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GB2184468A - Preventing the inflow of water from water-bearing strata - Google Patents

Preventing the inflow of water from water-bearing strata Download PDF

Info

Publication number
GB2184468A
GB2184468A GB08630278A GB8630278A GB2184468A GB 2184468 A GB2184468 A GB 2184468A GB 08630278 A GB08630278 A GB 08630278A GB 8630278 A GB8630278 A GB 8630278A GB 2184468 A GB2184468 A GB 2184468A
Authority
GB
United Kingdom
Prior art keywords
water
blocking
medium
strata
bearing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB08630278A
Other versions
GB8630278D0 (en
Inventor
Dr Manfred Heilmann
Miroslav Trsek
Bedrich Parizek
Ivailo Terzijski
Jan Cech
Ernst Kaulbars
Eberhard Loffler
Kurt Sterba
Fritz Kroll
Josef Tomiska
Bohumir Svoboda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
URANOVE DOLY K P HAMR
VYZK USTAV GEOLOG INZENYR
Brennstoffinstitut Freiberg
Original Assignee
URANOVE DOLY K P HAMR
VYZK USTAV GEOLOG INZENYR
Brennstoffinstitut Freiberg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by URANOVE DOLY K P HAMR, VYZK USTAV GEOLOG INZENYR, Brennstoffinstitut Freiberg filed Critical URANOVE DOLY K P HAMR
Publication of GB8630278D0 publication Critical patent/GB8630278D0/en
Publication of GB2184468A publication Critical patent/GB2184468A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/516Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls characterised by their form or by the form of their components, e.g. encapsulated material
    • C09K8/518Foams
    • EFIXED CONSTRUCTIONS
    • E02HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
    • E02DFOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
    • E02D3/00Improving or preserving soil or rock, e.g. preserving permafrost soil
    • E02D3/12Consolidating by placing solidifying or pore-filling substances in the soil
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/13Methods or devices for cementing, for plugging holes, crevices or the like
    • E21B33/138Plastering the borehole wall; Injecting into the formation
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F15/00Methods or devices for placing filling-up materials in underground workings

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Fluid Mechanics (AREA)
  • Physics & Mathematics (AREA)
  • Agronomy & Crop Science (AREA)
  • Soil Sciences (AREA)
  • Materials Engineering (AREA)
  • Paleontology (AREA)
  • Civil Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

A method and a medium for blocking the inflow of mineralized and/or acid-containing water from water-bearing strata, and in particular from fissured or porous solid rock, into excavations or mine openings, comprises injecting a treating fluid into water-bearing horizons with overlying strata of cohesive material. The injection pressure is at least 0.2 MPa below the frac pressure of the water-bearing horizons or the overlying strata. Gas is injected to foam the treating fluid, this treating fluid consists of a surfactant to which suitable stabilizers are added.

Description

SPECIFICATION Method and a medium for blocking the inflow of mineralized and/or acid-containing water.
This invention relates to a method and a medium for blocking the inflow of mineralized and/or acid-containing water from water-bearing strata, and in particular from fissured or porous solid rock, into excavations or mine openings.
As is generally known, water inflows from water-bearing strata into mine openings or excavations are prevented by removing the water from the strata concerned.
Appropriate processes are: well point drainage; roadway drainage; and combinations or roadway andfilterwell drainage, and drainage bydrainage roads and filter drains provided between water-bearing strata and drainage roads.
Other processes employed to prevent water inflows are blocking processes such as the provision of cut-offtrenches and the injection of blocking media into the pore spaces of water-bearing strata.
Basically, the processes mentioned help to keep water inflows into mine openings or excavations within desired limits.
However, the above processes have substantial disadvantages: they require enormous expenditures in terms of materials and technology. In well point or roadway drainage large amounts of water are removed from mine openings but these drainage operations have a detrimental effect on large areas which would otherwise be undisturbed by mining. In addition to the water in situ, water from catchment areas of excavations or mine openings has to be drained away continuously. Mainly, the blocking processes known so far involve greattechnoligical efforts, or are restricted, with respect to the blocking depths; they also involve substantial costs of blocking media such as synthetic resins or polymers orsimilarsubstancesusedforporespaceblocking (DD-PS21 902; DE-2544543).
An object ofthe invention is to reduce, or block, the inflow of mineralized and/or acid containing water from water-bearing strata, and in particularfrom fissured or porous solid rock, into excavations or mine openings, therby eliminating the disadvantages mentioned hereinabove and reducing the material expenditures involved.
According to this invention there is provided a method for blocking the inflow of mineralized and/or acid-containing water from water-bearing strata, and in particularfrom fissured or porous solid rod, into excavations or mine openings, in which method a complex treating fluid is prepared on the surface and is then introduced continuously, via injection wells, into a water-bearing horizon with overlying strata of cohesive material; and wherein the injectin pressure is at least 0.2 MPa below the frac pressure ofthe water-bearing horizon orthe overlying strata; and wherein a predetermined volume of gas is injected to foam the treating fluid.
In this invention the inflow of mineralized and/or acid-containing water from surrounding formations into mine opernings or excavations is blocked by injecting suitable media into the water-bearing strata.
A homogenous and complex liquid is prepared on the surface and is then introduced into injection wells in orderto reach andtreatall layers to be blocked. Afterthe continuous injection of this liquid via said wells into the water-bearing horizons with overlying cohesive strata a calculated volume of gas is injected to form a disperse medium (foam)for blocking.
The injection pressure required is at least 0.2 MPa below the frac pressure of the water-bearing horizons (layers) or the overlying strata.
Technological modifications stimulating foam formation consist of an injection of gas before and after the injection of the solution, or in an alternating injection of gas and a solution. In such processes the formation of a disperse medium is particularly intensive.
The treating fluids consisting of aqueous solutions of surfactants which form finely disperse and stable foams having a comparatively high density (p > 0.04 g/cm3) if contacted with a gas, are introduced into the water-bearing horizons and are foamed by means of the gas injected. Using a predetermined concentrations, a temporary barrier blocking the flow of ground water is formed in the process of foaming said fluid, this barrier having a specified extension as a function of the quantity of treating fluid used.
Preferably, the treating fluids should contain 0.5 to 5.0% of a surfactant. Nonionics such as oxyethylated fatty alcohols are used, or mixtures of nonionics and ionic surfactants such as amine salts, said mixtures containing no more than 5% of ionic surfactants.
Optionally, stabilizers such as polymers, clay minerals or higher alcohols are added to enhance the blocking effect, with portions ranging between 0.01 and 0.5 mass % related to the total amount oftreating fluid.
The barriers formed by the method according to the present invention result in a reliabletemporaty control of the water contained in the water-bearing horizon.
Contrary to conventional processes involving high technological effort and financial expenditure, the method according to the invention consists of blocking the inflow of water by means of a foam which fills the pore spaces of a given horizon. This foam meets the quality requirements with regard to stability and resistance to highly mineralized ground water. By using suitable surfactants, treating fluids can be produced which form stable blocking foams in the pore spaces of rocks even under conditions of extreme pressure and temperature.
The injection of the blocking fluid and the gas does not involve substantial technological expense. The blocking method may be used separately or in combination with known methods such as the blocking of deep subsurface areas adjacentto the bottom of cut-offtrenches.
Example The treating fluid amounting to 5 m3 per metre of thickness of the water-bearing horizon and consisting of a 5% solution of a nonionic such as e.g.
Dispergator BO, mixed with 5 parts by weight of an ionicsurfactantsuch as e.g. FCF350 is introduced in up to 5 equal portions in the process of alternating injections of said fluid and a gas into water-bearing horizons at a depth of 250m containing highly mineralized water. To enhance the blocking effect 0.1 mass % of polymer (TBS-O) (related to the total amount of fluid) are added to the treating fluid. The injection pressure employed to introduce the treating fluid is 2.8 MPa, and the injection pressure of the gas is 2.8to 3.5 MPa, and the injection pressure of the gas is 2.8 to 3.5 MPa. In the process, the permeability of the water-bearing horizon was reduced by 103 m/s.

Claims (5)

1. A method for blocking the inflow of mineralized and/or acid-containing water from water-bearing strata, and in particular from fissured or porous solid rock, into excavations or mine openings, in which method a complex treating fluid is prepared on the surface and is then introduced continuously, via injection wells, into a water-bearing horizon with overlying strata of cohesive material; and wherein the injection pressure is at least 0.2 MPa belowthe frac pressure of the water-bearing horizon or the overlying strata; and wherein a predetermined volume of gas is injected to foam the treating fluid.
2. A method according to Claim 1 wherein irrespective of the composition of the substances used, such substances are introduced in portions, by alternating injections of the fluid and a gas, to intensifytheformation of a disperse medium for blocking.
3. A medium for blocking the inflow of mineralized and/or acid-containing water from water-bearing strata, and in particularfrom rock strata containing ground water, into excavations, opencast mines or other mine openings, said medium being contained in a treating fluid and characterized in that is comprises a homogenous aqueous solution containing 0.5to 5.0 mass % of nonionicsuch as oxoethylated fatty alcohols, or mixtures of nonionics and ionic surfactants such as amine salts, said mixtures containing no more than 5% of ionic surfactants; that the medium forms a stable and finely disperse foam by means of a gas injected, said foam having a density of p > 0.04 g/cm3.
4. Medium in accordancewithClaim3,wherein stabilizers such as polymers, clay minerals or higher alcohols are added to enhance the blocking effect, with portions ranging between 0.01 and 0.5 mass % related to the amount of treating fluid.
5. A method or a medium substantially as herein described and exemplified.
GB08630278A 1985-12-18 1986-12-18 Preventing the inflow of water from water-bearing strata Withdrawn GB2184468A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD28464785A DD256429A3 (en) 1985-12-18 1985-12-18 METHOD AND MEDIUM FOR BLOCKING MINERALIZED AND / OR SAEFERING WATER INFLUENCES

Publications (2)

Publication Number Publication Date
GB8630278D0 GB8630278D0 (en) 1987-01-28
GB2184468A true GB2184468A (en) 1987-06-24

Family

ID=5574565

Family Applications (1)

Application Number Title Priority Date Filing Date
GB08630278A Withdrawn GB2184468A (en) 1985-12-18 1986-12-18 Preventing the inflow of water from water-bearing strata

Country Status (9)

Country Link
BE (1) BE905937A (en)
BG (1) BG48046A1 (en)
CS (1) CS578386A1 (en)
DD (1) DD256429A3 (en)
DE (1) DE3638246A1 (en)
FR (1) FR2591657A1 (en)
GB (1) GB2184468A (en)
HU (1) HUT42804A (en)
NL (1) NL8603114A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0380150A1 (en) * 1989-01-27 1990-08-01 Pumptech N.V. Delayed rigid foam systems and applications in particular for selective plugging treatments in the oil industry
EP0380151A1 (en) * 1989-01-27 1990-08-01 Pumptech N.V. Delayed rigid foam systems and applications in particular for plugging - selective treatments in the oil industry
WO1991007568A1 (en) * 1989-11-17 1991-05-30 Ministerstvo Gazovoi Promyshlennosti Sssr Method for finishing a well

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109811757B (en) * 2019-03-12 2020-12-01 安徽理工大学 A kind of prevention method of surface fissure geological disaster in mining area

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3530940A (en) * 1969-02-05 1970-09-29 Pan American Petroleum Corp Increasing foam stability in earth formations
GB2066874A (en) * 1980-01-02 1981-07-15 Shell Int Research Method of drilling a borehole through cavernous underground formations
GB2119358A (en) * 1982-04-30 1983-11-16 Dow Chemical Co Lightweight cement slurry
US4420462A (en) * 1982-03-22 1983-12-13 Clyde Robert A Catalytic heat exchanger
US4495995A (en) * 1980-05-19 1985-01-29 Phillips Petroleum Company Method for plugging and subsequent treatment of subterranean formations

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3342256A (en) * 1964-04-17 1967-09-19 Union Oil Co Method for recovering oil from subterranean formations
US3330351A (en) * 1964-07-24 1967-07-11 Union Oil Co Method for inhibiting the flow of liquid into a well bore
DE2544543C2 (en) * 1975-10-04 1986-07-03 Kyokado Engineering Co., Ltd., Tokio/Tokyo Method of consolidating poor quality soil
CH642415A5 (en) * 1979-08-24 1984-04-13 Grund Und Tiefbau Ag Bern Method of sealing a ground formation which surrounds an underground working face and is under the pressure of ground water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3530940A (en) * 1969-02-05 1970-09-29 Pan American Petroleum Corp Increasing foam stability in earth formations
GB2066874A (en) * 1980-01-02 1981-07-15 Shell Int Research Method of drilling a borehole through cavernous underground formations
US4495995A (en) * 1980-05-19 1985-01-29 Phillips Petroleum Company Method for plugging and subsequent treatment of subterranean formations
US4420462A (en) * 1982-03-22 1983-12-13 Clyde Robert A Catalytic heat exchanger
GB2119358A (en) * 1982-04-30 1983-11-16 Dow Chemical Co Lightweight cement slurry

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0380150A1 (en) * 1989-01-27 1990-08-01 Pumptech N.V. Delayed rigid foam systems and applications in particular for selective plugging treatments in the oil industry
EP0380151A1 (en) * 1989-01-27 1990-08-01 Pumptech N.V. Delayed rigid foam systems and applications in particular for plugging - selective treatments in the oil industry
FR2642468A1 (en) * 1989-01-27 1990-08-03 Schlumberger Cie Dowell FOAM SYSTEMS FOR SELECTIVELY CLAMPING UNDERGROUND FORMATIONS, ESPECIALLY AROUND PETROLEUM WELLS
FR2642467A1 (en) * 1989-01-27 1990-08-03 Schlumberger Cie Dowell DELAYED RIGID FOAM SYSTEMS AND APPLICATIONS IN PARTICULAR TO SELECTIVE CLAMPING TREATMENTS IN THE PETROLEUM INDUSTRY
WO1991007568A1 (en) * 1989-11-17 1991-05-30 Ministerstvo Gazovoi Promyshlennosti Sssr Method for finishing a well

Also Published As

Publication number Publication date
BE905937A (en) 1987-04-16
GB8630278D0 (en) 1987-01-28
DE3638246A1 (en) 1987-06-25
DD256429A3 (en) 1988-05-11
BG48046A1 (en) 1990-11-15
HUT42804A (en) 1987-08-28
FR2591657A1 (en) 1987-06-19
CS578386A1 (en) 1988-10-14
NL8603114A (en) 1987-07-16

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Legal Events

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WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)