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GB2018249A - Urea synthesis - Google Patents

Urea synthesis

Info

Publication number
GB2018249A
GB2018249A GB7909086A GB7909086A GB2018249A GB 2018249 A GB2018249 A GB 2018249A GB 7909086 A GB7909086 A GB 7909086A GB 7909086 A GB7909086 A GB 7909086A GB 2018249 A GB2018249 A GB 2018249A
Authority
GB
United Kingdom
Prior art keywords
solution
carbamate
urea
ammonia
passed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7909086A
Other versions
GB2018249B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of GB2018249A publication Critical patent/GB2018249A/en
Application granted granted Critical
Publication of GB2018249B publication Critical patent/GB2018249B/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/02Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds
    • C07C273/04Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of urea, its salts, complexes or addition compounds from carbon dioxide and ammonia

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Urea is produced form a gaseous mixture of H2, N2 and CO2, e.g. that obtained by the steam reforming of hydrocarbons. Carbon dioxide is absorbed from the mixture by the action, firstly, of an aqueous ammonia solution (e.g. above 70% by weight) and, secondly, of an ammonia-containing solution of ammonium carbonate, a solution of ammonium carbamate thus being obtained, together with a gaseous stream of nitrogen and hydrogen. The carbamate solution is passed to a urea reactor to obtain a urea solution containing unconverted carbamate and excess ammonia. The carbamate is decomposed and the evolved ammonia is recycled to the urea reactor along with carbon dioxide. The urea solution, now containing a reduced amount of carbamate (e.g. 50% of its original content), is passed to an adiabatic stripper in which the stripping gas used comprises hydrogen and nitrogen obtained from the CO2-absorption stage. Decomposition products together with water are removed from the adiabatic stripper, and are condensed in the presence of ammoniacal ammonium carbonate and the condensate so obtained is passed to the CO2-absorption step. <IMAGE>
GB7909086A 1978-04-05 1979-03-15 Urea synthesis Expired GB2018249B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT21993/78A IT1094295B (en) 1978-04-05 1978-04-05 INTEGRATED AMMONIA-UREA PROCEDURE

Publications (2)

Publication Number Publication Date
GB2018249A true GB2018249A (en) 1979-10-17
GB2018249B GB2018249B (en) 1982-09-02

Family

ID=11189914

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7909086A Expired GB2018249B (en) 1978-04-05 1979-03-15 Urea synthesis

Country Status (23)

Country Link
JP (1) JPS54132525A (en)
AU (1) AU519817B2 (en)
BE (1) BE875346A (en)
BR (1) BR7902122A (en)
CA (1) CA1110659A (en)
CH (1) CH637633A5 (en)
CS (1) CS230563B2 (en)
DD (1) DD142709A5 (en)
DE (1) DE2913793C3 (en)
DK (1) DK139179A (en)
EG (1) EG13847A (en)
ES (1) ES479940A1 (en)
FR (1) FR2421847A1 (en)
GB (1) GB2018249B (en)
IE (1) IE48099B1 (en)
IN (1) IN150631B (en)
IT (1) IT1094295B (en)
LU (1) LU81113A1 (en)
MX (1) MX151216A (en)
NL (1) NL7902566A (en)
PL (1) PL116665B1 (en)
SE (1) SE432591B (en)
SU (1) SU1225485A3 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2167066A (en) * 1984-11-02 1986-05-21 Toyo Engineering Corp Process for producing urea

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102016203277A1 (en) * 2016-02-29 2017-08-31 Thyssenkrupp Ag Integrated synthesis of ammonia and urea

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4832091B1 (en) * 1968-02-12 1973-10-04
IT1014987B (en) * 1974-06-12 1977-04-30 Snam Progetti INTEGRATED PROCEDURE UREA AM MONIACA
IT1034674B (en) * 1975-03-28 1979-10-10 Snam Progetti FLEXIBLE INTERGRATED PROCESS FOR THE PRODUCTION OF EDUREA AMMONIA
IT1065422B (en) * 1976-12-23 1985-02-25 Snam Progetti INTEGRATED AMMONIA-UREA PROCESS FOR UREA PRODUCTION

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NONE *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2167066A (en) * 1984-11-02 1986-05-21 Toyo Engineering Corp Process for producing urea

Also Published As

Publication number Publication date
FR2421847B1 (en) 1982-10-22
BE875346A (en) 1979-10-05
MX151216A (en) 1984-10-11
JPS54132525A (en) 1979-10-15
LU81113A1 (en) 1979-06-19
DE2913793B2 (en) 1980-06-04
PL214649A1 (en) 1979-12-17
AU519817B2 (en) 1981-12-24
PL116665B1 (en) 1981-06-30
CH637633A5 (en) 1983-08-15
IE48099B1 (en) 1984-09-19
SE432591B (en) 1984-04-09
AU4487679A (en) 1979-10-18
DD142709A5 (en) 1980-07-09
EG13847A (en) 1982-12-31
IE790706L (en) 1979-10-05
IT7821993A0 (en) 1978-04-05
BR7902122A (en) 1979-12-04
SE7903018L (en) 1979-10-06
DK139179A (en) 1979-10-06
GB2018249B (en) 1982-09-02
DE2913793C3 (en) 1981-05-27
SU1225485A3 (en) 1986-04-15
FR2421847A1 (en) 1979-11-02
NL7902566A (en) 1979-10-09
ES479940A1 (en) 1979-12-01
IT1094295B (en) 1985-07-26
CA1110659A (en) 1981-10-13
IN150631B (en) 1982-11-20
DE2913793A1 (en) 1979-10-11
CS230563B2 (en) 1984-08-13

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee