension in a liquid.
3. A method according to Claim 2 wherein the bioluminescence agent is subsequently added to the liquid.
4. A method according to Claim 1 wherein the bioluminescence agent in solution or suspension is added to the surface first and the releasing agent is then applied to the thus moistened surface.
5. A method according to any one of the preceding claims wherein the observation is made by use of an image intensifier.
6. A method according to Claim 5 wherein the image produced by the intensifier is recorded.
7. A method according to any one of the preceding claims used for visualisation of microbiological contamination of a textile fabric.
8. A method of testing for the presence, at the surface of an object, of living organisms having ATP-bearing cells, substantially as described.
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (8)

**WARNING** start of CLMS field may overlap end of DESC **. bioluminescence provides a substantially accurate image of the location and concentration of ATPbearing cells and thus of microbiological contamination. By use of an image intensifier, the image can be seen by the eye or recorded by a camera. The image intensifier may be provided with a video camera and recording system, and provided that the reagents applied do not inhibit the growth of the microorganism, the technique would appear to provide a method for observing and recording the developing extent of contamination as a function of time. A particularly advantageous aspect of the invention lies in the fact that the sample can be examined without any handling, which would involve the risk of itself adding undesirable microbilogical contamination, and without resorting to masseration as employed in the laboratory techniques hitherto employed for demonstrating bioluminescence. Whilst in the forgoing description reference has been made to the use only of Firefly enzyme to act as a bioluminescence agent with the ATP occuring in living organisms to produce bioluminescence, methods are to be regarded as being within the scope of the invention which employ other agents which result in the emission of bioluminescence on reaction with biochemical molecules or derivatives thereof. CLAIMS (Filed on 3 March 83)
1. A method oftesting forthe presence, at the surface of an object, of living organisms having ATP-bearing cells, comprising applying to said surface an agent for releasing ATP from the cells, providing agent for reaction with released ATP to produce bioluminescence, and observing the bioluminescence produced.
2. A method according to Claim 1 wherein the releasing agent is applied to the surface in solution or suspension in a liquid.
3. A method according to Claim 2 wherein the bioluminescence agent is subsequently added to the liquid.
4. A method according to Claim 1 wherein the bioluminescence agent in solution or suspension is added to the surface first and the releasing agent is then applied to the thus moistened surface.
5. A method according to any one of the preceding claims wherein the observation is made by use of an image intensifier.
6. A method according to Claim 5 wherein the image produced by the intensifier is recorded.
7. A method according to any one of the preceding claims used for visualisation of microbiological contamination of a textile fabric.
8. A method of testing for the presence, at the surface of an object, of living organisms having ATP-bearing cells, substantially as described.
GB08206873A 1982-03-09 1982-03-09 Microbiological testing detecting surface mildew Expired GB2116709B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB08206873A GB2116709B (en) 1982-03-09 1982-03-09 Microbiological testing detecting surface mildew

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB08206873A GB2116709B (en) 1982-03-09 1982-03-09 Microbiological testing detecting surface mildew

Publications (2)

Publication Number Publication Date
GB2116709A true GB2116709A (en) 1983-09-28
GB2116709B GB2116709B (en) 1986-02-19

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986007094A1 (en) * 1985-05-22 1986-12-04 University Of Wales College Of Medicine Bacterial cell extractant
WO1987006707A1 (en) * 1986-04-29 1987-11-05 Murex Corporation Bound assay components
GB2246197A (en) * 1990-07-12 1992-01-22 Bio Rad Laboratories Detection and imaging in biochemical assays using phosphorescent screens
GB2294115A (en) * 1994-10-11 1996-04-17 Whitlock Hughes Ltd Measuring surface contamination by organisms
GB2348438A (en) * 1999-03-19 2000-10-04 David Anthony Stafford Detecting microbes by bioluminescence
GB2358124A (en) * 2000-01-14 2001-07-18 Chemisphere Uk Ltd Method of cleaning and monitoring in ware washing machines
JP2002525123A (en) * 1998-09-30 2002-08-13 パッカード バイオサイエンス ベスローテン フェンノートシャップ How to detect ATP

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1379506A (en) * 1971-05-25 1975-01-02 Baxter Laboratories Inc Receptacle having a distendable sidewall
GB1550076A (en) * 1976-09-30 1979-08-08 Battelle Institut E V Methods of and samplers suitable for taking and collecting sample material
GB2073885A (en) * 1980-04-15 1981-10-21 Whitlock G D Method of and apparatus for detecting the presence of live organisms in substances
GB1601031A (en) * 1977-01-31 1981-10-21 Plakas C J Method for detection of bacterial concentration by luminescence
GB1604249A (en) * 1977-05-31 1981-12-02 Kolehmainen S Selective measurement of somatic and microbial cells

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1379506A (en) * 1971-05-25 1975-01-02 Baxter Laboratories Inc Receptacle having a distendable sidewall
GB1550076A (en) * 1976-09-30 1979-08-08 Battelle Institut E V Methods of and samplers suitable for taking and collecting sample material
GB1601031A (en) * 1977-01-31 1981-10-21 Plakas C J Method for detection of bacterial concentration by luminescence
GB1604249A (en) * 1977-05-31 1981-12-02 Kolehmainen S Selective measurement of somatic and microbial cells
GB2073885A (en) * 1980-04-15 1981-10-21 Whitlock G D Method of and apparatus for detecting the presence of live organisms in substances

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986007094A1 (en) * 1985-05-22 1986-12-04 University Of Wales College Of Medicine Bacterial cell extractant
WO1987006707A1 (en) * 1986-04-29 1987-11-05 Murex Corporation Bound assay components
GB2246197A (en) * 1990-07-12 1992-01-22 Bio Rad Laboratories Detection and imaging in biochemical assays using phosphorescent screens
GB2246197B (en) * 1990-07-12 1994-03-16 Bio Rad Laboratories Detection and imaging in biochemical assays using phosphor screens
GB2294115A (en) * 1994-10-11 1996-04-17 Whitlock Hughes Ltd Measuring surface contamination by organisms
JP2002525123A (en) * 1998-09-30 2002-08-13 パッカード バイオサイエンス ベスローテン フェンノートシャップ How to detect ATP
GB2348438A (en) * 1999-03-19 2000-10-04 David Anthony Stafford Detecting microbes by bioluminescence
GB2358124A (en) * 2000-01-14 2001-07-18 Chemisphere Uk Ltd Method of cleaning and monitoring in ware washing machines
GB2358124B (en) * 2000-01-14 2003-08-20 Chemisphere Uk Ltd Method of cleaning and monitoring in ware washing machines

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Publication number Publication date
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Legal Events

Date Code Title Description
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19980309