GB2156394A - Improving adhesion of coatings to textile fabrics - Google Patents
Improving adhesion of coatings to textile fabrics Download PDFInfo
- Publication number
- GB2156394A GB2156394A GB08506613A GB8506613A GB2156394A GB 2156394 A GB2156394 A GB 2156394A GB 08506613 A GB08506613 A GB 08506613A GB 8506613 A GB8506613 A GB 8506613A GB 2156394 A GB2156394 A GB 2156394A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fabric
- carboxylic acid
- coating
- acid
- adhesion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 56
- 238000000576 coating method Methods 0.000 title claims abstract description 29
- 239000004753 textile Substances 0.000 title description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 22
- 229920002635 polyurethane Polymers 0.000 claims abstract description 9
- 239000004814 polyurethane Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 19
- 229920000642 polymer Polymers 0.000 claims description 18
- 150000001735 carboxylic acids Chemical class 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 9
- 229920002125 Sokalan® Polymers 0.000 claims description 8
- 239000004584 polyacrylic acid Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920002994 synthetic fiber Polymers 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000008199 coating composition Substances 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000004677 Nylon Substances 0.000 abstract description 11
- 229920001778 nylon Polymers 0.000 abstract description 11
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 5
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 5
- 150000002009 diols Chemical class 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229920001944 Plastisol Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000004999 plastisol Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 229920006397 acrylic thermoplastic Polymers 0.000 description 1
- WERYXYBDKMZEQL-CQDYUVAPSA-N butane-1,4-diol Chemical group O[13CH2]CC[13CH2]O WERYXYBDKMZEQL-CQDYUVAPSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides improved adhesion by treating the fabric, prior to coating, with a polymeric carboxylic acid which may react with the fabric. The coating may be of a polyurethane & the fabric be of nylon.
Description
SPECIFICATION
Adhesion of coatings to textile fabrics
This invention relates to the improvement of adhesion of coatings to textile fabrics.
It is now quite common practice to coat textile fabrics with a thin layer of plastics, for example in order to obtain a waterproof fabric suitable for making up into foul weather clothing. One of the problems with coatings applied to flexible substrates like textile fabric is in obtaining adequate adhesion between the coating and the textile fabric so that they do not separate when the fabric is flexed. The lack of adhesion can be particularly marked with synthetic fabrics for example of nylon.
The present invention has been made from a consideration of this problem.
According to one aspect of the invention there is provided a method for improving adhesion between a fabric and a coating comprising treating the fabric with a polymeric carboxylic acid prior to coating.
Preferably the fabric to be treated will be one made from synthetic fibres, such as polyamide, which will react, at least partially with the acid. It is known that certain acids will react with polyamide fabrics to stiffen the fabric but it was not appreciated that adhesion between the fabric and a coating could also be improved by such treatment.
The polymeric carboxylic acid that is applied is preferably one which will react with the fabric. Typical acids are homopolymers of unsaturated carboxylic acids such as polyacrylic acid, polymethacrylic acid, polyitaconic acid, and copolymers for example of an unsaturated carboxylic acid with an olefin or an unsaturated ether such as a copolymer of maleic acid with ethylene or with methyl vinyl ether.
The treatment of the fabric with the acid may be carried out at ambient or elevated temperature, for example by immersion of the fabric in a solution or dispersion of the acid. The treated fabric is dried followed by exposure to elevated temperature for example above 100 C but preferably not above the heat setting temperature and finally washed to remove unreacted acid.
The treated fabric can be coated with any suitable coating of for example plastics, natural or synthetic rubber or silicone. Typical coatings of plastics materials with which good adhesion can be obtained are polyurethanes, polyvinylchlorides and acrylics. Particularly good results can be obtained using polyurethanes of the kind described in our Patent Application No.8037510 (Serial No.2087909).
The adhesion between the coating and fabric treated in accordance with the invention is maintained or even improved when the fabric is wetted and re-dried.
In another aspect of the invention, a polymer coating is modified by incorporation of groups that promote adhesion to a fabric substrate. For example a polymer coating such as a polyurethane containing a proportion of carboxylic acid side-chains exhibits better adhesion to a nylon fabric than a polymer of similar structure not containing carboxylic acid side-chains. Furthermore, coatings such as polyurethane coatings, containing a plurality of basic groups also adhere better to nylon when the fabric is pretreated with polyacrylic acid. Dry adhesion of coatings actually increases if the coating fabrics are wetted with water and then redried.
The following Examples further illustrate the invention:
Example I
A nylon 6.6 fabric (120 g/m2) was treated with a solution of polyacrylic acid (0.075% w/v) and a nonionic surfactant (0.05% w/v), dried and cured simultaneously at 190"C for 150 sec. Any unbound polymer was then washed off with water. The treated fabric and an untreated control were then direct-coated (knife-on-roll) with some commercially available polyurethanes, together with a standard cross-linking agent (Imprafix TH). Peel strengths were then measured (BS 3424, Method 9).
Polyacrylic Coating Peel Strength (N/5 cm) acid treated Weight Dry Wet Water zglm2) t2% Na Soaked,
oleate) Redried
Impranil C No 25 39 34 39
Yes 31 100 59 91
Impranil CHW No 36 36 27
Yes 43 68 48 73
Witoflex 635 No 36 47 40
Yes 45 57 48
Example Il Improved adhesion has also been observed when carboxylic acid side-chains were introduced into a polyurethane used to coat unmodified nylon fabric. Thus, a control polymer was synthesised by the successive reaction of 4,4'-diisocyanato-dicyclohexylmethane (2.0 mol) with butane -1,4-diol (1.0 mol) and polycaprolactone diol (MW 1250) (1.0 mol); a second polymer was then prepared in which 0.25 mol of the butane -1,4-diol was replaced by 2,2-bis-hydroxy-methylpropionic acid.Both polymers plus a standard cross-linked agent (13% wlw), were then coated onto a filament-woven nylon fabric (120 gim2). The dry peel adhesion of the modified coating was 57N/5 cm compared with 40N/5 cm for the control polymer.
The same control and polyacrylic acid (PAA) treated (0.075 w/v bath) nylon fabrics as described in Example I were next coated with a group of polyurethanes based on a control polymer derived from isophorone diisocyanate (2 mol), butane -1,4-diol (1 mol), and polycaprolactone (MW 2000) (1 mol). In these polymers, the parent hard-segment diol was replaced by a basic diol, N-methyldiethanolamine (NMDEA) in progressively increasing amounts, as shown in the following Table. Each polymer, together with a standard cross-linking agent, was then coated (25-33 g/m2) on to the nylon fabrics and their dry and wet peel adhesion was measured.
Proportion of NMDEA (mol) Peel Adhesion .0 0.25 0.5 0.75 1.0 (N15 cm)
Control fabric
Dry 21 26 26 26 25
Wet (Na oleate) 20 29 27 28 23
Wet (water) 27 28 22 34 22
Redried - - 35 39 38
PAA-treated fabric
Dry 53 32 36 37 45
Wet (Na oleate) 61 50 38 37 35
Wet (water) 60 49 33 31 36
Redried - 58 43 43 88
Dry peel adhesion to the control fabric was not affected by changes in polymer composition. Aithough all the polymers adhered better to PAA-modified fabric than to untreated fabric, the effect was greatest with the unmodified polymer, i.e. containing no NMDEA. Wet peel adhesion in sodium oleate and in water was for the most part at least as good as dry peel adhesion, and on certain PAA-treated fabrics it was significantly better.When the water-wetted specimens were redried, dry peel adhesion was actually greater (ca. 100% in one example) than the original dry adhesion. It has been observed that the polymers containing NMDEA all had very good adhesion to glass, even when wetted. That may be because of polar interactions between basic centres in the polymer and the glass surface.
Example 111 Nylon fabric (120 g/m2) was treated with polyacrylic acid solution (0.1% w/v) and dried. The treated fabric was coated using a knife-on-roll with a medium viscosity unpigmented polyvinylchloride plastisol to a coating weight of 130 g/m2 and with a high viscosity, pigmented polyvinylchloride plastisol to a coating weight of 173 g/m2. The peel strength of the product was from 250 to 300% better than that of an untreated nylon fabric having the same coating whilst the tear strength was of the same order.
Claims (17)
1. A method for improving adhesion between a fabric and a coating composition comprising treating the fabric with a polymeric carboxylic acid.
2. A method as claimed in Claim 1, wherein the polymeric carboxylic acid is one that reacts with the fabric.
3. A method as claimed in Claim 1 or Claim 2, wherein the polymeric carboxylic acid is a homopolymer of an unsaturated carboxylic acid or a copolymer of an unsaturated carboxylic acid with an olefin or an unsaturated ether.
4. A method as claimed in Claim 3, wherein the carboxylic acid is polyacrylic acid, polymethacrylic acid, polyitaconic acid, a copolymer of ethylene and maleic acid or a copolymer of methyl vinyl ether and maleic acid.
5. A method as claimed in any preceding claim, wherein the fabric comprises synthetic fibres.
6. A method as claimed in any preceding claim, wherein the fabric is treated with the polymeric carboxylic acid at ambient temperature.
7. A method as claimed in any of Claims 1 to 5, wherein the fabric is treated with the polymeric carboxylic acid at elevated temperature.
8. A method as claimed in any preceding claim wherein the polymeric carboxylic acid is applied to the fabric in the form of a solution or dispersion.
9. A method as claimed in any preceding claim, wherein after treatment with the polymeric carboxylic acid and prior to coating the fabric is dried.
10. A method as claimed in Claim 9, wherin after treatment with the polymeric carboxylic acid and prior to coating the fabric is heated.
11. A method as claimed in any preceding claim, wherein the coating is of plastics material, rubber or silicone.
12. A method as claimed in Claim 11, wherein the coating is of polyurethane, polyvinylchloride or an acrylic based polymer.
13. A method as claimed in Claim 11 or Claim 12, wherein the coating material is a polymer having groups which promote adhesion to the fabric.
14. A method as claimed in Claim 13, wherein the coating material is a polyurethane having carboxylic acid side chains or a plurality of basic groups.
15. A method as claimed in any preceding claim, wherein the coated fabric is wetted and then dried.
16. A method for improving the adhesion between a fabric and a coating composition substantially as described herein with reference to any one of the Examples.
17. Coated fabric produced by the method as claimed in any preceding claim.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB848408024A GB8408024D0 (en) | 1984-03-28 | 1984-03-28 | Adhesion of coatings to textile fabrics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB8506613D0 GB8506613D0 (en) | 1985-04-17 |
| GB2156394A true GB2156394A (en) | 1985-10-09 |
Family
ID=10558808
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB848408024A Pending GB8408024D0 (en) | 1984-03-28 | 1984-03-28 | Adhesion of coatings to textile fabrics |
| GB08506613A Withdrawn GB2156394A (en) | 1984-03-28 | 1985-03-14 | Improving adhesion of coatings to textile fabrics |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB848408024A Pending GB8408024D0 (en) | 1984-03-28 | 1984-03-28 | Adhesion of coatings to textile fabrics |
Country Status (1)
| Country | Link |
|---|---|
| GB (2) | GB8408024D0 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4994225A (en) * | 1988-06-28 | 1991-02-19 | Uniroyal Plastics Company, Inc. | Production of passive restraint device |
| US5046759A (en) * | 1989-04-07 | 1991-09-10 | Uniroyal Plastics Co., Inc. | Braided fabric structure for seamless fabric confinements |
| US5076975A (en) * | 1988-06-28 | 1991-12-31 | Uniroyal Plastics Company, Inc. | Production of radiation cured elastomer coated passive restraint device |
| US10981403B2 (en) | 2017-07-06 | 2021-04-20 | Hewlett-Packard Development Company, L.P. | Fabric print media |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117587643B (en) * | 2023-12-06 | 2025-10-28 | 中纺新材料科技有限公司 | Seawater erosion-resistant fabric and preparation method thereof |
-
1984
- 1984-03-28 GB GB848408024A patent/GB8408024D0/en active Pending
-
1985
- 1985-03-14 GB GB08506613A patent/GB2156394A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4994225A (en) * | 1988-06-28 | 1991-02-19 | Uniroyal Plastics Company, Inc. | Production of passive restraint device |
| US5076975A (en) * | 1988-06-28 | 1991-12-31 | Uniroyal Plastics Company, Inc. | Production of radiation cured elastomer coated passive restraint device |
| US5046759A (en) * | 1989-04-07 | 1991-09-10 | Uniroyal Plastics Co., Inc. | Braided fabric structure for seamless fabric confinements |
| US10981403B2 (en) | 2017-07-06 | 2021-04-20 | Hewlett-Packard Development Company, L.P. | Fabric print media |
| US11260688B2 (en) | 2017-07-06 | 2022-03-01 | Hewlett-Packard Development Company, L.P. | Fabric print medium |
Also Published As
| Publication number | Publication date |
|---|---|
| GB8506613D0 (en) | 1985-04-17 |
| GB8408024D0 (en) | 1984-05-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4670330A (en) | Moisture-permeable, antistatic, and oil-resistant work gloves and production of the same | |
| EP0293482B1 (en) | Gas-permeable and waterproof nonwoven fabric and process for its production | |
| US3185582A (en) | Process for making and finishing artificial hides or leathers | |
| EP0225060B1 (en) | Waterproof fabric having high moisture permeability and method of making same | |
| DE69927185T2 (en) | WATER VAPOR PERMEABLE, WATERPROOF MATERIAL AND METHOD FOR THE PRODUCTION THEREOF | |
| GB2156394A (en) | Improving adhesion of coatings to textile fabrics | |
| US2924587A (en) | Polyisocyanate-hydroxy aliphatic hydrocarbon substituted siloxane coating composition | |
| US4601951A (en) | Impregnation of leather with polyurethane dispersions | |
| EP0289627B1 (en) | Gas-permeable waterproof membrane and process for its production | |
| US4073984A (en) | Method for imparting a lustrous top surface to artificial leather | |
| CN1279313A (en) | A kind of manufacture method of polyurethane synthetic leather | |
| CN118756499A (en) | Imitation leather sheet and production method thereof | |
| JPS62205181A (en) | Water and oil repellent agent | |
| JP3378153B2 (en) | Manufacturing method of artificial leather | |
| US3961107A (en) | Fiber fleece containing a polymeric reinforcing material, and process for the production of such fleece | |
| CA1175310A (en) | Impregnation of leather with polyurethane dispersions | |
| JPS6331589B2 (en) | ||
| JPH0365823B2 (en) | ||
| KR19980028821A (en) | Manufacturing method of waterproof waterproof coating fabric | |
| EP0111132A2 (en) | Method and apparatus for preparing artificial hide or hide backing and the hide or hide backing thus obtained | |
| JPS599672B2 (en) | Artificial leather surface coating modifier | |
| JPH0268366A (en) | Coated cloth of dry touch | |
| KR910003715B1 (en) | Polyurethane film with permeability and process for preparation thereof | |
| JPS6163778A (en) | Production of hygroscopic water-proof cloth | |
| JPH01272870A (en) | Production of antimicrobial moisture-permeable and waterproof fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |