GB2037832A - Fire-retardant Composition and Method of Rendering Cellulosic Materials Fire-retardant - Google Patents
Fire-retardant Composition and Method of Rendering Cellulosic Materials Fire-retardant Download PDFInfo
- Publication number
- GB2037832A GB2037832A GB7849051A GB7849051A GB2037832A GB 2037832 A GB2037832 A GB 2037832A GB 7849051 A GB7849051 A GB 7849051A GB 7849051 A GB7849051 A GB 7849051A GB 2037832 A GB2037832 A GB 2037832A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition
- fire
- retardant
- weight
- cellulosic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 75
- 239000003063 flame retardant Substances 0.000 title claims abstract description 41
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 7
- 238000009877 rendering Methods 0.000 title claims description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004327 boric acid Substances 0.000 claims abstract description 23
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 21
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 21
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000011777 magnesium Substances 0.000 claims abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011575 calcium Substances 0.000 claims abstract description 6
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical class [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000470 constituent Substances 0.000 claims abstract 3
- 238000009413 insulation Methods 0.000 claims description 25
- 239000004615 ingredient Substances 0.000 claims description 9
- 238000005260 corrosion Methods 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 239000010893 paper waste Substances 0.000 claims description 6
- 229920000742 Cotton Polymers 0.000 claims description 5
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical class [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 239000000047 product Substances 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000011068 loading method Methods 0.000 description 14
- 238000012360 testing method Methods 0.000 description 12
- 238000007792 addition Methods 0.000 description 9
- 239000012774 insulation material Substances 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000005696 Diammonium phosphate Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 1
- 235000019838 diammonium phosphate Nutrition 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 238000007706 flame test Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000002803 maceration Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000019837 monoammonium phosphate Nutrition 0.000 description 1
- 239000006012 monoammonium phosphate Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Fireproofing Substances (AREA)
Abstract
The fire-retardant composition of United States Patent No. 3,983,040 is improved to a surprising extent by the addition thereto of from about 10% to about 40% by weight of ammonium sulfate. In producing the improved composition, the patented composition is first made by reacting a pulverized borate ore selected from the group consisting of calcium, sodium, magnesium, and potassium borates and mixtures thereof, with sulfuric acid and water for a time sufficient to produce a substantially dry reaction product containing a boric acid constituent and a sulfate constituent. After drying, the reaction product is pulverized and the ammonium sulfate, also in pulverized condition, is intimately mixed therewith, or the two may be pulverized together to produce the final improved product. Cellulosic material is rendered fire-retardant by application of the product thereto.
Description
SPECIFICATION
Fire-retardant Composition and Method of
Rendering Cellulosic Materials Fire-retardant
The invention is in the field of fire-retardant compositions, of matter, particularly though not exclusively those useful for treating cellulosic materials such as cotton batting and ground waste paper insulation.
Boric acid in powder form has long been used as a fire retardant for cellulosic materials of the type with which this invention is particularly concerned. My prior invention disclosed by U.S.
Patent No. 3,983,040 as issued September 28, 1976, under the title "Fire-Retardant Composition and Process of Producing Same", provided an effective and relatively economical substitute for the boric acid previously employed, although only about 80% as effective by weight. The fireretardant composition of that invention comprises a particulate reaction product of a borate ore and sulfuric acid, the ore having been selected from the group consisting of calcium, sodium, magnesium, and potassium borates, and mixtures thereof. The reaction product contains boric acid and a significant quantity of one or more sulfates selected from the group consisting of calcium, sodium, magnesium, and potassium sulfates. The ore is preferably finely ground prior to the application thereto of the acid, and water is added during mixing of the ore and acid.Heat produced exothermically during the mixing aids in drying the reaction product, whereupon it is pulverized to a fine powder ready for use.
In the making of the present invention, an objective was to increase the fire-retardant effectiveness of my previous composition to substantially that of boric acid.
In accordance with one aspect of the present invention, there is provided a fire-retardant composition of matter for cellulosic material, comprising a mixture containing, as the principal ingredient, a reaction product of sulfuric acid and a borate ore, the latter being selected from the group consisting of calcium, sodium, magnesium, and potassium borates and mixtures thereof, said reaction product containing boric acid and a significant quantity of one or more sulfates selected from the group consisting of calcium, sodium, magnesium, and potassium sulfates; and, as a relatively minor ingredient, an effective amount of ammonium sulfate to render the composition substantially at least as effective a fire-retardant for cellulosic materials as is solely boric acid.
In accordance with a further aspect of the present invention, there is provided a method of rendering cellulosic materials fire-retardant, comprising applying to said materials fireretardant composition according to any of claims 1 to 7 in quantities of from about 15% to about 30% by weight.
The reaction product of my aforesaid U.S.
Patent No. 3,983,040 is further processed by the addition thereto of from about 10% to about 40% by weight of ammonium sulfate. These ingredients may be ground to pulverized condition, either separately or together. If separately, they are intimately mixed thereafter to provide a dry powder, which constitutes the improved fire-retardant composition of this invention.
Although ammonium sulfate, by itself, is not a very effective flame retardant and has been used in the past as a diluent for various flame-retardant
compositions, I have found that there is a pronounced and advantageous synergistic reaction with the composition of my previous invention, which renders the resultant composition surprisingly more effective against both flame spread and smoulder. Thus, whereas my previous composition is approximately 80% as effective as boric acid for the same weight applied to a cellulosic material to be rendered fireretardant, my present composition is rendered fully comparable to boric acid in effectiveness on an equivalent weight basis and even superior thereto at elevated temperatures, e.g. 1400 F, as well as in the lower ranges of loading of insulation therewith.
That this is truly remarkable is shown by the fact that the addition of the same amount (e.g.
20% by weight) of pure boric acid to my previous composition yields only a small increase in flame retardancy and that a similar addition of ammonium phosphate (considered in the art as an extremely good flame retardant alone or in combination) actually has a negative effect on my previous composition.
Moreover, ammonium sulfate by itself is known to be conducive to severe smouldering, while boric acid is known to greatly inhibit smouldering.
Although the addition of ammonium sulfate to my previously patented composition in quantity of from about 10% to about 40% by weight is effective to prevent or greatly inhibit smouldering, it is preferred to utilize from about 1 5% to about 25%. When the addition is below about 10%, the effect is insufficient to warrant the addition, and, although smouldering is inhibited up to an ammonium sulfate content of 40%, above a 40% content smouldering increases and is severe at a content of about 50% when used at a loading of 20% by weight with the cellulosic insulation material to be made fire retardant.
The composition thus far described is corrosive, which may be undesirable in many instances. Accordingly, it is wise to exercise pH control to reduce acidity to or about neutral or to even adjust the pH slightly on the alkaline side by appropriate additions of an alkaline material, such as lime, borax, calcium carbonate, etc. Also, it may be desirable to add a corrosion inhibitor, which may be of one or more known types for particular metals concerned, e.g. a sodium siiicate, which will inhibit corrosion of steel, aluminium, and copper. Various other corrosion inhibitors are known and can be used along or in combination, without detriment to the
composition of the invention since the inhibitors
are employed only in relatively small quantities.
Loading of the cellulosic material to be made fire-retardant will vary in accordance with code
requirements in given areas of use. Normally,
loading of cotton batting is about 10% by weight
and loading of ground waste paper insulation is from about 15% to 30% by weight. It should be
borne in mind that high loadings are undesirable,
in that they increase density of the insulation
material to which the fire-retardant composition
is applied and reduce its insulating properties.
Unfortunately, flame retardants do not behave in a linear manner. Diminishing returns are experienced the more that is used, so that a composition of low effectiveness must be used in undesirable quantities to satisfy code requirements. It can be recognized, therefore, that the more effective the composition, the less loading required and the better the final insulation product. Thus, the importance of the present invention.
Typical examples follow.
Example 1
A sample of the fire-retardant composition of this invention was produced by first preparing a composition in accordance with my aforereferred-to U.S. Patent No. 3,983,040, wherein the reaction product was shown to contain 40% boric acid. This composition was ground to minus 200 mesh, U.S. standard sieve, and was intimately mixed with sufficient minus 200 mesh ammonium sulfate to produce a final composition containing 80% by weight of the previously patented composition and 20% by weight of the ammonium sulfate.
When tested for both flame spread and smoulder at ambient temperature of 720F. in comparison with powdered boric acid, both being applied to equivalent samples of ground waste paper insulation at respective loadings of 25% by weight, the results were identical.
Example 2
Similar comparative tests were carried out employing a similar fire-retardant composition of the invention in which the reaction product of the patent was ground with crystalline ammonium sulfate to yield a minus 200 mesh powder. The loadings for the respective tests were 20% by weight of the insulation material. Smoulder resistance was found to be equal, but resistance to flame spread was superior for the composition of the invention to that obtained by the use of boric acid.
Example 3
In comparative tests similar to those of
Example 1 in which the composition of the invention contained 30% by weight of ammonium sulfate and its loading on the insulation was 20% by weight in comparison with a 25% by weight loading of the boric acid, resistance to flame spread for the composition of the invention was superior to that for the boric acid and smoulder resistance was about equal.
Example 4
When the composition of the invention was prepared as in Example 1, but utilizing enough of the ammonium sulfate to constitute 50% by weight and at a loading of 20% by weight on the insulation material, resistance to flame spread was very good, but smoulder was so bad that the insulation was consumed.
Example 5
A sample of a fire-retardant composition was prepared as in Example 1, but using, instead of ammonium sulfate, the same amount of boric acid as an additive. The total boric acid content was therefore 60%, rather than the 40% of
Example 1. This composition was loaded on insulation material to the extent of 25% by weight and was tested in comparison with a similar loading of the fire-retardant composition of the present invention prepared as in Example 1. Both tests showed good smoulder resistance, but the one utilizing the composition of this invention showed superior flame spread resistance. It was noted that the addition of boric acid to the composition of my aforesaid patent resulted in only a slight improvement in the performance of that composition.
All of the above tests for flame spread were carried out on a loose fill basis involving maceration and mixing of the insulation in a "Waring" biender and application thereof, by random scattering, onto a wire rack fabricated from 1/2 inch hardware cloth and measuring 5"x 14", with spikes of wire rising vertically therefrom and a flange of the same hardware cloth near one end to hold a one to two-inch depth of the fluffed insulation when the filled rack was inclined at an angle of 45 to increase the possibility of flame spread. With the rack so inclined, the flame from a Bunsen burner was applied at the lowest portion of the insulation, as well as at several locations upwardly therefrom.
The tendency to spread flame was noted at each point of application of the flame.
The smoulder tests were performed separately.
For each test, twenty grams of the fire-retardant insulation were placed in a long rectangular form to a density of three Ibs. per cu. ft. The resulting brick of insulation was then removed and placed on the same wire rack on which the flame tests were performed. The flame from a Bunsen burner was applied to the lower top edge of the block for a period of thirty seconds. At the end of this time, the flame was removed and smouldering was timed by a stop-watch. Insulation in which smouldering ceased immediately was termed "good". Otherwise, the insulation was graded at fifteen second intervals up to the extinguishing point. If smouldering continued beyond one minute, the insulation would usually be consumed and would be considered to have failed.
The following tests are examples of failure:
Example 6
A sample of a fire-retardant composition was prepared as in Example 1, but utilizing powdered diammonium phosphate as an addition in place of powdered ammonium sulfate. The composition was incorporated in insulation and tested as in
Example 1, but failed both flame spread and smoulder tests. Such insulation would be hazardous.
Example 7
A sample of a fire-retardant composition, again prepared us in Example 1 but utilizing powdered mono-ammonium phosphate in place of the ammonium sulfate, was incorporated in insulation and tested as in Example 1. The insulation failed both flame spread and smoulder tests. Such insulation would be hazardous.
Testing of insulation is usually done at ambient temperature of about 720F. and relative humidity of 40%. However, this is not realistic for
cellulosic insulation blown into the attics of homes. Such attics can become extremely hot on summer afternoons in temperate climates and
remain at elevated temperatures of 130 to 1400 F.
and higher for a number of hours. Due to
moisture equilibrium of cellulose fibres, such fibres tend to lose moisture at these higher temperatures and are more susceptible to flame spread.
We therefore conducted a test as follows:
Example 8
A composition sample in accordance with the invention was prepared and incorporated into a sample of insulation as in Example 1, but at a loading of 30%. It and a corresponding sample of insulation incorporating only boric acid were then kept for a period of two hours in an environment that was maintained at 1300 F. They were then tested for flame spread. The sample containing only powdered boric acid was on the borderline of failure. The sample containing the composition of the present invention showed excellent resistance to flame spread.
A typical formulation for the composition of the
present invention is as follows:
Ingredient Weight in Ibs
Composition of Draganov U.S.
Patent No.3,983,040 1,413
Ammonium Sulfate 400
Hydrated Lime 174
Corrosion Inhibitors 13
- Total 2,000
In rendering cellulosic material fire-retardant,
the dry powder composition is applied by dusting
thereonto, as with cotton batting, or by mixing
intimately therewith, as with ground waste paper
insulation material that is normally installed by
blowing into attics, between interior and exterior
walls, etc.
Whereas specific examples are set forth herein in describing the invention, it should be understood that the invention is not limited thereto and that changes may be made within the scope of the generic teachings hereof and the claims that follow.
Claims (12)
1. A fire-retardant composition of matter for cellulosic material, comprising a mixture containing, as the principal ingredient, a reaction product of sulfuric acid and a borate ore, the latter being selected from the group consisting of calcium, sodium, magnesium, and potassium borates and mixtures thereof, said reaction product containing boric acid and a significant quantity of one or more sulfates selected from the group consisting of calcuim, sodium, magnesium, and potassium sulfates; and, as a relatively minor ingredient, an effective amount of ammonium sulfate to render the composition substantially at least as effective a fire-retardant for cellulosic materials as is solely boric acid.
2. A composition according to claim 1, wherein an alkaline material is included as another relatively minor ingredient in intimate association with the other ingredients to render the composition substantially neutral in pH.
3. A composition according to claim 2, wherein one or more corrosion inhibitors are intimately mixed with the other ingredients as minor constituents of the composition.
4. A composition according to claim 1, wherein the reaction product is present from about 90% to about 60% by weight of the composition, and the ammonium sulfate is present from about 10% to about 40% by weight of the composition.
5. A composition according to claim 1, wherein the reaction product is present from about 85% tr, about 75% by weight of the composition, and the ammonium sulfate is present from about 1 5% to about 30% by weight of the composition.
6. A composition according to claim 1, wherein for every 2000 pounds of the composition of matter, there are about 1,413 pounds of the reaction product, about 400 pounds of the ammonium sulfate, about 174 pounds of hydrated lime, and about 13 pounds of corrosion inhibitors.
7. A fire-retardant composition of matter for cellulosic material, substantially as hereinbefore described.
8. A fire-retardant cellulosic material, comprising cellulosic material treated with the fire-retardant composition of matter of any preceding claim.
9. A material according to claim 8, wherein the cellulosic material is finely divided waste paper intimately mixed with the fire-retardant composition of matter.
10. A material according to claim 8, wherein the cellulosic material is cotton batting.
11. A method of rendering cellulosic materials fire-retardant, comprising applying to said materials fire-retardant composition according to any of claims 1 to 7 in quantities of from about 15% to about 30% by weight.
12. A method according to claim 11, wherein the cellulosic material is cotton batting or ground waste paper insulation.
1 3. A method of rendering cellulosic material fire-retardant, substantially as hereinbefore described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7849051A GB2037832A (en) | 1978-12-19 | 1978-12-19 | Fire-retardant Composition and Method of Rendering Cellulosic Materials Fire-retardant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB7849051A GB2037832A (en) | 1978-12-19 | 1978-12-19 | Fire-retardant Composition and Method of Rendering Cellulosic Materials Fire-retardant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB2037832A true GB2037832A (en) | 1980-07-16 |
Family
ID=10501807
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7849051A Pending GB2037832A (en) | 1978-12-19 | 1978-12-19 | Fire-retardant Composition and Method of Rendering Cellulosic Materials Fire-retardant |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB2037832A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3147601A1 (en) * | 1980-12-08 | 1982-08-12 | United States Borax & Chemical Corp., Los Angeles, Calif. | FIRE DELAY ADDITIVE AND RESIN PRODUCTS CONTAINING THEM |
-
1978
- 1978-12-19 GB GB7849051A patent/GB2037832A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3147601A1 (en) * | 1980-12-08 | 1982-08-12 | United States Borax & Chemical Corp., Los Angeles, Calif. | FIRE DELAY ADDITIVE AND RESIN PRODUCTS CONTAINING THEM |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4184969A (en) | Fire- and flame-retardant composition | |
| US4168175A (en) | Fire retardant compositions | |
| US6306317B1 (en) | Phosphate free fire retardant composition | |
| US5151225A (en) | Flame retardant composition and method for treating wood | |
| CA1224579A (en) | Intumescent material | |
| US4374171A (en) | Smolder and flame resistant insulation materials, composition and method | |
| US6309746B1 (en) | Halogen-free fire-retarding composition, yarn fire-retarded with the latter and fire-resistant textile structure comprising such yarns | |
| US4132655A (en) | Fire-retardant composition and method of rendering cellulosic materials fire-retardant | |
| US4725382A (en) | Fire retardant composition | |
| US4065413A (en) | Fire resistance wood-based boards, process for producing same and compositions useful therefor | |
| US4126473A (en) | Flame retarding compositions for cellulosic boards | |
| CN103717709A (en) | Fire retardant composition and method for treating wood | |
| CA1247807A (en) | Fibre board, a method for making it, and a binder composition | |
| US6660190B2 (en) | Fire and flame retardant material | |
| US4292188A (en) | Non-abrasive bauxite-based fire retardant | |
| US6107242A (en) | Absorbent material including coir fibres and/or coir dust | |
| GB2037832A (en) | Fire-retardant Composition and Method of Rendering Cellulosic Materials Fire-retardant | |
| RU2224775C1 (en) | Fire-proof swelling paint | |
| US10767306B2 (en) | Water based liquid fire retardant for use in cellulose insulation | |
| US6894099B2 (en) | Stabilized borax based fire retardant system | |
| US4351669A (en) | Impregnating composition, a process for its preparation and products prepared by using the composition | |
| US4302345A (en) | Flame retarding cellulosic materials with sodium or potassium thiocyanate | |
| CN102773894A (en) | Environment-friendly flame-retardant liquid for flame retarding of wood and preparation method for environment-friendly flame-retardant liquid | |
| KR101989968B1 (en) | Fire retardant composition and its manufacturing method | |
| US5455065A (en) | Treatment for improving cellulosic insulation |