GB2198189A - Aerosol valve - Google Patents
Aerosol valve Download PDFInfo
- Publication number
- GB2198189A GB2198189A GB08629603A GB8629603A GB2198189A GB 2198189 A GB2198189 A GB 2198189A GB 08629603 A GB08629603 A GB 08629603A GB 8629603 A GB8629603 A GB 8629603A GB 2198189 A GB2198189 A GB 2198189A
- Authority
- GB
- United Kingdom
- Prior art keywords
- valve
- valve body
- stem
- valve stem
- unit according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
- B65D83/44—Valves specially adapted for the discharge of contents; Regulating devices
- B65D83/48—Lift valves, e.g. operated by push action
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Nozzles (AREA)
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Abstract
An aerosol valve comprising a mounting cup (10), a gasket (14) having a central opening, a valve housing (12), a valve stem (20) and a valve body (16), wherein the valve stem and valve body move within the valve housing in response to pressure on the valve stem, the improvement comprising a valve body having at least one upstanding wall (26) defining a recess (22) in the valve body and having a slot (21) extending from the top shoulder of the upstanding wall which slot communicates with the interior of the container when the valve is actuated; a valve stem having a longitudinal opening therethrough and a member (24) that frictionally and releasably engages within the valve body recess, said valve stem further having an orifice (42) aligned with the longitudinal opening of the valve stem, which communicates at one side with the slot in the recess of the valve body and at the other side with the longitudinal opening in the valve stem; and the central opening of the gasket sealing the slot defined by the upstanding wall of the valve body when the valve is in a closed position.
Description
1 1 h 2198189 L.ERDS01, VAM This invention relates to a valve for a
pressurized package commonly referred to as an aerosol package.
Aerosol packages usually comprise a valve unit situated in the neck of the container which is opened by finger pressure against an actuator disposed at one terminus of a valve stem. The valve unit has a inovable valve body and associated hollow valve stem which unseats from a gasket,, thereby permitting flow of product into a hollow valve stem (product conduit).
With certain products. e.g. paints, It Is desirable that the valve stem be separable from the valve body in-order to clean the product conduit should drying and resultant clogging occur. To provide the aforementioned valve stem removal capability,, the valve stem, at one end. is rolded integral to the valve actuator to thereby perrL,.it its separation from the valve body by pulling on the actuator. At the other end the valve stem mates with a rovable valve body situated beneath a resilient gasket. the valve stem being passed through a central opening in the resilient gasket. The gasket seals the product discharge orifice in the valve stem when the valve Is in a closed position. By depressing the valve stem. the product orifice in the stem is open to flow Jof product from the container.
More particularly. the aforedescribed aerosol valve comprises a container closure. commonly called a rounting cup, which Is clinched to the container bead. Within and crilnped to an upstanding central portion of the mounting cup, comnonly called a pedestal, is a valve housing having a resilient gasket disposed atop thereof, which gasket forms a seal between the valve housing and the mounting cup. Disposed within the housing is reciprocable valve closing/opening member comprising a valve body and valve ster, which body and stem have communicating passages for egressof the pressurized product to a discharge orifice situated in a finger depressible actuator.
The aerosol valve described above is commonly referred to in the aerosol industry as a 'female' valve, in contrast to the so called Omaleff valve wherein the valve stem is molded integral to the valve body. United States Patent Nos. 3,033,473, 380611203, 3,074,601 and 3,209,960 describe aerosol valves of the Ofemaleff type and United States Patent 2, 631,814 and aerosol valve of the vmalew type.
Furthermore, in prior aerosol valves, the product orifice in the valve stem is formed by a radial pin extending laterally through the wall of the valve stem, a so-called Oside actionO molding operation. The presence of the Oside actionff pin necessitates the removal of the pin before ejection of the molded part, with a consequent time delay in the molding operation.
Moreover, with orificesizes commonly used in aerosol valves, the Nside actionff pin often breaks with consequent shutdown of the 4molding operation.
Additionally, in prior aerosol valves, the central opening of the gasket seals radially against the product orifice in the valve ster.. Th c. scaline of the valve Eter. orifice upon closure of the valve forecloseú gravitational return of the product in the hollow valve ster. frcr roving past the valve stem orifice with the often consequent result that residual product in the hollow valve ster- dryE and clogs the passage in the valve ster.
Broadly stated, the invention is an improvement in an aerosol valve having a moveable, gasketed valve body-valve stem located within a valve housing, comprising a valve body having at least one upstanding wall defining a recess in the valve body and having a slot extending from the top shoulder of the upstanding wall which slot communicates with the interior of the container when the valve is actuated; a valve stem having a longitudinal opening therethrough and a rer-ber that frictionally and releasably engages within the valve body recess, said valve ster further having an orifice aligned with the longitudinal opening of the valve stem, which connunicates at one end with the Elot in the recess of the valve body and at the other end with the orifice in the valve stem; and the central opening of the gasket sealing the slot defined by the upstanding wall of the valve body when the valve -is in a closed position.
More specifically, and as a preferred embodiment, the aerosol valve of this invention includes a recess in the valve body beneath the valve Eter, orifice.
Referring to the drawings:
Figure 1 is a longitudinal sectional view of the valve of this invention in closed position.
Figure 2 is a longitudinal section of the valve of this invention in open position.
Fig-ure 3 is an enlarged longitudinal section of the valve stem.of Figures 1 and 2.
Figure 4 is a bottom plan view of Figure 3.
Figure 5 is an enlarged longitudinal partial section of the valve body of Figures 1 and 2.
Figure 6 is a top plan view of Figure 5.
Fig-ure 7 is an enlarged longitudinal partial section of the valve stem and valve body of Figure 1.
Figure a is a perspective view of the valve body of Figures 1, 2, 5-7.
Referring to the drawings, the mounting cup is generally designated as 10. Crimped to the mounting cup 10 is a valve housing 12 and a gasket 14. Disposed within the housing 12 is the valve body 16 having a recess 22, which valve body is biased toward the gasket 14 by the spring 18. A conventional dip tube 46 is shown attached to the bottom of the housing 12. A valve stem, generally designated as 201 is disposed within the recess.22 (shown in greater detail in Figure 5) in the top of the valve body 16 through the friction fitment of the depending extension 24 of the valve stem 20. Upstanding arcuate walls 26 (shown in V 25 detail in Figure 8) forn the upper portion of the recess 22 and define a slot 21. Beneath the slot 21.; defined by the upstanding arcuate walls 26, are grooves 32 in the side wall of the valve body recess 22, which grooves 32 comr.unicate with the space or reservoir 34 situated in the valve body recess 22 beneath the valve stem 20. An annular recess 50 is disposed in the top shoulder 40 of the valve body 16.
The valve stem 20 has an orifice 42 communicating with the spce 34. which orifice in the preferred embodiment of the invention acts as a product flow control orifice. A recess 30 is formed in the base of the valve stem 20 having a shoulder 28 against which the arcuate walls 26 bottom when the valve body 16 and valve stem 20 are in assembled relation. The outer wall 48 of the recess 30 in the valve stem 20 is tapered. Actuator button 36 is mounted on the upper portion of the valve stem 20. An annular rib or barb 38 is formed on the valve stem 20, which rib 38 anchors the valve stem 20 to the actuator button 36 and facilitates removal of the valve stem 20 from the valve body 16. 20 In the closed position of the aerosol valve, shoum in Figure 1. the gasket 14 seals against the annular top shoulder 40 of the valve body 16 and the upstanding arcuate walls 26 of the valve body 16 to prevent passage of product through the slot 21. In the open position of the valve, shown in Figure 2. pressure on the actuator button 36 depresses the valve stem 20 and the valve body 16 to expose the slot 21 to the pressurized contents of the container, thereby permitting passage of the container contents through the slot 21, the grooves 32, the space 34, the orifice 42 to the discharge orifice 44.
The product passages formed in the valve stem. and valve body of the subject invention require no side actiono molding pins. Further disposing the orifice 42 on the discharge side of the space 34 serves the function of permitting product in the valve stem on the discharge side of orifice 42 to back flow into the space 34 and thus not dry and clog the product passage in the valve stem. Still further, disposing the orifice 42 on the discharge side of the space 34 creates a residue of propellant in space 34 upon closing of the aerosol valve, which residue will assist in purging the valve stem and actuator product passages of residual product to thereby avoid or reduce clogging.
in assembling the several valve components, a sub-assembly comprising the valve stem, valve body, spring and gasket is initially made. Such a sub-assembly properly orients and maintains the position of the gasket relative to the valve body, thereby enabling rapid assembly of the sub-assembly and other valve components without risk of dislodging the orientation of the gasket to the other components prior to permanent positioning of the gasket through crimping of the valve to the mounting cup.
The structure in the valve stem-valve body fitment portions.that facilitates disposition and positional stabilization of the gasket onto the valve body is best shown in Figure 7. In assembling the valve unit the gasket 14 is passed over the outside -6 0 surface of valve Eter 20 and ultimately seated on the shoulder 40 of the valve body 16. Movement of the gasket 14 to a seating atop shoulder 40 of arcuate walls 26 is facilitgted by the sloped shoulder 48 the valve stem 20. 5 Moreover, the height of the upstanding arcuate walls 26 is preferably greater than the gasket thickness, so as to avoid the top shoulder of-the arcuate walls 26 passing beneath the gasket 14 during pressure filling of the container with propellant body. The structure designation numbers used herein in the description of Figures 1 and 2 likewise designate the same structural components in Figures 3-8.
9 8
Claims (11)
1. An aerosol valve unit comprising a mounting cup having a central aperture therein, a valve assembly positioned within said cup and comprising a valve housing, a valve body movably mounted within said housing, a valve spring upwardly biassing the valve body within the valve housing against the underside of the mounting cup, a hollow valve stem extending upwardly from the valve body through the central aperture, said valve stem being actuable by downward pressure thereon to move the valve body against said spring bias away from the underside of the mounting cup, an annular gasket positioned about the valve stem and sealingly engaging between the valve body and the underside of the mounting cup, and fluid flow passageway in the valve body permitting pressurized product to flow from the valve housing to the hollow bore of the valve stem, when said stem is depressed, wherein said fluid flow passageway in the valve body comprises a transverse slot formed in annular wall upstanding from the valve body, that slot being sealed by said gasket when the valve is in the closed condition.
2. A valve unit according to claim 1, wherein the transverse slot extends downwardly from the upper rim of said annular wall.
3. A valve unit according to claim 1 or 2, wherein the valve body presents an outwardly directed annular shoulder adjacent the base of said annular upstanding wall which serves as an additional sealing surface when the valve is in the closed condition by virtue of the annular gasket engaging against said shoulder.
4. A valve unit according to C12i.-n 1, 2 or 3, wherein the valve stem is a frictional fit within the valve body.
5. A valve unit according to any one of claims 1-4, wherein the valve body defines an internal recess or chamber into which fits the proximal end of the valve stem, and wherein the wall of the recess or chamber is formed with one or more longitudinally extending grooves which communicate with said transverse slot to provide, when the valve is opened, a passageway for the flow of pressurized product from said slot into the bore of the valve stem.
6. A valve unit according to claim 5, wherein said internal recess or chamber extends from the proximal end of the valve stem to define a reservoir space within the valve body, the bore of valve stem and said 9 1 groove(s) being in open communication with said reservoir space for the discharge and inflow, respectively, of said pressurized product, when the valve is open.
7. A valve unit according to claim 6, wherein said bore of the valve stem opens axially into said reservoir space through a metering aperture in the end face of the valve stem.
8. A valve unit according to any one of claims 1-7, wherein the upstanding annular wall on the valve body presents two diametrically opposed transverse slots separated one from the other by arcuate sections of 10 said upstanding annular wall.
9. A valve unit according to any one of claims 1-8, wherein the valve stem has a downwardly open annular recess which mates with the upstanding annular wall on the valve body.
10. A valve unit according to claim 9, wherein the outer surface of the valve stem is inwardly chamfered in the region of said annular recess.
11. A valve unit according to claim 1, substantially as hereinbefore described with refrence to the accompanying drawings.
PubliAhed 1988 at The Patent Office, State House, 66171 High I-Jolborn, London WC1R 4TP. Further copies may be obtained from The Patent Office,
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN895/MAS/87A IN170360B (en) | 1986-12-11 | 1987-12-11 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US93481786A | 1986-12-03 | 1986-12-03 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8629603D0 GB8629603D0 (en) | 1987-01-21 |
| GB2198189A true GB2198189A (en) | 1988-06-08 |
| GB2198189B GB2198189B (en) | 1990-01-24 |
Family
ID=25466109
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8629603A Expired - Lifetime GB2198189B (en) | 1986-12-03 | 1986-12-11 | Aerosol valve |
Country Status (18)
| Country | Link |
|---|---|
| EP (1) | EP0294425B1 (en) |
| JP (1) | JPH0661511B2 (en) |
| KR (1) | KR950014317B1 (en) |
| AT (1) | ATE85585T1 (en) |
| AU (1) | AU600547B2 (en) |
| BR (1) | BR8707560A (en) |
| CA (1) | CA1303565C (en) |
| DE (1) | DE3784165T2 (en) |
| DK (1) | DK426788D0 (en) |
| FI (1) | FI883569A7 (en) |
| GB (1) | GB2198189B (en) |
| MX (1) | MX160262A (en) |
| NO (1) | NO883294L (en) |
| NZ (1) | NZ222798A (en) |
| PT (1) | PT86287B (en) |
| SG (1) | SG35790G (en) |
| WO (1) | WO1988004266A1 (en) |
| ZA (1) | ZA879077B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2257474A (en) * | 1991-07-02 | 1993-01-13 | Abplanalp Robert H | Aerosol valve unit |
| US5439148A (en) * | 1991-02-06 | 1995-08-08 | B.J. Driessen & Zn. B.V. | Dispensing system from a container under pressure |
| US5480095A (en) * | 1993-09-14 | 1996-01-02 | Minnesota Mining And Manufacturing Company | Actuator and container for dispensing fluids |
| WO2003095334A1 (en) * | 2002-05-08 | 2003-11-20 | S. C. Johnson & Son, Inc. | Post-foaming gel, container therefor and apparatus and method for heating and dispensing |
| US6830164B2 (en) | 2000-11-27 | 2004-12-14 | S. C. Johnson & Son, Inc. | Post-foaming gel, container therefor and apparatus and method for heating and dispensing |
| GB2432406A (en) * | 2005-11-18 | 2007-05-23 | Keith Laidler | Aerosol valve |
| CN104801453A (en) * | 2014-12-22 | 2015-07-29 | 徐龙 | A spray valve and its working method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5906046A (en) * | 1997-07-31 | 1999-05-25 | Precision Valve Corporation | Aerosol tilt valve and method of forming same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB823430A (en) * | 1956-11-28 | 1959-11-11 | Jerome Moritz | Aerosol dispenser |
| GB986274A (en) * | 1962-04-18 | 1965-03-17 | Green Edward Howard | Improved spray button for an aerosol dispenser |
| GB1346440A (en) * | 1971-03-26 | 1974-02-13 | Green E H | Aerosol dispensing valve construction |
| GB1523732A (en) * | 1974-12-20 | 1978-09-06 | Green E H | Aersol valve and sprayhead |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1244457A (en) * | 1917-04-09 | 1917-10-30 | Benjamin F Bain | Mechanical toy. |
| US2913154A (en) * | 1955-11-07 | 1959-11-17 | Aerosol Res Company | Aerosol valve assembly |
| GB832507A (en) * | 1956-03-07 | 1960-04-13 | Metal Box Co Ltd | Improvements in or relating to dispensing apparatus for use with containers |
| US3098589A (en) * | 1959-05-21 | 1963-07-23 | Graham Cecil Robert Montgomery | Liquid dispensing device |
| FR1404762A (en) * | 1963-07-31 | 1965-07-02 | Improvements to valve sprayers | |
| US3741446A (en) * | 1970-12-03 | 1973-06-26 | Ciba Geigy Corp | Low pressure product container dispensing valve |
| FR2155033A5 (en) * | 1971-10-05 | 1973-05-18 | Rosenthal Claude | |
| US3915390A (en) * | 1972-10-08 | 1975-10-28 | Green Edward | Aerosol valve and sprayhead |
| FR2465938A1 (en) * | 1979-09-20 | 1981-03-27 | Aerosol Inventions Dev | ADDITIONAL GAS VALVE FOR AEROSOL PACKAGING |
-
1986
- 1986-12-11 GB GB8629603A patent/GB2198189B/en not_active Expired - Lifetime
-
1987
- 1987-12-03 BR BR8707560A patent/BR8707560A/en not_active IP Right Cessation
- 1987-12-03 AT AT88900314T patent/ATE85585T1/en not_active IP Right Cessation
- 1987-12-03 DE DE8888900314T patent/DE3784165T2/en not_active Expired - Fee Related
- 1987-12-03 AU AU10808/88A patent/AU600547B2/en not_active Expired
- 1987-12-03 EP EP88900314A patent/EP0294425B1/en not_active Expired - Lifetime
- 1987-12-03 WO PCT/US1987/003182 patent/WO1988004266A1/en not_active Ceased
- 1987-12-03 CA CA000553440A patent/CA1303565C/en not_active Expired - Lifetime
- 1987-12-03 PT PT86287A patent/PT86287B/en not_active IP Right Cessation
- 1987-12-03 JP JP63500689A patent/JPH0661511B2/en not_active Expired - Lifetime
- 1987-12-03 KR KR1019880700912A patent/KR950014317B1/en not_active Expired - Fee Related
- 1987-12-03 MX MX9608A patent/MX160262A/en unknown
- 1987-12-03 ZA ZA879077A patent/ZA879077B/en unknown
- 1987-12-03 FI FI883569A patent/FI883569A7/en not_active IP Right Cessation
- 1987-12-03 NZ NZ222798A patent/NZ222798A/en unknown
-
1988
- 1988-07-25 NO NO883294A patent/NO883294L/en unknown
- 1988-07-29 DK DK426788A patent/DK426788D0/en not_active Application Discontinuation
-
1990
- 1990-05-22 SG SG357/90A patent/SG35790G/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB823430A (en) * | 1956-11-28 | 1959-11-11 | Jerome Moritz | Aerosol dispenser |
| GB986274A (en) * | 1962-04-18 | 1965-03-17 | Green Edward Howard | Improved spray button for an aerosol dispenser |
| GB1346440A (en) * | 1971-03-26 | 1974-02-13 | Green E H | Aerosol dispensing valve construction |
| GB1523732A (en) * | 1974-12-20 | 1978-09-06 | Green E H | Aersol valve and sprayhead |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5439148A (en) * | 1991-02-06 | 1995-08-08 | B.J. Driessen & Zn. B.V. | Dispensing system from a container under pressure |
| GB2257474B (en) * | 1991-07-02 | 1995-04-05 | Abplanalp Robert H | Aerosol valve unit |
| CN1042500C (en) * | 1991-07-02 | 1999-03-17 | 罗伯特·亨利·阿普拉纳尔普 | Spray valve device |
| GB2257474A (en) * | 1991-07-02 | 1993-01-13 | Abplanalp Robert H | Aerosol valve unit |
| US5480095A (en) * | 1993-09-14 | 1996-01-02 | Minnesota Mining And Manufacturing Company | Actuator and container for dispensing fluids |
| US5711484A (en) * | 1993-09-14 | 1998-01-27 | Minnesota Mining And Manufacturing Company | Dispensing tube for directing the dispensing of fluids |
| US6830164B2 (en) | 2000-11-27 | 2004-12-14 | S. C. Johnson & Son, Inc. | Post-foaming gel, container therefor and apparatus and method for heating and dispensing |
| WO2003095334A1 (en) * | 2002-05-08 | 2003-11-20 | S. C. Johnson & Son, Inc. | Post-foaming gel, container therefor and apparatus and method for heating and dispensing |
| GB2432406A (en) * | 2005-11-18 | 2007-05-23 | Keith Laidler | Aerosol valve |
| CN104801453A (en) * | 2014-12-22 | 2015-07-29 | 徐龙 | A spray valve and its working method |
| CN104801453B (en) * | 2014-12-22 | 2017-01-25 | 徐龙 | A spray valve and its working method |
| CN106513200A (en) * | 2014-12-22 | 2017-03-22 | 徐龙 | Spray valve having continuous spraying function and facilitating filling and working method thereof |
| CN106513200B (en) * | 2014-12-22 | 2019-02-19 | 徐龙 | With continuous spraying function and filling convenient spray valve and its working method |
Also Published As
| Publication number | Publication date |
|---|---|
| PT86287B (en) | 1993-08-31 |
| EP0294425A4 (en) | 1990-04-24 |
| NO883294D0 (en) | 1988-07-25 |
| EP0294425B1 (en) | 1993-02-10 |
| NZ222798A (en) | 1990-04-26 |
| FI883569L (en) | 1988-07-29 |
| CA1303565C (en) | 1992-06-16 |
| DK426788A (en) | 1988-07-29 |
| KR950014317B1 (en) | 1995-11-24 |
| DE3784165D1 (en) | 1993-03-25 |
| AU1080888A (en) | 1988-06-30 |
| FI883569A0 (en) | 1988-07-29 |
| DK426788D0 (en) | 1988-07-29 |
| EP0294425A1 (en) | 1988-12-14 |
| GB8629603D0 (en) | 1987-01-21 |
| GB2198189B (en) | 1990-01-24 |
| PT86287A (en) | 1989-01-17 |
| KR890700103A (en) | 1989-03-02 |
| WO1988004266A1 (en) | 1988-06-16 |
| MX160262A (en) | 1990-01-24 |
| BR8707560A (en) | 1988-12-06 |
| SG35790G (en) | 1990-07-13 |
| ATE85585T1 (en) | 1993-02-15 |
| JPH01501533A (en) | 1989-06-01 |
| FI883569A7 (en) | 1988-07-29 |
| AU600547B2 (en) | 1990-08-16 |
| DE3784165T2 (en) | 1993-05-27 |
| ZA879077B (en) | 1988-05-27 |
| JPH0661511B2 (en) | 1994-08-17 |
| NO883294L (en) | 1988-07-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20051211 |