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GB2023782A - Coal gasifier systems - Google Patents

Coal gasifier systems Download PDF

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Publication number
GB2023782A
GB2023782A GB7907263A GB7907263A GB2023782A GB 2023782 A GB2023782 A GB 2023782A GB 7907263 A GB7907263 A GB 7907263A GB 7907263 A GB7907263 A GB 7907263A GB 2023782 A GB2023782 A GB 2023782A
Authority
GB
United Kingdom
Prior art keywords
lockhopper
separator
gas
gasifier
coal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB7907263A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of GB2023782A publication Critical patent/GB2023782A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/30Fuel charging devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/723Controlling or regulating the gasification process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/78High-pressure apparatus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845Quench rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

An apparatus for handling lock gas which enters a charging lockhopper (12) from a fixed bed coal gasifier vessel (10), after the charging of the gasifier vessel with coal, includes a separator (36) having a fluid inlet (38), a gas outlet (42) and a drain (44). After a charging operation, a pump (56) floods the lockhopper (12) with water under pressure to force the lock gas through the fluid inlet (38) to the separator (36) without loss of gas pressure. When rising water is sensed (at 48) in the separator, the pump (56) is deactivated and drain valves (30, 46) are opened to drain water from the separator and lockhopper back into a storage tank (52). The lock gas leaves the separator under pressure and may be applied to gas cleanup equipment. <IMAGE>

Description

SPECIFICATION System and method for handling lock gas in a coal gasifier system The present invention relates to coal gasification and more particularly to an improved method and system for handling lock gas generated during operation of a coal gasifier.
In the fixed bed coal gasification process, coal is loaded or charged into the gasifier vessel at its upper end. Each new charge lands on previously-deposited charges. Steam and an oxidizing gas are admitted at the lower end of the gasifier vessel. Combustion occurring near the bottom of the gasifier vessel consumes some of the coal while the rest of the coal is gasified to yield raw gas.
In one type of fixed bed coal gasification process, a relatively constant superatmospheric pressure is maintained in the gasifier vessel. In a pressurized gasifier system, coal may be introduced into the gasifier by means of a charging lock or lockhooper arrangement.
A quantity or charge of coal is loaded into the lockhopper at atmospheric pressure while the lockhopper is sealed from the gasifier vessel.
After the lockhopper is fully loaded, the lockhopper internal pressure is elevated by a high pressure filling gas until it is on the order of or slightly greater than the gasifier vessel interior pressure. A coal carrying filling tube between the lower end of the lockhopper and the upper end of the gasifier vessel is then opened to allow the coal to be charged into the vessel.
As the coal is introduced into the gasifier vessel through the filling tube, gas generated within the vessel rises through the filling tube into the lockhopper. This gas is generally referred to as lock gas although its chemical composition is substantially the same as the raw gas which the gasifier vessel is intended to produce.
Since the lockhopper has to be at atmospheric pressure before coal can be loaded into it, the accumulated lock gas must be disposed of before the next loading operation.
The simplest way to disposed of lock gas is to exhaust it into the atmosphere as the lockhopper is being depressurized. This method, while simple, is unacceptable for at least two reasons. First, the lock gas contains elements such as sulphur compounds which would contribute to atmospheric polution if exhausted without treatment. Second, since the lock gas has substantially the same composition as any gas generated within the gasifier vessel, simply exhausting it into atmosphere is a complete waste of its energy potential.
It has been suggested that lock gas might be used as an incinerator fuel. However, there is concern that burning untreated lock gas might contribute to atmospheric pollution.
Moreover, the pressure of lock gas exhausted from the lockhopper during depressurization fluctuates widely and non-uniformly. Additionally, each gasifier has its own gas generating characteristics. This lack of uniformity among gasifiers, which may have a common lock gas handling system, and the widely fluctuating lock gas pressure from any one gasifier further tend to discourage use of lock gas an an incinerator fuel.
It has also been suggested that expanded or low pressure lock gas might be re-compressed and applied to gas cleanup equipment along with raw gas generated in the gasifier vessel.
However, since the pressure of expanded lock gas is on the order of atmospheric pressure or 14.7 pounds per square inch while the raw gas pressure is on the order of 330 pounds per square inch, a considerable amount of energy must be expended in re-compressing the lock gas. This reduces the overall efficiency of the coal gasification process.
The present invention is a system and method for removing lock gas from the lockhopper without substantial loss of gas pressure.
A lock gas handling system constructed in accordance with the present invention is intended to be used in a coal gasifier system of the type having a gasifier vessel, a lockhopper for receiving coal to be charged into the gasifier and means for pressurizing the lockhopper prior to charging. The lock gas handling system includes a separator having a controllable fluid inlet from the lockhopper, a controllable fluid drain and a gas outlet. A liquid storage tank is connected to the lockhopper. Liquid can be pumped from the reservoir into the lockhopper at the conclusion of a charging operation to force lock gas through the separator to the gas outlet under pressure.
The system further includes means responsive to the presence of liquid in the separator to terminate the pumping operation and to open the controllable fluid drain. Both the lockhopper and the separator are drained of liquid before more coal is loaded into the lockhopper.
While the specification concludes with claims particularly pointing out and distinctly claiming that which is regarded as the present invention, further details of a preferred embodiment of the invention may be more readily ascertained from the following detailed description when read in conjunction with the accompanying schematic drawing of a coal gasifier system including apparatus embodying the present invention.
Referring to the drawing, a fixed bed gasifier vessel 10 receives coal through a charging arrangement which includes a lockhopper 12, and other components described later. Ash resulting from burning of this coal vessel is discharged from the gasifier vessel 10 through a second ash lockhopper 1 8 connected to the bottom of the vessel 10 through a valve 20. A second valve 22 is located in a discharge tube from the ash lockhopper 1 8.
To maintain vessel pressure when disposing of ash, one of the valves 20 and 22 is always closed. More specifically, if valve 22 is opened to discharge accumulated ash from the lockhopper 1 8, then valve 20 remains closed. If valve 20 is opened to allow more ash to enter the lockhopper 1 8 from the vessel 10, then valve 22 remains closed.
Steam and an oxidizing gas, such as air or oxygen, is applied to the vessel 10 through an inlet pipe 24 which enters the vessel 10 at the bottom wall.
Gas generated during operation of the gasifier vessel, referred to as raw gas, is quenched with water in a quenching chamber 26 before being applied to gas cleanup equipment through an outlet conduit 28.
In addition to lockhopper 12, the charging apparatus includes an inlet valve 30, an outlet valve 1 2 and a filler tube 1 6 leading into the gasifier vessel 10. Like the corresponding valves of the ash lockhopper, at least one of the valves 14 and 30 is always closed to avoid loss of pressurization within the gasifier vessel 10. More specfically, when valve 30 is opened to admit more coal to the lockhopper 12, valve 14 remains closed. Conversely, if valve 14 is opened to charge coal from the lockhopper 1 2 into the gasifier vessel 10, then valve 30 remains closed.
When coal is being loaded into lockhopper 1 2 through open valve 30, the interior of the lockhopper is at atmospheric pressure or 14.7 punds per square inch. The gasifier vessel 10 on the other hand operates at a superatmospheric pressure, which, in one embodiment of the invention, may be on the order of 330 pounds per square inch. In order to charge coal into gasifier vessel 10, the lockhopper 1 2 is pressurized prior to charging by means of a filling gas provided from a source 32 through a valve 34. The filling gas elevates the pressure within the lockhopper 1 2 to a level equal to or slightly greater than the operating pressure of the gasifier vessel 1 0.It is necessary, of course, that all inlet and outlet connections to lockhopper 12, other than the connection to filling gas source 32, be closed at the time of pressurization.
When pressurization is complete, valve 34 is closed to disconnect the filling gas source 32. Valve 14 is opened to allow coal in the pressurized lockhopper 1 2 to be introduced into the vessel 10 through tube 1 6. As the coal enters the vessel 10, a raw gas rises through tube 1 6 and valve 14 causing the lockhopper 12 to be charged with lock gas at a pressure on the order of the pressure within the gasifier vessel 10.
The accumulated lock gas is removed from the system without significant loss in gas pressure by the operation of the apparatus described below.
The apparatus includes a gas separator 36 having a fluid inlet line 38 with a valve 40, a gas outlet line 42 preferably connected to gas cieanup equipment (not shown) and a drain line 44 which may be selectively connected to the interior of lockhopper 1 2 through a valve 46. A valve 47 is located in the outlet line 42. The separator 36 includes a liquid level detector 48 located near the bottom wall of the separator chamber. The detector 48 may be connected to a valve controller unit 50 which would basically be an event-triggered timing circuit for controlling the various valves in the lock gas handling system in a manner to be described below.
The apparatus further includes a storage tank 52 for a pressurizing liquid, preferably water. The tank 52 has an outlet 54 to a pump 56, the discharge side of which is connected to a valve 58. The tank 52 further includes a drain inlet 60 having a valve 62. A single pipe 64 is connected between one side of each of the valves 58 and 62 and the lower end of the lockhopper 1 2.
The operation of the lock gas handling system during a complete charging cycle is described below. For purposes of illustration, it is assumed that the cycle begins with lockhopper 1 2 at atmospheric pressure and only valve 30 open. Pump 56 is inoperable.
After the lockhopper 1 2 has been filled with coal admitted through the open valve 30, valve 30 is closed and valve 34 is opened to admit pressurizing gas from source 32 into the lockhopper 1 2. When the pressure within the lockhopper 1 2 has been raised to a level equal to or slightly greater than the pressure within the gasifying vessel 10, valve 34 is closed and valve 14 is opened to allow coal to be introduced into the vessel 10. When lockhopper 1 2 has been emptied of its charge of coal, valve 1 4 is closed with a quantity of lock gas being trapped in the lockhopper 1 2.
To remove this lock gas from the system without loss in gas pressure, valve 40 and 58 are opened and pump 56 is activated to force water from the tank 52 through valve 58 and pipe 64 into the lockhopper 1 2. The rising water in lockhopper 1 2 forces the lock gas through the open valve 40 into the separator 36. The pump 56 continues to operate until rising water in lockhopper 1 2 enters the separator 36 through valve 40 and is detected by the liquid level detector 48. When liquid is detected in the separator 36, a signal is applied to valve controller 50 which causes valve 58 to close and pump 56 to be deactivated. Valve 47 is closed, and valves 30 and 46 are opened to drain any accumulated water in separator 36 back into lockhopper 1 2. Valve 62 is also opened to allow any water within lockhopper 12 to be drained back into the tank 52 through the inlet 60.
When the water has been drained from lockhopper 12, valves 40, 46, and 62 are closed.
The lockhopper is ready for another load of coal.
Since the lockhopper 1 2 is substantially purged of lock gas by the system described above, no significant amount of lock gas leaves the system in the course of depressurization.
Tank 52 is shown with a gas stack 66 through which collected flash gas can be applied to an incinerator or other suitable device.
A single water tank may serve more than one coal gasifier system. For example, a second pump 68, an outlet valve 70 and an inlet valve 72 are illustrated for use in handling lock gas in a second system (not shown).
These components would be operated independently of pump 56 and valves 58 and 62 to supply water through a supply pipe 74 to the second coal gasifier system.

Claims (14)

1. A coal gasifier system having a gasifier vessel, a lockhopper for receiving coal to be charged into the gasifier and means for increasing the lockhopper pressure to substantially the gasifier pressure, including a separator having a fluid inlet from the lockhopper and a gas outlet; and means for maintaining the lock gas pressure at substantially the gasifier pressure level as the lock gas is exhausted from the lockhopper into the separator at the end of a charging operation.
2. A coal gasifier system as claimed in claim 1 including apparatus for recovering lock gas which enters the lockhopper from the gasifier vessel during charging, said apparatus comprising a separator having a fluid inlet from said lockhopper and a gas outlet; and means for flooding said lockhopper with liquid under pressure after a charging operation to force the lock gas through said separator without substantial loss of gas pressure.
3. A coal gasifier system as claimed in claim 1 including means for pressurizing the lockhopper prior to charging, and apparatus for handling lock gas which enters the lockhopper from the gasifier vessel during charging, said apparatus comprising a separator having a controllable fluid inlet from said lockhopper, a controllable fluid drain and a gas outlet; a liquid storage tank; pumping means operable at the conclusion of a charging operation for forcing liquid from said storage tank into said lockhopper to drive lock gas through said separator to said gas outlet under pressure; and means responsive to the presence of liquid in said separator to deactivate said pumping means and to open said controllable fluid drain in said separator.
4. Apparatus as claimed in claim 3 wherein said fluid drain communicates with said storage tank so that liquid drained from said separator is returned to said tank.
5. Apparatus as claimed in claim 3 wherein said fluid drain is connected to the interior of the lockhopper.
6. Apparatus as claimed in any one of claims 3 to 5 wherein said pumping means includes a pump having an inlet side for receiving a liquid from said storage tank and a discharge side; a first valve connected in a fluid line on the discharge side of said pump; a second valve connected in a fluid return line to said storage tank; and a common fluid line connecting one side of each of said first and second valves to said lockhopper.
7. Apparatus as claimed in claim 6 further including at least one additional means connected to said storage tank.
8. A method of recovering lock gas for use in a coal gasifier system having a gasifier vessel, a lockhopper for receiving coal to be charged into the gasifier vessel, means, for pressurizing the lockhopper prior to charging, a separator selectively connected to the lockhopper and a liquid storage tank, the method comprising recovering the lock gas which enters the lockhopper from the gasifier vessel during charging, by the steps including connecting the separator to the lockhopper at the end of a charging operation; and flooding the lockhopper with liquid from the storage tank under pressure to force the lock gas from the lockhopper through the separator at substantially the extant pressure within the gasifier vessel.
9. A method as claimed in claim 8 including the additional steps of terminating the flooding operation upon the detection of flooding liquid in the separator, and draining the flooding liquid from the separator and the lockhopper before more coal is loaded into the lockhopper.
10. A method as claimed in claim 9 wherein the flooding liquid is returned to the liquid storage tank during draining step.
11. A coal gasified system as claimed in claim 1 substantially as hereinbefore described with referenced to and as illustrated in the accompanying drawings.
1 2. A method of recovering lock gas as claimed in claim 8 substantially as hereinbefore described with reference to and as illustrated in the accompanying drawings.
1 3. Lock gas when recovered by the apparatus as claimed in any one of claims 1 to 7 and 11.
14. Lock gas when recovered by the method as claimed in any one of claims 8 to 10 and 12.
GB7907263A 1978-05-10 1979-03-01 Coal gasifier systems Withdrawn GB2023782A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US90460478A 1978-05-10 1978-05-10

Publications (1)

Publication Number Publication Date
GB2023782A true GB2023782A (en) 1980-01-03

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ID=25419426

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7907263A Withdrawn GB2023782A (en) 1978-05-10 1979-03-01 Coal gasifier systems

Country Status (3)

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JP (1) JPS54163903A (en)
DE (1) DE2918189A1 (en)
GB (1) GB2023782A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012104866B4 (en) * 2012-06-05 2014-10-30 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method for operating a bulk material lock device
CN103666580B (en) * 2013-11-29 2015-07-22 武汉凯迪工程技术研究总院有限公司 Coupled biomass pressurized pyrolysis process and system

Also Published As

Publication number Publication date
JPS54163903A (en) 1979-12-27
DE2918189A1 (en) 1979-11-15

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