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GB2011901A - Perfluoroalkylthioethyl Ether Derivatives - Google Patents

Perfluoroalkylthioethyl Ether Derivatives

Info

Publication number
GB2011901A
GB2011901A GB7900061A GB7900061A GB2011901A GB 2011901 A GB2011901 A GB 2011901A GB 7900061 A GB7900061 A GB 7900061A GB 7900061 A GB7900061 A GB 7900061A GB 2011901 A GB2011901 A GB 2011901A
Authority
GB
United Kingdom
Prior art keywords
alkyl
perfluoroalkyl
alkylene
hydrogen
perfluoroalkylthioethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7900061A
Other versions
GB2011901B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/866,674 external-priority patent/US4190531A/en
Priority claimed from US05/874,714 external-priority patent/US4266080A/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB2011901A publication Critical patent/GB2011901A/en
Application granted granted Critical
Publication of GB2011901B publication Critical patent/GB2011901B/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/004Surface-active compounds containing F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/681Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of solid materials for removing an oily layer on water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C02F1/682Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water by addition of chemical compounds for dispersing an oily layer on water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/32Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Public Health (AREA)
  • Materials Engineering (AREA)
  • Pyridine Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Perfluoroalkyl compounds containing ether groups have the formula RfR1SCH2CH2OTZ wherein Rf is perfluoroalkyl optionally substituted by C2-6 perfluoroalkoxy, R1 is alkylene, alkyleneoxy, -thio- or aminoalkylene, T is C1-18 alkylene or phenylene, and Z is hydrogen, hydroxy, alkoxy, acyl, carbamyl, -O- CH2CH2SR1Rf, -NR3R4, where R3 and R4 each is C1-22 alkyl or together with nitrogen form a heterocyclic ring; <IMAGE> where R5 is hydrogen, oxygen, C1-22 alkyl, or substituted C1-22 alkyl, X is an anion, and y is 1 or 2; z is 0 or 1. They can be prepared directly by free- radical catalyzed addition of a perfluoroalkyl-thiol to a vinyl ether or subsequent reaction. These compounds are useful as surfactants and oil spill collecting agents.
GB7900061A 1978-01-03 1979-01-02 Perfluoroalkyl-thioethyl ether derivatives Expired GB2011901B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/866,674 US4190531A (en) 1978-01-03 1978-01-03 Method of concentrating and collecting oil spills
US05/874,714 US4266080A (en) 1978-02-02 1978-02-02 Perfluoroalkylthioethyl ether derivatives

Publications (2)

Publication Number Publication Date
GB2011901A true GB2011901A (en) 1979-07-18
GB2011901B GB2011901B (en) 1982-08-25

Family

ID=27127961

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7900061A Expired GB2011901B (en) 1978-01-03 1979-01-02 Perfluoroalkyl-thioethyl ether derivatives

Country Status (1)

Country Link
GB (1) GB2011901B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012028031A1 (en) * 2010-08-31 2012-03-08 广东标美硅氟新材料有限公司 A compounded oil outflow round-up agent, a reocess for its production and its use

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012028031A1 (en) * 2010-08-31 2012-03-08 广东标美硅氟新材料有限公司 A compounded oil outflow round-up agent, a reocess for its production and its use

Also Published As

Publication number Publication date
GB2011901B (en) 1982-08-25

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee