GB2010879A - Flexible Coating Resins From Siloxane Resins Having a Very Low Degree of Organic Substitution - Google Patents
Flexible Coating Resins From Siloxane Resins Having a Very Low Degree of Organic SubstitutionInfo
- Publication number
- GB2010879A GB2010879A GB7849484A GB7849484A GB2010879A GB 2010879 A GB2010879 A GB 2010879A GB 7849484 A GB7849484 A GB 7849484A GB 7849484 A GB7849484 A GB 7849484A GB 2010879 A GB2010879 A GB 2010879A
- Authority
- GB
- United Kingdom
- Prior art keywords
- weight percent
- resins
- silanol
- flexible coating
- low degree
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title abstract 3
- 238000000576 coating method Methods 0.000 title abstract 3
- 229920005989 resin Polymers 0.000 title 2
- 239000011347 resin Substances 0.000 title 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 title 1
- 238000006467 substitution reaction Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 5
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000008119 colloidal silica Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- -1 ether ester Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- ZJBHFQKJEBGFNL-UHFFFAOYSA-N methylsilanetriol Chemical compound C[Si](O)(O)O ZJBHFQKJEBGFNL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- QMYDVDBERNLWKB-UHFFFAOYSA-N propane-1,2-diol;hydrate Chemical compound O.CC(O)CO QMYDVDBERNLWKB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Silicon Polymers (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Surface Treatment Of Glass (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A pigment-free aqueous coating composition comprises a dispersion of colloidal silica in a solution in a lower aliphatic alcohol-water mixture or in an ether ester of ethylene or propylene glycolwater mixture of the partial condensate of a silanol of the formula RSi(OH)3 in which R is an alkyl radical having 1 to 3 carbon atoms or a phenyl radical. At least 70 weight percent of the silanol is CH3Si(OH)3 and at least 1 weight percent of the silanol is C6H5Si(OH3). The composition contains 10 to 50 weight percent of solids consisting essentially of 10 to 70 weight percent of colloidal silica and 30 to 90 weight percent of the partial condensate, and the composition contains sufficient acid to provide a pH in the range of from 2.8 to 6.0. The composition is useful for coating solid substrates, in particular for providing a scratch-proof and flexible coating on plastics materials.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86397077A | 1977-12-23 | 1977-12-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2010879A true GB2010879A (en) | 1979-07-04 |
| GB2010879B GB2010879B (en) | 1982-08-04 |
Family
ID=25342228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7849484A Expired GB2010879B (en) | 1977-12-23 | 1978-12-21 | Flexible coating resins from siloxane resins having a very low degree of organic substitution |
Country Status (6)
| Country | Link |
|---|---|
| JP (2) | JPS5487736A (en) |
| BE (1) | BE873005A (en) |
| CA (1) | CA1116771A (en) |
| DE (1) | DE2855792C2 (en) |
| FR (1) | FR2412595A1 (en) |
| GB (1) | GB2010879B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000006633A1 (en) * | 1998-07-27 | 2000-02-10 | Pilkington Plc | Coating for plastic substrate |
| WO2009014798A1 (en) | 2007-07-26 | 2009-01-29 | 3M Innovative Properties Company | Respirator, welding helmet, or face shield that has low surface energy hard-coat lens |
| EP3257890A1 (en) * | 2010-04-07 | 2017-12-20 | Allnex Netherlands B.V. | Crosslinkable composition |
| US10604622B2 (en) | 2013-04-08 | 2020-03-31 | Allnex Netherlands B.V. | Composition crosslinkable by Real Michael Addition (RMA) reaction |
| US10647876B2 (en) | 2011-10-07 | 2020-05-12 | Allnex Netherlands B.V. | Crosslinkable composition cross-linkable by real Michael addition reaction and resins for use in said composition |
| US10759962B2 (en) | 2015-04-17 | 2020-09-01 | Allnex Netherlands B.V. | Method for applying RMA crosslinkable coating on modified epoxy primer coating |
| US10767074B2 (en) | 2015-04-17 | 2020-09-08 | Allnex Netherlands B.V. | Process for the manufacture of a crosslinkable composition |
| US10774238B2 (en) | 2015-04-17 | 2020-09-15 | Allnex Netherlands B.V. | Method for curing a RMA crosslinkable resin coating, RMA crosslinkable compositions and resins for use therein |
| US11814536B2 (en) | 2015-04-17 | 2023-11-14 | Allnex Netherlands B.V. | Floor coating compositions |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1116771A (en) * | 1977-12-23 | 1982-01-19 | Ronald H. Baney | Flexible coating resins from siloxane resins having a very low degree of organic substitution |
| EP0048114A1 (en) * | 1980-09-12 | 1982-03-24 | Dow Corning Limited | Siloxane resin compositions and preparation and use |
| JPS5968377A (en) * | 1982-10-14 | 1984-04-18 | Toshiba Silicone Co Ltd | Coating composition and its preparation |
| JPS60221702A (en) * | 1985-01-23 | 1985-11-06 | Toray Ind Inc | Molding having transparent coating layer |
| JP2653023B2 (en) * | 1988-04-22 | 1997-09-10 | 大阪有機化学工業 株式会社 | Coating composition |
| EP1087001B1 (en) * | 1999-09-24 | 2004-12-01 | General Electric Company | Curable abrasion-resistant coating compositions |
| DE102021129250A1 (en) | 2021-11-10 | 2023-05-11 | EXXERGY GmbH | Improving glass strength and fracture toughness with a non-brittle coating |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1241236A (en) * | 1969-05-01 | 1971-08-04 | Owens Illinois Inc | Process of coating plastics with organopolysiloxanes and articles made thereby |
| IL37707A (en) * | 1970-09-25 | 1974-10-22 | Stauffer Chemical Co | Binder composition,its preparation and coating compositions containing it |
| GB1391850A (en) * | 1971-04-28 | 1975-04-23 | Matsushita Electric Industrial Co Ltd | Nonflammable coating composition for electronic parts |
| BE793556A (en) * | 1971-12-30 | 1973-06-29 | Stauffer Chemical Co | COATING COMPOSITIONS PROVIDING GALVANIC PROTECTION |
| BE793558A (en) * | 1971-12-30 | 1973-06-29 | Stauffer Chemical Co | COATING COMPOSITIONS PROVIDING GALVANIC PROTECTION |
| GB1390270A (en) * | 1972-11-06 | 1975-04-09 | Monsanto Ltd | Coating compositions |
| US3986997A (en) * | 1974-06-25 | 1976-10-19 | Dow Corning Corporation | Pigment-free coating compositions |
| CA1116771A (en) * | 1977-12-23 | 1982-01-19 | Ronald H. Baney | Flexible coating resins from siloxane resins having a very low degree of organic substitution |
-
1978
- 1978-09-19 CA CA000311613A patent/CA1116771A/en not_active Expired
- 1978-11-17 JP JP14216678A patent/JPS5487736A/en active Granted
- 1978-12-21 FR FR7835958A patent/FR2412595A1/en not_active Withdrawn
- 1978-12-21 GB GB7849484A patent/GB2010879B/en not_active Expired
- 1978-12-22 DE DE19782855792 patent/DE2855792C2/en not_active Expired
- 1978-12-22 BE BE192502A patent/BE873005A/en unknown
-
1980
- 1980-08-18 JP JP11332480A patent/JPS5641267A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000006633A1 (en) * | 1998-07-27 | 2000-02-10 | Pilkington Plc | Coating for plastic substrate |
| WO2009014798A1 (en) | 2007-07-26 | 2009-01-29 | 3M Innovative Properties Company | Respirator, welding helmet, or face shield that has low surface energy hard-coat lens |
| EP2179307A4 (en) * | 2007-07-26 | 2017-12-06 | 3M Innovative Properties Company | Respirator, welding helmet, or face shield that has low surface energy hard-coat lens |
| EP3257890A1 (en) * | 2010-04-07 | 2017-12-20 | Allnex Netherlands B.V. | Crosslinkable composition |
| US10647876B2 (en) | 2011-10-07 | 2020-05-12 | Allnex Netherlands B.V. | Crosslinkable composition cross-linkable by real Michael addition reaction and resins for use in said composition |
| US10604622B2 (en) | 2013-04-08 | 2020-03-31 | Allnex Netherlands B.V. | Composition crosslinkable by Real Michael Addition (RMA) reaction |
| US10774238B2 (en) | 2015-04-17 | 2020-09-15 | Allnex Netherlands B.V. | Method for curing a RMA crosslinkable resin coating, RMA crosslinkable compositions and resins for use therein |
| US10767074B2 (en) | 2015-04-17 | 2020-09-08 | Allnex Netherlands B.V. | Process for the manufacture of a crosslinkable composition |
| US10759962B2 (en) | 2015-04-17 | 2020-09-01 | Allnex Netherlands B.V. | Method for applying RMA crosslinkable coating on modified epoxy primer coating |
| US10920101B2 (en) | 2015-04-17 | 2021-02-16 | Allnex Netherlands B.V. | RMA crosslinkable compositions and RMA crosslinkable resins for easy to clean coatings |
| US11072724B2 (en) | 2015-04-17 | 2021-07-27 | Allnex Netherlands B.V. | Adhesion promotor for real michael addition crosslinkable compositions |
| US11414565B2 (en) | 2015-04-17 | 2022-08-16 | Allnex Netherlands B.V. | Process for the manufacture of a crosslinkable composition |
| US11674055B2 (en) | 2015-04-17 | 2023-06-13 | Allnex Netherlands B.V. | RMA crosslinkable compositions and RMA crosslinkable resins for easy to clean coatings |
| US11674054B2 (en) | 2015-04-17 | 2023-06-13 | Allnex Netherlands B.V. | Method for curing a RMA crosslinkable resin coating, RMA crosslinkable compositions and resins for use therein |
| US11713402B2 (en) | 2015-04-17 | 2023-08-01 | Allnex Netherlands B.V. | RMA crosslinkable compositions and RMA crosslinkable resins for easy to clean coatings |
| US11814536B2 (en) | 2015-04-17 | 2023-11-14 | Allnex Netherlands B.V. | Floor coating compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2010879B (en) | 1982-08-04 |
| DE2855792A1 (en) | 1979-06-28 |
| DE2855792C2 (en) | 1982-03-25 |
| JPS5618626B2 (en) | 1981-04-30 |
| BE873005A (en) | 1979-06-22 |
| DE2855792B1 (en) | 1981-01-29 |
| JPS5487736A (en) | 1979-07-12 |
| JPS5641267A (en) | 1981-04-17 |
| FR2412595A1 (en) | 1979-07-20 |
| CA1116771A (en) | 1982-01-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19931221 |