GB2174601A - Insecticides comprising fluvalinate and thiometon - Google Patents
Insecticides comprising fluvalinate and thiometon Download PDFInfo
- Publication number
- GB2174601A GB2174601A GB08610791A GB8610791A GB2174601A GB 2174601 A GB2174601 A GB 2174601A GB 08610791 A GB08610791 A GB 08610791A GB 8610791 A GB8610791 A GB 8610791A GB 2174601 A GB2174601 A GB 2174601A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- compound
- aphid
- aphids
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- INISTDXBRIBGOC-CGAIIQECSA-N [cyano-(3-phenoxyphenyl)methyl] (2s)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate Chemical compound N([C@@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-CGAIIQECSA-N 0.000 title abstract description 16
- OPASCBHCTNRLRM-UHFFFAOYSA-N thiometon Chemical compound CCSCCSP(=S)(OC)OC OPASCBHCTNRLRM-UHFFFAOYSA-N 0.000 title abstract description 16
- 239000002917 insecticide Substances 0.000 title description 5
- 241001124076 Aphididae Species 0.000 claims abstract description 29
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 15
- 241000238631 Hexapoda Species 0.000 claims abstract description 7
- 235000016068 Berberis vulgaris Nutrition 0.000 claims description 29
- 241000335053 Beta vulgaris Species 0.000 claims description 29
- 241000721621 Myzus persicae Species 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 18
- 241001425390 Aphis fabae Species 0.000 claims description 15
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 11
- 239000004480 active ingredient Substances 0.000 claims description 3
- 235000013339 cereals Nutrition 0.000 claims description 3
- 241000253994 Acyrthosiphon pisum Species 0.000 claims description 2
- 241000273346 Aphis helianthi Species 0.000 claims description 2
- 241001401861 Phorodon humuli Species 0.000 claims description 2
- 230000000749 insecticidal effect Effects 0.000 claims description 2
- 244000020551 Helianthus annuus Species 0.000 claims 1
- 235000003222 Helianthus annuus Nutrition 0.000 claims 1
- 240000004713 Pisum sativum Species 0.000 claims 1
- 235000010582 Pisum sativum Nutrition 0.000 claims 1
- 244000061456 Solanum tuberosum Species 0.000 claims 1
- 235000002595 Solanum tuberosum Nutrition 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 description 6
- 239000004495 emulsifiable concentrate Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- -1 xylene Chemical class 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000721714 Macrosiphum euphorbiae Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 241001401863 Phorodon Species 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 231100001184 nonphytotoxic Toxicity 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A method of combating insects, particularly aphids, comprises applying to a locus, separately or together, fluvalinate and thiometon. A suitable composition comprises fluvalinate <IMAGE> and thiometon <IMAGE> in a weight ratio of, e.g., 0.5-1 to 1-3.
Description
SPECIFICATION
Improvements in or relating to insecticides
The present invention relates to insecticides.
It has been found that the use of
a) the compound of formula I,
hereinafter referred to by the common name "fluvalinate", in association with b) the compound of formula II,
hereinafter referred to by the common name "thiometon", is particularly effective in combating insect pest, especially aphids.
Fluvalinate is a known insecticide effective in the control of insects in cotton crops, in vegetable crops and in tabacco crops (see for example French patent application No. 2 405 922 and European patent application No. 0 038 617). Thiometon is also a known insecticide used for the control of aphids. It has now been found, that the use of fluvalinate in combination with thiometon surprisingly and substantially enhances the effectiveness of the latter in combating such insects, especially aphids.
Accordingly, the invention provides an improved method of combating insects in a locus, which comprises applying to the locus, in admixture or separately, an insecticidally effective amount of fluvalinate of formula I and thiometon of formula II.
The method of the invention is useful for combating aphids and other pests of the order of hemipter. Particularly it is useful for the control of aphids in any crops, for example potato aphid (Myzus persicae and Macrosiphum euphorbiae), pea aphid (Arctisiphon pisi and Aphis fabae), cereal aphid, beet aphid, hop aphid (Phorodon humili), sunflower aphid, rape aphid, bean aphid, green peach aphid and market garden aphid, especially green peach aphid (Myzus persicae) and bean aphic (Aphis fabae).
The weight ratio of fluvalinate: thiometon is preferably of 0.5-1:1-3, more preferably of 0.6-0.8:1.5-2.5, most preferably of 0.72:2.
Suitable application rates are 0.030-0.060 kg preferably 0.035-0.045 kg per hectare of fluvalinate in admixture with 0.060-0.180 kg, preferably 0.090-0.150 kg per hectare of thiometon. Particularly good results are obtained against the aphids Myzus persicae and Aphis fabae by applying 0.432 kg per hectare of fluvalinate in admixture with 0. 120 kg per hectare of thiometon, e.g. by applying 0.500 or 0.600 1 per hectare of a formulation having a concentration of 72 g/l of fluvalinate and 200 g/l of thiometon.
The application of fluvalinate and thiometon, in admixture or separately, may be effected according to known methods and with usual apparatus.
The invention also provides an insecticidal composition comprising as active ingredients the compound of formula I and the compound of formula II.
In the composition of the invention, the weight ratio of fluvalinate: thiometon is preferably as defined above.
The composition of the invention may be employed in either solid or liquid forms e.g. in the form of a wettable powder or a emulsifiable concentrate incorporating conventional diluents.
Such compositions may be produced in conventional manner, e.g. by mixing the active ingredients with a diluent and optionally other formulating ingredients such as surfactants.
The term diluents as used herein means any liquid or solid agriculturally acceptable material which may be added to the active constituent to bring it to an easier or improved applicable form, respectively to a usable or desirable strength of activity. It can for example be talc, kaolin, diatomaceous earth, xylene, or water.
Liquid forms may include non-phytotoxic diluents such as alcohols, glycols, glycolic ethers, aliphatic and aromatic hydrocarbons, e.g. xylene, alkylnaphthalenes and other petroleum distillates, and ketones, e.g. cyclohexanone and isophorone. Adjuvants such as surface active agents, e.g. wetting and emulsifying agents such as polyglycol ethers formed by reaction of alkylene oxides with high molecular weight alcohols, mercaptans or alkyl phenols and/or alkylbenzene sulphonates may be included in emulsifiable concentrate forms. Adjuvants such as wetting agents, e.g. condensation products or formaldehyde with naphthalene sulphonate, an alkylarylsulphonate or a lignin sulphonate, may be included in wettable powders to be applied as an aqueous suspension.
The composition of the invention may also be formulated in the form of a twin packet.
In general, the formulations include from 0.1 to 90% by weight of active agents, from 0 to 20% by weight of agriculturally acceptable surfactant and 99.99% to 10% by weight of diluent(s), the active agents consisting of the compound of formula I and the compound of formula
II, preferably in the weight ratio as defined above.
Concentrate forms of compositions generally contain between about 2 and 90%, preferably between about 5 and 70% by weight of active agents. Application forms of formulation may for example contain from 0.1 to 20% by weight, preferably from 0.1 to 5% by weight of active agents.
Aside from the above mentioned carriers, diluents and adjuvants, other additives such as stabilizing agents, deactivators, surface adhesion improvers, anti-corrosives, defoaming agents and pigments may also be included.
The invention is illustrated by the following Examples in which all parts and pourcentages are by weight.
Example 1
85 parts of fluvalinate and 210 parts of thiometon are mixed with 60 parts of isooctylphenyl decaglycol ether and 20 parts of the calcium salt of an alkyl-aryl-sulphonate and 625 parts of xylene. The thus obtained emulsifiable concentrate may be diluted with water to the desired concentration prior to use.
Example 2
20 parts of the calcium salt of an alkyl-aryl-sulphonate and 33 parts of nonylphenylpolyglycol ether are added to 412 parts of an aromatic petroleum fraction having a boiling point of 156-178"C and the mixture is stirred until a homogeneous solution is obtained. 30 parts of a commercial stabilizer are added and then 400 parts of thiometon (50%) and 80 parts fluvalinate (90%) and the mixture is thoroughly mixed until a homogeneous solution is obtained. The thus obtained emulsifiable concentrate may be diluted with water to the desired concentration prior to use.
Application Examples
The activity of the new combination in controlling aphids is shown in tests carried out on beet plots. In these tests, 0.500 or 0.600 I/ha of an emulsifiable concentrate prepared according to
Example 1 or 2 and comprising 72 g/l of fluvalinate and 200 g/l of thiometon has be sprayed.
The application is carried out a the beginning of the infestation, i.e. 1 green peach aphid (Myzus persicae) for 2 beets and 20 to 30% of the beets infested by bean aphids (Aphis fabae).
The evaluation of aphids has been effected on 20 or 25 beets by plot, before application and 2, 7, 14, 21 and 28 days later. The results are reported in the following tables. In the tables M means Myzus persicae and A means Aphis fabae.
Test A (Table a)
The test was carried out on the variety Masabel at the stade of 10 leaves. At the beginning, 36 green peach aphids were present for 25 beets and 6 bean aphids were present for 25 beets.
Table a
Dose .Average number of aphids for 25 beets after application ( in days) M A M A M A M A Untreated 22 2.3 14 6.3 2.3 3.5 0.5 7.8 0,51/ha 6 1.3 1.5 1.3 0 1 0 4.5 Test B (Table b)
The test was carried out on the variety Arigo mono at the stade of 8-12 leaves. The beets were artificially infested by a supply of 4 aphids for 5 beets.
Table b
Average number of aphids for 25 Dose beets after application (in days) 2 7 14 21 M A M A M A M A Untreated 36 115 36 186 20 339 16 47 36 186 20 339 16 47 0.5 l/ha 0.5 6 0.5 4 1 73 1.3 64 Test C (Table c)
The test was carried out on the variety Haweduca at the stade of 8-10 leaves. At the beginning, 299 bean aphids were present for 25 beets.
Table c
Dose Average number of aphids for 25 beets after application (in days) 2 7 14 21 A A A A Untreated 305 607 1070 2578 0.5 l/ha 8 32 181 715 Test D (Table d)
The test was carried out on the beet variety Virtus at the stade of 4-6 leaves. The average number of green peach aphids and bean aphids for 20 beets before application was 52,5 and 1 respectively.
Table d
Average number of aphids for 20 beets Dose after application (in days) 2 .7 14 21 28 M A M A M A M A M A Untreated 49.5 4 44,5 2.5 184 20;;7 464 14.5 519 16.2 0.5 1 21.8 3 24.5 2.2 58.0 8.5 69.5 4,0 107 5,2 0.6 1/ha 6.0 0.5 9.0 1.2 15.5 2.5 42.8 1.5 77 4.7 Test E (Table e)
The test was carried out on the beet variety Donor at the stade of 6-8 leaves. The plants were infested principally by green peach aphids (on average 27.5 for 20 beets before applications). During 15 days, the aphid green peach aphid population increased as well as for bean aphids which appeared after 15 days.
Table e
Dose Average number of aphids for 20 beets after application (in days) 2 8 15 21 28 Untreated 27.3 - 105.8 - 278 28.2 75.8 50.5 12.5 0.5 1/ha 20 0 9.3 15.3 13.0 4.8 25.2 2.8 - 0.6 1/ha 1,0 - 1,0 - 12.3 2.0 2,5 9.7 4.5 - Test F (Table f)
The test was carried out on the beet variety Monohil at the stade of 6-8 leaves.The average number of green peach aphids and bean aphids before application was 3.0 and 38.5 respectively. 15 days after treatment, the aphids disappeared.
Table f
Average number of aphids for 20 beets Dose after application (in days) 2 7 15 M A M A M A Entreated 6.2 7.3 6.8 16.3 67.7 24. 3 0.5 1/ha 0.2 0.0 4.8 2.0 18.2 12.8 0.6 l/ha 0.2 0 3 0.5 0.8 10.7 12.5 Test G (Table g)
The test was carried out on the beet variety Monosvalof at the stade of 6-8 leaves.Before application, the average number of green peach aphids and bean aphids for 20 beets was 11.2 and 37.5 respectively.
Table g
Average number of aphids for 20 beets Dose after application (in days) 2 7 15 21 0.5 1/ha 0.5 0.8 : 0.3 0.0 0.3 33.6 23.8 23.7 0.6 1/ha 0.0 1 0.3 1 0.5 0 5 o.3 ! 20.6 28.5 28.5 Test H (Table h)
The test was carried out on the beet variety Virtus at the stade of 2-4 leaves. The average number of green peach aphids before application was 12 for 20 beets.
Table h
Dose Average number of aphids for 20 beets after application (in days) 2 7 15 21 28 M A M A M A M A 0.5 1/ha 4.0 8.8 2.5 1.3 0.2 0.8 0.5 6.5 3.3 16.0 0.6 I/ha 1,5 1.5 2.7 0.2 0 0.2 1.5 0.7 3.5 4.7 24.0 No phytotoxicity symptom has been noted in the above tests A to H.
Claims (16)
1. A method of combating insects in a locus which comprises applying to the locus, in admixture or separately, an insecticidally effective amount of
a) the compound of formula I
in association with
b) the compound of formula II
2. A method according to claim 1, wherein the weight ratio compound of formula I: compound of formula II is 0.5-1: 1-3.
3. A method according to claim 2, wherein the weight ratio compound of formula I: compound of formula 11 is 0.6-0.8: 1.5-2.5.
4. A method according to claim 3, wherein the weight ratio compound of formula I: compound of formula II is 0.72:2.
5. A method according to claim 1 to 4, wherein the compound of formula I and the compound of formula II are applied at a rate of 0.030-0.060 kg/ha and 0.060-0.180 kg/ha respectively.
6. A method according to claim 5, wherein the compound of formula I and the compound of formula II are applied at a rate of 0.035-0.045 kg/ha and 0.090-0.150 kg/ha respectively.
7. A method according to claim 6, wherein the compound of formula I and the compound of formula Il are applied at a rate of 0.432 kg/ha and 0.120 kg/ha respectively.
8. A method according to anyone of claims 1 to 7, wherein the locus is a potato, sunflower, pea, cereal, beet, hop, rape or market garden locus.
9. A method according to anyone of claims 1 to 8, wherein the insects are aphids.
10. A method according to claim 9, wherein the aphids are potato aphid, sunflower aphid, pea aphid, rape aphid, cereal aphid, beet aphid, hop aphid, bean aphid, green peach aphid or market garden aphid.
11. A method according to claim 10, wherein the aphids are bean aphid or green peach aphid.
12. An insecticidal composition comprising as active ingredients the compound of formula I and the compound of formula II as defined in claim 1.
13. A composition according to claim 12, wherein the weight ratio compound of formula I: compound of.formula II is 0.5-1: 1-3.
14. A composition according to claim 13, wherein the weight ratio compound of formula l: compound of formula II is 0.6-0.8: 1.5-2.5.
15. A composition according to claim 14, wherein the weight ratio compound of formula I: compound of formula II is 0.72:2.
16. A composition according to anyone of claims 12 to 15, containing from 0.1 to 90% of the compounds of formula I and II.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8506929A FR2581509B1 (en) | 1985-05-07 | 1985-05-07 | COMBINATION BASED ON FLUVALINATE AND THIOMETON, USEFUL FOR COMBATING INSECTS |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| GB8610791D0 GB8610791D0 (en) | 1986-06-11 |
| GB2174601A true GB2174601A (en) | 1986-11-12 |
| GB2174601B GB2174601B (en) | 1988-07-06 |
Family
ID=9319041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB08610791A Expired GB2174601B (en) | 1985-05-07 | 1986-05-02 | Improvements in or relating to insecticides |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS61268607A (en) |
| AU (1) | AU5710886A (en) |
| BE (1) | BE904659A (en) |
| FR (1) | FR2581509B1 (en) |
| GB (1) | GB2174601B (en) |
| GR (1) | GR861131B (en) |
| NL (1) | NL8601135A (en) |
| ZA (1) | ZA863432B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2032255A1 (en) * | 1989-10-06 | 1993-01-16 | Sumitomo Chemical Co | ACARICIDAL COMPOSITION. |
-
1985
- 1985-05-07 FR FR8506929A patent/FR2581509B1/en not_active Expired
-
1986
- 1986-04-23 BE BE1/011480A patent/BE904659A/en not_active IP Right Cessation
- 1986-04-29 GR GR861131A patent/GR861131B/en unknown
- 1986-05-02 GB GB08610791A patent/GB2174601B/en not_active Expired
- 1986-05-02 NL NL8601135A patent/NL8601135A/en not_active Application Discontinuation
- 1986-05-05 AU AU57108/86A patent/AU5710886A/en not_active Abandoned
- 1986-05-06 JP JP61104564A patent/JPS61268607A/en active Pending
- 1986-05-07 ZA ZA863432A patent/ZA863432B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2032255A1 (en) * | 1989-10-06 | 1993-01-16 | Sumitomo Chemical Co | ACARICIDAL COMPOSITION. |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA863432B (en) | 1987-12-30 |
| GB8610791D0 (en) | 1986-06-11 |
| AU5710886A (en) | 1986-11-13 |
| JPS61268607A (en) | 1986-11-28 |
| GB2174601B (en) | 1988-07-06 |
| FR2581509B1 (en) | 1988-09-09 |
| NL8601135A (en) | 1986-12-01 |
| GR861131B (en) | 1986-08-26 |
| BE904659A (en) | 1986-10-23 |
| FR2581509A1 (en) | 1986-11-14 |
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